Ch. 8 Flashcards

1
Q

based on the kinetic-molecular theory states what four things about gases? a gas with these characteristics is called what?

A
  1. space between molecules is so small, it has no volume
  2. molecules in constant motion and collision of molecules against container walls is pressure of gas
  3. molecules experience no intermolecular forces
  4. Avg KE is proportional to absolute temp
    A GAS WITH THESE THINGS IS AN IDEAL GAS
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2
Q

what is formula to find K from C

A

K=C+273.15

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3
Q

pressure can use what units

A

1 atm=760 torr=760mmHg

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4
Q

what is standard temp and pressure

A

its NOT STANDARD CONDITIONS
temp is 0C, pressure is 1 ATM, and 1 mol of gas is 22.4 L

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5
Q

what is charles law

A

if pressure is constant than volume is proportional to temp, gas will expand when heated and vice versa

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6
Q

what is boyles law

A

if temp is constant than pressure is inversely proportional to volume. increase volume causes more space to move therefore decreasing pressure

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7
Q

if volume is constant than what is pressures relationship with temp

A

pressure is proportional to temp

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8
Q

what are some deviations from ideal gas behavior

A
  1. pressure of real gases is smaller than if gas was ideal (because more interactions b/w molecules not walls)
  2. volume of real gas is smaller than if gas was ideal (because volume occupied by gas is no longer negligible)
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9
Q

what conditions of pressure and temp causes ideal deviations

A

high pressure and low temp

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10
Q

what is total pressure

A

this is due to the collisions of all types of molecules within containers

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11
Q

what is partial pressure

A

the pressure exerted by one type of gas in the overall pressure of all gases within a container

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12
Q

what is daltons law of partial pressures

A

total pressure is sum of partial pressures of all constituent gases

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13
Q

what is effusion

A

escape of a gas molecule through a hole into an evacuated region

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14
Q

what is rate of effusion based on

A

based on weight of molecule since heavier molecules take longer to move

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15
Q

what is gas constant

A

0.083 L-atm/K-mol

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16
Q

a barometer with a liquid less dense than mercury would have the same, more, or less reading compared to a barometer with mercury

A

it would have a higher reading because the liquid would need to reach higher in the column for it to be equal at the pressure of the atmosphere

17
Q

with constant n and p, what is ideal gas formula?

A

v1/t1=v2/t2

18
Q

with constant n and t, what is ideal gas formula?

A

p1v1=p2v2

19
Q

with constant n and v, what is ideal gas formula?

A

p1/t1=p2/t2

20
Q

what is combined gas law? what value needs to stay constant

A

n needs to be constant for the formula to be p1v1/t1=p2v2/t2

21
Q

what is avogadros law

A

if equal volume containers have same pressure and temp, then they contain same number of particles

22
Q

what is avogadros formula

A

V1/n1=v2/n2

23
Q

what is standard molar value? what conditions must be met before you use this?

A

SMV is 22.4 L and temp must be 273 and pressure 1 atm

24
Q

how can you tell if a gas will deviate from ideal gas behavior

A

any gas that interacts with other molecules, increased IMF, will deviate because ideal gases have zero IMF

25
Q

how can you tell if a gas will more likely act as an ideal gas

A

if its small, most likely not polyatomic, zero to weak IMF

26
Q

what conditions cause ideal gases to deviate?

A

high pressure and low temp

27
Q

what conditions causes ideal gas law to give similar results as to real gas?

A

high temp and low pressure because these conditions allow molecules not to get close to each other

28
Q

gas in the same container may have different speeds but they will always have the same

A

temperature or kinetic energy

29
Q

molecule 1 is .6 grams and molecule 2 is .2 grams, which molecule will still be in a container with a small hole in it

A

molecule 1 because it weighs more having a slower effusion

30
Q

what is grahams law of effusion?

A

square root of molar mass of gas b divided by molar mass of gas A, first molecule always at bottom

31
Q

how would you calculate molar ratio

A
  1. balance equation, 2. you divide moles of specific compound by total moles on its specific side (reactants or products)
32
Q

partial pressure is proportional to

A

total number of moles of a gas