Carbohydrates - disaccharides Flashcards

1
Q

Reactions of –OH groups in monosaccharides

2 points

A
  1. Intermolecular (occurring between different molecules)

2. Intermolecular condensation - way in which monosaccharides join together to form disaccharides and polysaccharides

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2
Q

Two monosaccharide units joined by a

A

glycosidic bond

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3
Q

The glycosidic bond can be

A

α or β depending on arrangement of –OH on anomeric C

always involve anomeric C of one of the component monnosaccharides

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4
Q

Maltose

A

2 glucose units joined a-(1-4)

Iso-maltose is similar but joined -(1-6)

Formed during the breakdown of starch

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5
Q

a-bond vs. b-linkage

2 points

A
  1. Even though some carbohydrates are composed of the same sugars (building blocks) they might differ in linkages
  2. they define the final conformation, properties and function of carbohydrates
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6
Q

Sucrose

A
  1. 1 fructose (ketohexose) and 1 glucose (aldohexose) joined together
  2. a (1-2) if start with glucose. b (2-1) if start with fructose
  3. Known as ‘caster sugar’ commercially extracted from sugarcane or beetroot
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7
Q

summary

Maltose and isomaltose are disaccharides linked by

A

a bond

formed during starch breakdown

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8
Q

summary

Celllobiose

A

a disaccharide of Glc joined by b (1-4) linkage

product of cellulose digestion

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9
Q

summary

Sucrose

A
  1. a disaccharide from sugarcane or beetroot
  2. consisting of Glc and Fru,
  3. joined by a(1-2) bond
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10
Q

summary

Some carbohydrates are composed of the same building blocks but they differ in

A

linkages.

Linkages define the final conformation, properties and function of carbohydrates

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