Carbohydrates Flashcards

1
Q

what chemical elements are carbohydrates made up of?

A

C H O

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2
Q

what are the three types of carbohydrates?

A

monosaccharides, disaccharides, polysaccharides

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3
Q

how can sugars be classified?

A

reducing and non-reducing

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4
Q

how are reducing and non-reducing sugars classified?

A

it is dependant on their ability to share electrons (reducing sugars can donate electrons -the carbonyl group becomes oxidised- the sugars become the reducing agent)

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5
Q

nemonic for lose/ gain of electrons

A

OIL RIG

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6
Q

can non reducing sugars donate electrons?

A

no tf they cannot be oxidised

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7
Q

how are monosaccharides named?

A

number of carbons
eg 5 carbons—-> pentose

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8
Q

how are sugars identifiable?

A

-ose ending

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9
Q

what is the molecular formula of glucose?

A

C6H12O6

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10
Q

what is the main function of glucose?

A

energy source (main substrate used in respiration, releasing energy for the production of ATP)

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11
Q

what is an isomer?

A

same molecular formula but different atom arrangement in space (tf diff properties)

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12
Q

what are the two isomers of glucose?

A

alpha (α) glucose and beta (β) glucose

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13
Q

what does structural variety in carbohydrates result in?

A

different functions between carbohydrates

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14
Q

what does glucose form when in aqueous solutions?

A

a ring structure

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15
Q

where is the hydroxyl on C1 in beta (β) glucose?

A

think drawing (β)
above

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16
Q

where is the hydroxyl on C1 in alpha (α) glucose?

A

below

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17
Q

is starch made of alpha (α) glucose or beta (β) glucose?

A

alpha (α) glucose

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18
Q

is glycogen made of alpha (α) glucose or beta (β) glucose?

A

alpha (α) glucose

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19
Q

is cellulose made of alpha (α) glucose or beta (β) glucose?

A

beta (β) glucose

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20
Q

what polysaccharides are formed from the different isomers of glucose?

A

strach, glycogen, cellulose

21
Q

what are sugars containing 5 carbons called?

A

pentose sugars

22
Q

what are two important examples of pentose sugars?

A

ribose and deoxyribose

23
Q

where is ribose found?

A

the nucleotides that make up RNA

24
Q

where is deoxyribose found?

A

the nucleotides that make up DNA

25
what is the difference between ribose and deoxyribose?
deoxyribose has lost 1 oxygen on C2
26
when are polysaccharides and disaccharides formed?
when two hydroxyl groups (-OH) on diff monosaccharides interact to form a strong covalent bond (glycosidic bond)
27
how are glycosidic bonds formed?
through condensation reactions
28
what is the result of a glycosidic bond being formed?
-either a polysaccharide or disaccharide -1 water molecule being removed
29
α glucose + α glucose-->
maltose
30
α glucose + β galactose-->
lactose
31
α glucose + fructose-->
sucrose
32
β glucose + β glucose-->
cellobiose
33
what are the features of monosaccharides?
-the simplest carbohydrates -sweet-tasting -soluble -full of C-H bonds for energy storage
34
what do tri/tetr-oses exist as?
chains
35
what do pent/hex-oses exist as?
rings
36
what is the colour change when using Benedict's?
blue green yellow organge-red
37
reducing sugars reduce Cu2+--->
Cu+ (forming copper (I) oxide precipitate
38
can non-reducing sugars be tested with Benedict's?
no, the glycosidic bond must be hydrolysed to free the reducing groups
39
what is the test for non-reducing sugars?
-boil with HCl (to break into monosaccharides) -cool and add NaHCO3 (to neutralise) -test with Benedict's, like reducing
40
as there are many different monosaccharides...
there are many different types of glycosidic bonds
41
what type of glycosidic bond does maltose have?
α 1,4 (disaccharide)
42
what type of glycosidic bond does sucrose have?
α 1,2 (disaccharide)
43
what type of glycosidic bond does cellulose have?
β 1,4 (polysaccharide)
44
what type of glycosidic bond does amylose have?
α 1,4 (polysaccharide)
45
what type of glycosidic bond does amylopectin have?
α 1,4 and 1,6 (polysaccharide)
46
what is each glycosidic bond catalysed by?
by enzymes specific to which OH groups are interacting
47
what examples of polysaccharides am I expected to know
starch, glycogen and cellulose
48
what are polysaccharides?
macromolecules, made up of lots of monomers joined by glycosidic bonds, formed by condensation reactions