C6 - Chemistry Out There Flashcards
C6 - Chemistry Out There
What is reduction?
Gain of electrons
C6 - Chemistry Out There
What does an oxidising agent do?
Accept electrons and gets reduced
C6 - Chemistry Out There
What does a reducing agent do?
Donate electrons and get oxidised
C6 - Chemistry Out There
What does displacement reactions involve?
One metal kicking another one out of a compound
C6 - Chemistry Out There
What is the rule for displacement reactions?
A more reactive metal will displace a less reactive metal from its compound
C6 - Chemistry Out There
Why do some iron and steels rust?
When they come into contact with air and water
C6 - Chemistry Out There
When does rusting of iron only occur?
When iron is in contact with both water and oxygen
C6 - Chemistry Out There
What is rust a form of?
Hydrated iron (III) oxide
C6 - Chemistry Out There
What is the equation for rusting?
Iron + oxygen + water -> hydrated iron (III) oxide
C6 - Chemistry Out There
What type of reaction is rusting of iron?
Redox
C6 - Chemistry Out There
What happens to iron when it reacts with oxygen?
Loses electrons - oxidised. Each Fe atom loses 3 electrons to become Fe3+.
C6 - Chemistry Out There
What happens to oxygen when it reacts with iron?
Reduced. Each O atom gains 2 electrons to become O2-.
C6 - Chemistry Out There
What are the 4 ways to prevent rusting?
Make alloys. Barrier. Tin coating/plating. More reactive metals (galvanising)
C6 - Chemistry Out There
What are steels alloys of?
Iron with carbon and small quantities of other metals
C6 - Chemistry Out There
What is stainless steel?
One of most common steels - rustproof alloy of iron, carbon and chromium.
C6 - Chemistry Out There
How does a barrier prevent rusting?
Keeps out water, oxygen or both.
C6 - Chemistry Out There
How is painting ideal to prevent rusting?
Ideal for large and small structures. Nice and colourful.
C6 - Chemistry Out There
How is oiling or greasing used to prevent rusting?
Has to be used when moving parts are involved e.g. Bike chains
C6 - Chemistry Out There
What is tin plating?
A coat of tin is applied to the object e.g. Food cans.
C6 - Chemistry Out There
How does tin plating prevent rusting?
Acts as a barrier, stopping water and oxygen from reaching iron surface.
C6 - Chemistry Out There
Tin plating only as long as…
Tin remains intact. If scratched, iron will lose electrons and rust even faster.
C6 - Chemistry Out There
Why is it not always a good idea to buy reduced bashed tins?
They could be starting to rust.
C6 - Chemistry Out There
How does the sacrificial method work?
Place a more reactive metal with the iron. Water and oxygen react with the sacrificial metal instead of iron.
C6 - Chemistry Out There
What is galvanising?
A coat of zinc put on object. Zinc is sacrificial protection - more reactive - loses electrons in preference to iron.
C6 - Chemistry Out There
What sort of items are galvanised?
Steel buckets and corrugated iron roofing
C6 - Chemistry Out There
How can blocks of metal prevent rusting?
E.g. Magnesium can be bolted onto iron. Magnesium loses electrons in preference to iron.
C6 - Chemistry Out There
When are block of metal used on items?
Hulls of ships and underground iron pipes.
C6 - Chemistry Out There
What is oxidation?
Loss of electrons
C6 - Chemistry Out There
What does electrolysis mean?
Breaking down a substance with electricity
C6 - Chemistry Out There
How does electrolysis work?
Electric current passed through a molten or dissolved ionic compound, causing it to decompose. This creates a flow of charge through the electrolyte.
C6 - Chemistry Out There
What happens to the positive ions in electrolysis?
Move towards the cathode (-ve) and gain electrons.
C6 - Chemistry Out There
What happens to negative ions in electrolysis?
Move towards anode (+ve) and lose electrons
C6 - Chemistry Out There
What happens in electrolysis when ions lose or gain electrons?
They become atoms or molecules and are discharged from the solution at the electrodes.
C6 - Chemistry Out There
What is the ionic equation at the anode during electrolysis of copper (II) sulfate?
4OH- - 4e- → O2 + 2H2O
C6 - Chemistry Out There
What is the ionic equation at the cathode during electrolysis of copper (II) sulfate?
Cu2+ + 2e- → Cu
C6 - Chemistry Out There
What are ions are there in aqueous solutions?
Hydrogen ions (H+), hydroxide ions (OH-) and ions from the solute (ionic compounds)
C6 - Chemistry Out There
What is it sometimes easier to do in electrolysis?
Discharge ions from the water instead of from the solute
C6 - Chemistry Out There
What does discharging ions from the water instead of the solute do in electrolysis?
Produce hydrogen at the cathode and oxygen at the anode.
C6 - Chemistry Out There
What ions does a solution of aqueous sulfuric acid contain?
SO42- , H+ , OH-
C6 - Chemistry Out There
What is the equation at the cathode for electrolysis with sulfuric acid?
2H+ + 2e- → H2
C6 - Chemistry Out There
What is the equation at the anode for electrolysis with sulfuric acid?
4OH- - 4e- → O2 + 2H2O
C6 - Chemistry Out There
What reaction takes place at the anode?
Oxidation
C6 - Chemistry Out There
What reaction takes place at the cathode?
Reduction
C6 - Chemistry Out There
Where is hydrogen produced in electrolysis?
Cathode
C6 - Chemistry Out There
Where is oxygen produced in electrolysis?
Anode
C6 - Chemistry Out There
What is the reaction at the cathode for the electrolysis of copper(II) sulfate solution?
