Carbohydrates - questions Flashcards
What three elements do carbohydrates contain?
CHO
List two functions of carbohydrates
Energy store
structural
cell recognition
metabolism
Monosaccharides are defined as polyhydroxy carbonyl compounds. What are the two sorts of carbonyl group?
aldehyde
ketone
How many carbon atoms are there in glucose?
6
Is glucose an aldose or a ketose?
aldose
What is an epimer?
- Different compounds (structures) with the same molecular formula
- differ by configuration at only one carbon
What is a chiral carbon atom?
C atom with 4 different groups bonded to it
In a-glucose is the –OH group on C1 above or below the ring?
below
below ring is a. above ring is b
What is the name of the bond that joins two monosaccharides together to form a disaccharide?
glycosidic
What two monosaccharides make up lactose ?
galactose and glucose
In maltose are the two glucose units joined by an a1-4 or a b1-4 bond?
.
What is a reducing sugar?
Reducing sugar: the monosaccharide with the free anomeric C can reform a straight chain =>
carbonyl (-C=O) group can be oxidised (-COOH).
If the sugar is oxidised it acts as a reducing agent.
Name a common non-reducing disaccharide
.
State two properties that are important for storage polysaccharides
a links readily degraded by enzymes
highly branched - rapid release of monosaccharide
What are the names of the two molecules that make up starch?
Amylose
Amylopectin
What type of glycosidic bonds are present in glycogen?
a links
a1-6 branches every 10-12 glucose units
What type of glycosidic bonds are present in cellulose?
B-(1-4) linked glucose
What do alternate glucose units do in order to form a straight chain of cellulose?
rotated 180 degrees from previous one (flipped)
What is the name of the polysaccharide found in insect exoskeletons?
Chitin
What is the name of the polysaccharide found in bacterial cell walls whose formation is inhibited by penicillin?
peptidoglycan (murein)
Chains of heteropolysaccharide made up of repeating N-acetyl glucosamine (NAG) and N-acetyl muramic acid (NAM)