C9- Hydrocarbons Flashcards
What is crude oil
Crude oil is a mixture of molecules called hydrocarbons
How is crude oil formed
Crude oil is formed over millions of years from the skeletons of plankton buried in the mud.
-Crude oil is found in rocks and is a finite resource
What are hydrocarbons
Hydrocarbons are molecules made out of hydrogen and carbon atoms only
Alkanes are a group of hydrocarbons
What is the general formula for alkanes
The general formula for alkanes is CnH(2n+2)
You multiply the amount of carbon atoms by two and then add two to get the amount of hydrogen atoms
The first four alkanes are Methane,ethane,propane and butane
How does the size if the hydrocarbon molecule affect its viscoxity
As the size of the hydrocarbon molecule increases, viscosity also increases. This means that long chain hydrocarbons are very viscous and move very slowly
Note:viscousity refers to the thickness of a fluid
How does the size of the hydrocarbon molecule affect its flammability
As the size of the hydrocarbon increases its flammability decreases. This means that shorter chain hydrocarbons (e.g methane) are much more flammable than longer chain hydrocarbons
How does the size of the hydrocarbon affect its boiling point
-Shorter chain hydrocarbons have lower boiling points than longer chain molecules. As the size of the hydrocarbon molecule increases so does the boiling point
What happens when hydrocarbons are burnt
- When hydrocarbons are burnt they release energy
- The carbon and hydrogen atoms react with oxygen in combustion to release energy. The carbon and hydrogen are oxidised.
What happens if the oxygen is unlimited in a combustion reaction
If the oxygen is unlimited in a combustion reaction then the reaction will produce carbon dioxide and water. This is called complete combustion
Hydrocarbon+oxygen—>carbon dioxide + water vapour
What is fractional distillation and why is it used
- In order to make the hydrocarbons in crude oil useful you have to separate them using a technique called fractional distillation
- In fractional distillation the crude oil is split into different fractions. Each fraction contains hydrocarbons with a similar number of carbon atoms
How does fractional distillation happen
1.Firstly the crude oil and heated to a very high temperature
2.This causes the crude oil to evaporate and turn into a has
3.The crude oil vapour then enters a fractional distillation column that is hotter at the bottom and colder at the top
4.The hydrocarbon vapours then rise up the fractional distillation column and condense when they reach their boiling point(they turn back into a liquid
5The liquid fractions are removed
6.The other hydrocarbon vapours continue to rise up the fractional distillation column until they reach their boiling points when they condense
Longer chain hydrocarbons condense into liquids early on whereas shorter chain hydrocarbons with low boiling points condense later on.
What happens to very long chain hydrocarbons and very short chain hydrocarbons in a fractional distillation column
Very long chain hydrocarbons have very high boiling points and come out of the fractional distillation column at the bottom
Very short chain hydrocarbons have very low boiling points and so do not condense , they leave the column at the top as gasses
What can different fractions of hydrocarbons be used for
Some hydrocarbon fractions can be used as fuel and others can be used as chemicals to make chemicals
What happens during cracking
During cracking a longer chain hydrocarbon is broken down into a shorter chain hydrocarbon and an alkene.
Cracking is important as shorter chain hydrocarbons are in high demand as they are more flammable and can be used as fuels.
What are the two different methods of cracking
- Catalytic cracking- This is where the hydrocarbon is heated to a very high temperature with a catalyst to break it down and vaporise it . The catalyst speeds the reaction up.
- Steam cracking-This is where the hydrocarbon is heated with steam at high temperatures. The hydrocarbon vapourises and mixes with the steam and is broken down into a shorter chain hydrocarbon and an alkene