carboxylic acids Flashcards
functional group
-COOH
first four carboxylic acids
methanoic, ethanoic, propanoic, butanoic acid
what happens when carboxylic acids react with carbonates?
produce a salt, water and carbon dioxide
general formula
CnH2n+1COOH
what are the salts called in a carbonate reaction e.g ethanoic acid?
ethanoate
what happens when carboxylic acids dissolve in water?
they dissolve and release H+ ions, resulting in an acidic solution, but don’t ionise completely so form weak acidic solutions, so have a higher pH than strong acids with the same conc
what happens when carboxylic acids react with alcohols?
esters are formed
functional group of ester
-COO-
what type of acids are carboxylic?
weak
where does the position of equilibrium lie in the reversible reaction of carboxylic acid in water solution?
to the left
reversible reaction example ethanoic acid in water
CH3COOH (aq) <-> CH3COO- (aq) + H+ (aq)
how are esters made?
by heating carboxylic acids with alcohols under reflux and with a sulfuric acid catalyst
ethanoic acid + ethanol –>
ethyl ethanoate + water
general equation for esters
carboxylic acid + alcohol –> ester + water
how do you give esters the symbol?
carboxylic acid subtract final H + first C,H part of alcohol