Carbohydrates Flashcards

1
Q

Are the most abundant class of bioorganic molecules on planet Earth.

A

Carbohydrates

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2
Q

In the form of cellulose carbohydrates served as what?

A

Structutal Element

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3
Q

In the form of starch, carbohydrates?

A

provide energy reserves for the plant

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4
Q

Is a polyhydroxy aldehyde, a polyhydroxy ketone, or a compound that yields polyhydroxy aldehydes or polyhydroxy ketones upon hydrolysis.

A

Carbohydrate (Cn(H2O)n)

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5
Q

What are the classifications of carbohydrates

A

Monosacaride
Disaccharide
Oligosaccharide
Polysaccharide

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6
Q

Are images that coincide at all points when the images are laid upon each other

A

Superimposable mirror images

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7
Q

Are images where not all points coincide when the images are laid upon each other

A

Non-superimposable mirror images

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8
Q

Is an atom in a molecule that has four different groups bonded into a tetrahedral orientation

A

Chiral center

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9
Q

Is a molecule whose mirror images are not superimposable

A

Chiral molecule

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10
Q

Is a molecule whose mirror images are superimposable

A

Achiral molecule

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11
Q

Which of the molecule of chirality do not possess handedness?

A

Achiral molecule

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12
Q

Which one do possess handedness?

A

Chiral molecules

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13
Q

The simplest type of carbohydrates in the building block for more complex type of carbohydrates

A

Monosaccharides

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14
Q

Are isomers that have the same molecular and structural formulas but differ in the orientation of atoms in space

A

Stereoisomers

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15
Q

Stereoisomers can be subdivided into two types, what are these?

A

Enantiomers
Diastereomers

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16
Q

What is the meaning of “entantios”?

A

Opposite

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17
Q

Are stereoisomers whose molecules are non superimposable mirror images

A

Enantiomers

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18
Q

Are stereoisomers whose molecules are not mirror images

A

Diastereomers

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19
Q

Cis-trans isomers are?

A

Diastereomers

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20
Q

If the molecules have the same molecular formula, they are?

A

Isomers

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21
Q

If the atoms bonded in the same order in two molecules, they are?

A

Stereoisomers

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22
Q

If the atoms are NOT bonded in the same order in the two molecules, they are?

A

Constitutional isomers

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23
Q

Is a compound that rotates the plane of polarized light?

A

Optically active compound

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24
Q

Is a chiral compound that rotates the plane of polarized light in a clockwise direction

A

Dextrorotatory compound

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25
The latin "dextro" means?
Right
26
Is a chiral compound that rotates the plane of polarized light in a counterclockwise?
Levorotatory compound
27
Is a two dimensional structural notation for showing the spatial arrangement of groups about chiral centers in molecules
Fischer projection formula
28
If the -OH is in the right then it is a?
D-isomer
29
If the -OH is in the left then it is a?
L-isomer
30
Are enantiomers whose molecules differ only in the configuration at one chiral center?
Epimers
31
What are the three four five and six carbon monosacaride atoms called?
Triose Tetrose Pentose Hexose
32
Is a monosaccharide that contains an aldehyde functional group
Aldose
33
Is a monosaccharide that contains a ketone functional group
Ketose
34
Monosaccharides are often called as?
Sugars
35
True or false. Sugar is a general designation for either a monosaccharide or a disaccharide?
True
36
Saccharide from latin "saccharum" means
Sugar
37
Is a two dimensional structural notation that specifies the three dimensional structure of a cyclic form of a monosaccharide
Haworth projection formula
38
The resulting cyclic compounds are cyclic, what?
Hemiacetals
39
A cyclic monosaccharide containing a six atom ring is called?
Pyranose
40
One containing a five atom ring is called?
Furanose
41
Is the hemiacetal carbon atom present in a cyclic monosaccharide structure
Anomeric carbon atom
42
Are cyclic monosaccharides that differ only in the positions of the substituents on the a anomeric carbon atom
Anomers
43
What are the acidic sugars
Aldonic acid alduronic acid aldaric acid
44
Is an acid group that is on top and it uses weak oxidizing agent
Aldonic acid
45
Is an acid group that is on bottom and it uses enzymes
Alduronic acid
46
Is an acid groupn that is on both top and bottom. It uses strong oxidizing agent
Aldaric acid
47
Is an acetyl formed from a cyclic monosaccharide by replacement of the hemiacetal carbon -OH group within -OR group. It exists both and alpha and beta form.
Glycoside
48
The bond that links the two monosaccharides of a disaccharide together. The bond in a disaccharide resulting from the reaction between the hemiacetyl carbon atom -OH group of one monosaccharide in an -OH group on the other monosaccharide
Glycosidic linkage
49
Polysaccharides are often also called as what?
Glycans
50
True or false Unlike monosaccharides and most disaccharides polysaccharides are not sweet.
True
51
What are the types of polysaccharides?
Storage polysaccharide Structural polysaccharide Acidic polysaccharide
52
Energy storage polysaccharide in plants
Starch
53
Energy storage polysaccharide for animals aka animal starch
Glycogen
54
- Is a structural component of plant cell walls - Is the most abundant naturally occurring polysaccharide - The woody portions of plants - Contains 5,000 glucose units - Non-digestible
Cellulose
55
- The second most abundant naturally occurring polysaccharide - Function is to give rigidity - Been found in the cell walls of fungi - Structurally identical to cellulose - ND-glucosamine, product of hydrolysis of chitin, that is marketed as a dietary supplement
Chitin
56
Are also associated with the jelly like consistency of the vitreous humor of the eye
Hyaluronic acid
57
The greek word hyalos means?
Glass
58
- Is a blood anticoagulant - It prevents the formation of clots in the blood and - Source for pharmaceutical heparin is intestinal or lung tissue of slaughterhouse animals
Heparin
59
Nucleic acids, beta-d-ribose, beta-d-deoxyribose, and ATP
D-Ribose
60
Formed in metabolic processes
D-Ribulose
61
Gum Arabic. Plum and cherry gums
D-Arabinose
62
Wood, gums, proteoglycans, glycosaminoglycans
D-Xylose
63
Heart cells/muscle
D-Lyxose
64
Intermediate in ironic acid pathway
L-Xylulose
65
Another name for D-Ribose
DNA & RNA sugar
66
aka wood sugar
D-Xylose
67
A constituent of a lyxoflavin isolated from human heart
D-Lyxose
68
Two Constituent of glycoproteins
D-Xylose and D-Arabinose
69
Is an intermediate in pentose phosphate pathway (PPP)
Ribulose phosphate
70
What are D-glucose?
Grape sugar Dextrose Blood sugar
71
What is the source of D-Glucose?
Fruit juices