C6 Electrolysis Flashcards

1
Q

why cannot solid ionic compounds cannot conduct electricity .

A

The ions are locked in place and are not free to move , they are held together by strong electrostatic forces of attraction .

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2
Q

Why can ionic compounds that are molten or dissolved in water conduct electricity ?

A

the forces of attraction are broken and the ions are free to move .

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3
Q

what are electrolytes

A

compound that is broken down by electrolysis and therefore can conduc electricity

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4
Q

what are the two ions n lead bromine

A

Pb2+ Br-

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5
Q

how many electrodes are in electrolysis

A

two

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6
Q

what are the electrodes made of

A

conducting materal such as graphite or a metal .

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7
Q

what is the negative electode

A

cathode

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8
Q

what is the positive electrode

A

anode

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9
Q

what happens pb2+ (lead) whta type of reaction is ths

A

the Pb+ gain two electrons from Pb atoms this is called Reduction
Pb—>pb2+ +2e-

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10
Q

what happens in reduction

A

u gain electrons

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11
Q

What happens to Br-

A

Br- looses oe electron to for Br atoms this is called oxidation

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12
Q

what happens in oxidiation

A

loose electrons

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13
Q

what is electrolysis

A

electrolysis is the breakdown of a substance conataining ions by electricity

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14
Q

how are metals less reactive than carbon extracted

A

metals less reactive than carbon cna be extracted by reduction with carbon .

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15
Q

how are metals more reactive than carbon extracted.

A

Metals more reactive than carbon can be extracted using electrolysis .

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16
Q

What does aluminium oxide contain

A

it contains aluminum ions (AL3+) and Oxide ions (02-)

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17
Q

why is aluminium oxide not produced by the electrolysis of an aqueous solution ?

A

As aluminium oxide is insoluble in water .

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18
Q

what is the first step of electrolysis with aluminium oxide

A

aluminium oxide is mixed with cryolite .

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19
Q

why is aluminium oxide mixed with cryolite

A

as it lowers the melting point of aluminium oxide as it as a high a very high melting point , reducing the amount of energy needed and saves money for electrolysis .

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20
Q

what are the anode and cathode made of and why ?

A

Made of graphite , as it is a very good conductor of electricity and has a very high melting point .

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21
Q

where are the AL3+ ions attracted to.

A

AL3+ ions are attracted to the cathode (the negative electrode .

22
Q

Give the half equation at the cathode for aluminium oxide what type of reaction is it and why

A

AL3+ + 3E- arrow AL - it is a reduction as each ion gains three electrons and forms aluminium atoms .

23
Q

Why is aluminium ions attracted to the negative elctorde

A

As aluminium ions are metals so are positively charged so are atracted to the negative electrode as opposites attract and gain three electrons ,

24
Q

where are oxide ions attracted to in alumnium oxide

A

02- ions are attracted to the anode (positive terminal)

25
what is the half equation at the anode for aluminium oxide . What type or reaction is it and why
202-4e-arrowO2 it is oxidation as the oxide ions loses two electrons to form an oxygen atom .
26
Why must the anode be replaced regularly | wrtie the equation for this .
as the oxygen molecules produced at the anode react with the graphite (carbon) , forming C02 gas . c+02arrow co2
27
why do u need to double everything at the anode for aluminium oxide
as oxygen atoms at the anode pair up up to form oxygen molecules .
28
give two reasons why electrolysis is expensive
- Melting the compounds such as aluminium oxide requires a great deal of energy . - A lot of energy is required to produce the electric current .
29
Meaning of aqueous solutions
dissolved in water
30
water molecules ionise (split) forming what ?
hydrogen ions H+ | and hyrdoxide ions OH-
31
what is the formula for Copper sulfate solution
CuSO4(aq)
32
what does CuSO4 split into
CU2+ SO42- and H+ -hydrogen ions and OH- hydroxide ions because aqueous
33
What are the two possible things that can be produced at the cathode for copper sulfate solution .
Cu2+ | or H+
34
which one is porduced at the cathode at copper sulfate solution and why .
Hydrogen is produced at the cathode if the metal is more reactive than hydrogen . Copper is less reactive than hydrogen os i produced
35
What is produced at the anode for copper sulfate solution
oxygen gas , usually , when carrying out electrolysis on an aqueous solution , we usually get oxygen produced at the anode .
36
Why should electrodes be inert
As it is important that electrodes do notg react witht he chemicals that were making an electrolysis .
37
what is the meaning of inert
do not react .
38
what material is often used as inert electrodes and why
platinum is ofen used as inert electrodes as platinum is a very unreactive material .
39
What is the half equation at the cathode for copper sulfate solution
Cu2+ +2e- ---> Cu
40
what type of reaction is at the cathode for copper sulfate solution and why
it is a reduction as copper ions gain 2 electrons to become copper attoms .
41
what is the half equation for the anode for copper sulfate solution and why . What type of reaction is it ?
40H----> 02+ 2H20 + 4e- | hydroxide ions react to make oxygen and water and use 4 electrons in the process so it is an OXIDATION REACTION .
42
What is the formula for sodium chloride
NaCl
43
what two ions is sodium chloride made up of
Na+ sodium ions and Cl- and chloride ions and H+-hrdogen ions and OH- hydroxide ions as it is in an aqueous solution .
44
What are the two potential discharges at the cathode for sodium chloride
Na+ sodium ions | H+ hydrogen ions
45
What is produced at the cathode for sodium chloride
Hydrogen is prooduced at the cathode if the metal is more reactive than hydrogen . Sodium is MORE reactive than hydrogen so HYDROGEN is produced at the CATHODE
46
What are the two potential discharges at the anode for sodium chloride
Cl- chlorine ions | OH- hydroxide ions
47
what is produced at the anode for sodium chloride
If the aqueous solution contains halide ions (Cl-,Br-,I-) then the halogen will be produced at the anode otherwise oxyegn .As the sodium chloride contains chloride ions , CHLORINE GAS will be produced at the ANODE .
48
What is thehalf equation and reaction at the cathode for sodium chloride
2H+ + 2e ---> H2 The hydrogen ion is gaining one electron to become a hyrdogen atom so is a REDUCTION . However hydrogen atoms pair to make hydrogen molecules so everything doubles .
49
What is the half equation and reaction at the anode for sodium chloride
2CL- --->cL2 +2e- The chloride ion looses one electron to form a chloride atom so it is an OXIDATION , however , chlorine atoms pair to form chlorine molecules so everything doubles .
50
what is a positively charged ion called
cation
51
what is a negatively charged ion called
anion