C8 Flashcards
Tests for positive ions(cations)
Flame tests
Precipitate with sodium hydroxide
Tests for negative ions(anions)
Which ions
Hallides
Carbonates co3
Sulfates so4
Identifying a half-life ion and what does the precipitate colour tell us
Cl. Br l
Add couple drops of nitric acid
Followed by a couple drops of SILVER NITRATE (agno3)
AgCl-white.
AgBr-cream. Solids
AgI-yellow.
As you go down g7 precipitate gets darker
Testing for carbonates (CO3)
Add dilute acid
If present CO2 gas is released + limewater turns milky
Testing for sulfates
+
Positive results
Add couple drops of HCl
Followed by couple drops of barium chloride (BaCl2)
Positive results =white precipitate
Precipitate with sodium hydroxide
Metal ions form a precipitate (insoluble metal hydroxide)
When SODIUM HYDROXIDE SOLUTION is added
Transition metals produce precipitates
Instrumental methods (flame emission spectroscopy) advantages
- accurate (close to true value)
- sensitive (can detect small amounts)
- rapid(quick)
- only small sample needed
- provide quantitative data-measure conc of substance
Flame emission spectroscopy what happens
A SAMPLE is put into a FLAME and the LIGHT GIVEN OUT is passed through a SPECTROSCOPE
Output is a LINE SPECTRUM that can be used to identify metal ions+measure their conc
Colour of precipitate
Calcium - calcium hydroxide
Aluminum -aluminum hydroxide
Magnesium -magnesium hydroxide
Calcium hydroxide-white
Aluminium hydroxide-white but clear with excess NaOH
Magnesium hydroxide-white
Precipitates of
Cu 2+
Fe 2+
Fe 3+
Cu 2+-blue
Fe 2+-green
Fe 3+-brown
How do we know a substance is pure
The boiling or melting point
A pure substance melts and boils at SPECIFIC TEMPERATURE
(Straight lines)
How can we tell a substance is impure
Lowers mp
Increases bp
RANGE OF TEMPS
(Wobbly line)
Formulation is
A useful mixture with specific purpose
Eg paint,fuel,medicine,alloys,fertilizer,food, cleaning products
Unadulterated is
A substance with nothing added to it
In its natural state
Eg milk,fresh orange
Chromatography is used to
Separate mixtures + identify substances
What is a solvent front
The distance a solvent (water) moves up the page
Control variables of the start line in chromatography
WATER level must NOT be ABOVE the line or ink will dissolve
Must be drawn in PENCIL pen ink will dissolve in water or run up the page
Stationary phase is
+
What happens if a substance is more attracted to the stationary phase
The paper
Substance will not move far up the paper
Mobile phase is
+what happens if a substance is more attracted to the mobile phase
The solvent
Substance will move further up water
Rf value is calculated by
Distance moved by substance/distance moved by solvent
Units-cm or mm
Rf is always over 1
Conducting flame tests
Has to have 1 metal ion in sample, if a mixture then flame colour is masked
LOOP CLEANED by dipping in HCL acid and holding it in a BLUE BUNSEN FLAME until it burns with NO COLOUR
DIPPED IN SAMPLE +PUT IN BLUE FLAME
Observe and RECORD FLAME COLOUR
Flame colour Lithium ions Sodium ions Potassium ions Calcium ions Copper ions
Li-red Na-yellow K-lilac Ca-orange/red Cu-green