Carbohydrates Flashcards

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1
Q

What are Carbohydrates components of?

A
  • Water and Carbon
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2
Q

What molecules are carbohydrates made of?

A
  • Hydrogen, Oxygen + Carbon

- Ratio 1:2:1 - CH20

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3
Q

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A

CARBOHYDRATES ARE

  • Main source of Energy for all living organisms –Glucose.
  • Serve as structural components such as DNA – Ribose, Cell wall made up of cellulose.
  • The simplest carbohydrates are sugar units also called saccharides.
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4
Q

What are the 4 types of Carbohydrates?

A
  • Monosaccharides (1 saccharide)
  • Disaccharides (2 saccharide)
  • Oligosaccharide (3 or more saccharides)
  • Polysaccharide ( >10 saccharides)
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5
Q

What are the simplest carbohydrates/ sugar units also called

A
  • Saccharides also called sugar units.
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6
Q

What are Monosaccharides?

give examples

A
  • Simplest carbohydrates + can’t be hydrolysed to
    smaller carbs.
  • End in -ose
  • E.g. Glucose, Galactose, Fructose
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7
Q

What is the functional group of a monosaccharide?

A
  • Carbonyl Group

- Chemically organic functional group composed of a carbon atom double-bonded to an oxygen atom → [C=O]

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8
Q

What are the 2 Carbonyl groups for a Monosaccharide?

A
  • Aldehyde ( C=O bonded to at least one Hydrogen) always in C chain.
  • Ketone ( C=O bonded to 2 Carbons) always w/in C chain.
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9
Q

What do Aldehyde’s and Ketones turn to when they’re monosaccharides.

A
  • Aldoses

- Ketoses

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10
Q

Read

A
  • Most common monosaccharide: 3-7 carbons (unbranched)
  • No. of C atoms given by prefix: tri-, tetr-, pent-, hex-, hept-
  • No. of carbons Generic Name: 3 Triose
    4 Tetroses
    5 Pentoses
    6 Hexoses
    7 Heptoses
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11
Q

Read

A
  • A 3C triose sugar with an aldehyde group = aldotriose sugar
  • A 4C tetrose sugar with an aldehyde group = aldotetrose sugar
  • A 5C pentose sugar with an aldehyde group = aldopentose sugar
  • A 6C hexose sugar with an aldehyde group = aldohexose sugar
  • A 7C heptose sugar with an aldehyde group = aldohepose sugar
  • A 3C triose sugar with an ketone group = ketotriose sugar
  • A 4C tetrose sugar with an ketone group = ketotetrose sugar
  • A 5C pentose sugar with an ketone group = ketopentose sugar
  • A 6C hexose sugar with an ketone group = ketohexase
  • A 7C heptose sugar with an ketone group = ketoheptose sugar
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12
Q

What are Chiral Centers?

see pics slide 11 +12 + 13 +14

A
  • Chiral centers are tetrahedral atoms (usually C) that have 4 diff substituents.
  • Molecules with “n” chiral centers have 2n stereoisomers.
  • E.g. Glyceraldehyde: 1 chiral center
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13
Q

What are Isomers?

A
  • 2 compounds that have the same molecular formula, but have diff structural formulas.
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14
Q

Read

A
  • Ribose & Ribulose are isomers that differ by the location of the carbonyl group (C=O).
  • In ribose the C=O belongs to an aldehyde
  • In ribulose the C=O belongs to a ketone
  • Ribose is classified as an aldose, Ribulose is a ketose
  • Similarly Glucose & Fructose are isomers where glucose is an aldose & fructose is a ketose.
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15
Q

What is the main source of energy for cells or humans?

A
  • Glucose ( C6 H12 06)
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16
Q

Read

A
  • Look at slides 16 - 19
17
Q

How are monosaccharides attached to each other?

A
  • By covalent bonds called Glycosidic bonds by a condensation rxn.
18
Q

Where are Glycosidic bonds formed?

A
  • Between C 1 of a monosaccharide & a hydroxyl (OH) carried by a C atom in a diff monosaccharide molecule.
19
Q

Give an example of a Disaccharide?

A
  • Maltose (2 glucose molecules covalently bind by a glycosidic bond.
  • Lactose (Galactose + Glucose)
  • Sucrose (Glucose + Fructose)
20
Q

Oligosaccharide example?

A
  • Raffinose

- Stachyose

21
Q

What are Polysaccharides also called?

A
  • Glycans
22
Q

Function of a Polysaccharide?

A
  • Energy storage (glycogen in animal & starch in plant cells)
  • Structural support (cellulose in plant cell wall)
23
Q

Examples of Polysaccharides?

A
  • Glycogen
  • Starch
  • Cellulose
  • Chitin
24
Q

Use of monosaccharides in animals?

A
  • Glucose is carried by the blood to transport energy to cells throughout the body.
25
Q

Use of monosaccharide in plants?

A
  • Fructose
    = sweet taste
    = attracts animals
    = disperse seeds
26
Q

Use of disaccharide in animals?

A
  • Glycogen = short-term energy store in liver & in muscles.
27
Q

Use of disaccharide in plants?

A
  • Sucrose – carried by Phloem to transport energy to cells

through the plant.

28
Q

Use of Polysaccharides in animals?

A
  • Glycogen = short-term energy store in liver & in muscles
29
Q

Use of Polysaccharides in plants?

A
  • Cellulose = strong fibers, used to construct plant cell wall.
30
Q

Read

A
  1. Major source of energy which is available immediately as glucose.
  2. When excess Carbohydrate is available it can be stored as glycogen in the liver & muscle cells of animals & starch in plants.
  3. Forms Structural Tissue in - Plants - cellulose
    - Animals – proteoglycans: teeth, cartilage
    - Bacteria - cell wall
  4. Found in the plasma membrane linked to lipids – glycolipids & play a role in structural integrity of the cell.
  5. Found in the plasma membrane linked to proteins – glycoproteins & play a role in cell recognition.
  6. Ribose sugar is important in the formation of DNA & RNA.
  7. Proteins Sparing Action – when Carbohydrates are not sufficient in our body, proteins are broken down to fulfil the requirement of Carbohydrate.
  8. Helps prevent Ketosis – in the absence of adequate Carbohydrate, large amounts of ketone bodies are produced in the blood. This increases the blood acidity. In severe cases this can lead to coma/death.
  9. Provides Fibre – creates soft bulky stool that moves quickly through the large intestine.