Carbohydrates - disaccharides Flashcards
Reactions of –OH groups in monosaccharides
2 points
- Intermolecular (occurring between different molecules)
2. Intermolecular condensation - way in which monosaccharides join together to form disaccharides and polysaccharides
Two monosaccharide units joined by a
glycosidic bond
The glycosidic bond can be
α or β depending on arrangement of –OH on anomeric C
always involve anomeric C of one of the component monnosaccharides
Maltose
2 glucose units joined a-(1-4)
Iso-maltose is similar but joined -(1-6)
Formed during the breakdown of starch
a-bond vs. b-linkage
2 points
- Even though some carbohydrates are composed of the same sugars (building blocks) they might differ in linkages
- they define the final conformation, properties and function of carbohydrates
Sucrose
- 1 fructose (ketohexose) and 1 glucose (aldohexose) joined together
- a (1-2) if start with glucose. b (2-1) if start with fructose
- Known as ‘caster sugar’ commercially extracted from sugarcane or beetroot
summary
Maltose and isomaltose are disaccharides linked by
a bond
formed during starch breakdown
summary
Celllobiose
a disaccharide of Glc joined by b (1-4) linkage
product of cellulose digestion
summary
Sucrose
- a disaccharide from sugarcane or beetroot
- consisting of Glc and Fru,
- joined by a(1-2) bond
summary
Some carbohydrates are composed of the same building blocks but they differ in
linkages.
Linkages define the final conformation, properties and function of carbohydrates