Carbohydrate structure and transport Flashcards

1
Q

what is a carbohydrate

A

it is an energy producing nutrient

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2
Q

what is the structure of a basic monosaccharide

A

(CH2O)n

for every single carbon, there will be 2 hydrogens present

this structure only applies to unmodified monosaccharides, so this doesn’t count for deoxyribose

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3
Q

what functional group do glyceraldehydes have

A

aldehydes

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4
Q

what functional group do dihydroxyacetones have

A

ketones

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5
Q

how do you figure out which carbon in your carbohydrate is the alpha or number 1

A

the most oxidized carbon (the one beside your your carbonyl group)

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6
Q

what is the main difference for numbering the carbons for aldoses and ketones?

A

for aldoses the carbonyl is C1 and for ketones carbonyl is C2

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7
Q

why are sugar structures so diverse

A

because of chirality and isomers

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8
Q

isomers

A

same formula, different structure

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9
Q

constitutional isomers

A

same formula but different order of functional group bonding

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10
Q

stereoisomers

A

same formula and structure but are enantiomers or diastereomers (non mirror image)

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11
Q

epimers

A

different at one asymmetric carbon

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12
Q

why are different molecular positions important

A

it impacts protein interaction

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13
Q

what does reducing a sugar mean?

A

being able to revert a sugar back to its linear form through a redox reaction

in order for this to happen there needs to be a free (-OH) on the anomeric carbon that can be converted back to a C=O (the carbonyl is oxidized to a carboxyl)

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14
Q

Glycosidic bonds

A

these are bonds that link sugars through a condensation reaction

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15
Q

what is required to cleave glycosidic bonds

A

hydrolysis reaction, requiring a water

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16
Q

what two monosaccharide sugars combine to form disaccharide sucrose

A

glucose and fructose

17
Q

why is glycogen important in our bodies

A

because it stores glucose in long chains and without this the osmotic pressure in our bodies will build

18
Q

at what end are glucose units added and removed?

A

from the non-reducing end that can’t open back up

19
Q

where is glycogen found

A

in the liver and muscle

20
Q

which enzymes help cleave/breakdown disaccharides

A

lactase, maltase, and sucrase

21
Q

how do specific proteins recognize specific sugars

A

through amino acid side chains in active sites of enzymes

22
Q

what is an alpha type bond

A

when the OH is below the plane

23
Q

what is a beta type bond

A

when the OH is above the plane