Carbohydrates Flashcards

1
Q

What are carbs and where do they come from?

A

Made from plants via photosynthesis in form of glucose.

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2
Q

Explain monosaccharides.

A

Smallest form of carbs. They are either aldehyde or ketones that have 2+ hydroxyl groups.

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3
Q

What is dihydroxyacetone?

A

Smallest monosaccharide. Ketose used in sunless tanning agent.

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4
Q

What is D-glyceraldhyde?

A

Smallest monosaccharide. Aldose. Glucose metabolite during respiration.

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5
Q

What is an isomer?

A

Same molecular formula but different structure

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6
Q

Two types of isomers.

A

Constitutional and stereoisomers

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7
Q

What are constitutional isomers?

A

Different in attachment of atoms. Same molecular formula but different arrangement of atoms.

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8
Q

What are stereoisomer and name two types.

A

Atoms connected in the same order but different spatial arrangement.
Enantiomers and diastereoisomer.

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9
Q

What are enantiomers?

A

Non-superimposable mirror images.

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10
Q

What are diastereoisomers and give two types.

A

Isomers that are not mirror images.
Epimers and anomers.

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11
Q

What are epimers?

A

Differ at one of several asymmetric carbon atom.

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12
Q

What are anomers?

A

Isomers that different at a new asymmetric carbon atom formed on ring closure.

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13
Q

What is a disaccharide?

A

Two monomers covalently bonded together by an o-glycosidic bond. End can revert into linear form and act as reducing sugar.

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14
Q

What monomers make maltose and where is it found?

A

Two glucose. Found in malt, corn syrup.

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15
Q

What monomers make sucrose and where is it found in?

A

Glucose and fructose. Sugar, sugar cane, sugar beet.

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16
Q

What monomers make lactose and where is it found in?

A

Galactose and glucose. In dairy.

17
Q

Explain how lactose intolerance is caused.

A

Lack of lactase causes lactose to pass into large intestine. H.conc. Of lactose causes h.osmolarity in large intestine stopping the water from being absorbed into blood leading to watery stool. Fermentation of lactose by bacteria causes production of carbon dioxide causing bloating.

18
Q

What is a polysaccharide?

A

Most carbs in nature found as polysaccharide or glycans. Many monomers joined together.

19
Q

Name two forms of polysaccharides.

A

Homopolysaccharides and heteropolusaccharides.

20
Q

In what form is glucose stored in during photosynthesis?

A

Starch, broken down into glucose monosaccharides.

21
Q

Name two types of starch.

A

Amylose and amylopectin

22
Q

Describe amylose.

A

Long chain of alpha 1.4 linked glucose monomers.

23
Q

Describe amylopectin.

A

Chain of monomers with branches. Alpha 1.6 linked glucose form branches.

24
Q

What is the energy store in animals called?

25
What is the energy store in animals called?
Glycogen.
26
Repeating monomers of glucose and has frequent branching of alpha 1.6 linked glucose molecules. Less soluble and doesn’t contribute to osmolarity. Soluble.
27
What is the energy store in plants?
Cellulose.
28
Describe cellulose.
Tough, fibrous, water insoluble. Linear chain of beta glucose monomers. 1.4 glycosidic bonds. Resistant to digestion.
29
Example of heteropolysaccharide.
Glycosaminoglycans are I branched heteropolysaccharide, made of repeating disaccharide units. Rich in ECM.
30
How is glucosaminoglycans is made.
Activating monomeric sugar, transfer across membrane, condense activated sugars into polysaccharids, add sulphate. All steps requires enzymes.
31
What are proteoglycans?
Protein with specific sulphate glycosaminoglycans. Attached outside of PM and ECM. abundant in connective tissue. For adhesion, recognition, transfers between cells and ECM.
32
What are glucoproteins?
Attachment carbs. Functions: enzyme, transport, receptors, hormones, and structural proteins.
33
Are amino acids and carbs under genetic control?
Amino acids yes carbs no.
34
What are lectins?
Proteins bind to carbs that allow glycoproteins to fulfil properties. Eg. Leukocytes migrate along blood vessel to find and destroy bacteria. During this endothelium cells will express a lectin called p-selectin which binds to oligosaccharides on glycoproteins expressed on leukocytes surface. This slows leukocytes down and through interaction with further lectin show the way to the infected site.