Cu2+ + 2e- → Cu
C6 - Chemistry Out There
What is the reaction at the anode for the electrolysis of copper(II) sulfate solution?
4OH- - 4e- -> O2 + 2H2O
C6 - Chemistry Out There
What charge does the cathode have?
Negative
C6 - Chemistry Out There
What charge does the anode have?
Positive
C6 - Chemistry Out There
What happens when chlorine gas is passed through a solution of iron(II) salt?
Solution turns from green to yellow
C6 - Chemistry Out There
Why does the solution change colour when chlorine gas is passed through a solution of iron(II) salt?
Iron (II) ion is oxidised to iron (III). Fe2+ ion loses an electron to form Fe3+
C6 - Chemistry Out There
What causes the reaction to oxidise and turn a different colour when chlorine gas is passed through a solution of iron(II) salt?
Oxidising agent - chlorine gas
C6 - Chemistry Out There
What must be the reducing agent when chlorine gas is passed through a solution of iron(II) salt?
Iron (II) ion
C6 - Chemistry Out There
What happens to the chlorine when chlorine gas is passed through a solution of iron(II) salt?
Chlorine gains the electron Fe2+ lost. Chlorine reduced.
C6 - Chemistry Out There
When iron atoms are reacted with dilute acid how are iron (II) ions formed?
When iron atoms are oxidised.
C6 - Chemistry Out There
When iron atoms are reacted with dilute acid what happens to the iron atoms?
Lose electrons - oxidised by hydrogen ions
C6 - Chemistry Out There
When iron atoms are reacted with dilute acid what happens to the hydrogen atoms?
Gain electrons - reduced by iron atoms.
C6 - Chemistry Out There
What is the order of reactivity for zinc, iron, magnesium and tin/copper from most reactive to least reactive?
Magnesium, zinc, iron, tin/copper.
C6 - Chemistry Out There
What happens to metal ions in displacement reactions?
Gain electrons - are reduced
C6 - Chemistry Out There
What happens to the metal atoms in displacement reactions?
Loses electrons - are oxidised
C6 - Chemistry Out There
What happens between hard water and soap?
Doesn’t lather. Makes scum
C6 - Chemistry Out There
What do you need to do to get a good lather with hard water?
Add more soap, use softer water.
C6 - Chemistry Out There
What does hard water form on pipes/kettles/boilers?
Limescale (calcium carbonate)
C6 - Chemistry Out There
What does limescale act as?
Thermal insulator
C6 - Chemistry Out There
How is a kettle with limescale different to a clean kettle?
Kettle with limescale in heating element will take longer to boil.
C6 - Chemistry Out There
What can limescale eventually do to pipes?
Block them
C6 - Chemistry Out There
What does hard water contain?
Calcium ions (Ca2+), magnesium ions (Mg2+), or both.
C6 - Chemistry Out There
What happens as water flows over rocks and through soil?
The soils/rocks contain Ca and Mg compounds - these ions dissolve in the water.
C6 - Chemistry Out There
What does magnesium sulfate dissolve in?
Water
C6 - Chemistry Out There
What does calcium carbonate commonly exist as?
Chalk, limestone and marble.
C6 - Chemistry Out There
Does calcium carbonate dissolve in water?
No but reacts with acids.
C6 - Chemistry Out There
How do we know rainwater is slightly acidic?
Carbon dioxide from air dissolves in rainwater forming carbonic acid.
C6 - Chemistry Out There
What is the word equation when rainwater reacts with carbon dioxide?
Carbon dioxide + water → carbonic acid
C6 - Chemistry Out There
What is the symbol equation when rainwater reacts with carbon dioxide?
CO2 + H2O -> H2CO3
C6 - Chemistry Out There
What is the molecular formula of carbonic acid?
H2CO3
C6 - Chemistry Out There
What can rainwater react with to form calcium hydrogencarbonate?
Calcium carbonate
C6 - Chemistry Out There
What is the word equation for producing calcium hydrogencarbonate?
Carbon dioxide + water + calcium carbonate → calcium hydrogencarbonate
C6 - Chemistry Out There
What is the symbol equation for producing calcium hydrogencarbonate?
H2CO3 + CaCO3 → Ca(HCO3)2
C6 - Chemistry Out There
What are the two types of hardness?
Temporary and permanent
C6 - Chemistry Out There
What is temporary hardness caused by?
Hydrogencarbonate ion (HCO3-) in Ca(HCO3)2
C6 - Chemistry Out There
What is permanent hardness caused by?
Dissolved calcium sulfate (amongst other things)
C6 - Chemistry Out There
How is temporary hardness removed?
By boiling
C6 - Chemistry Out There
What does boiling do to temporary hardness?
Calcium hydrogencarbonate decomposes to form insoluble calcium carbonate.
C6 - Chemistry Out There
Why doesn’t boiling remove permanent hardness?
Calcium carbonate precipitate (limescale) is insoluble
C6 - Chemistry Out There
What is the word equation for removing temporary hardness?
Calcium hydrogencarbonate → calcium carbonate + water + carbon dioxide
C6 - Chemistry Out There
What is the symbol equation for removing temporary hardness?
Ca(HCO3)2 (aq) → CaCO3 (s) + H2O (l) + CO2 (g)
C6 - Chemistry Out There
How can bot types of hardness be removed?
Using washing soda (sodium carbonate, NaCO3) or by ‘ion exchange resin’.
C6 - Chemistry Out There
How does NaCO3 remove both types of hardness?
Carbonate ions join to calcium ions to make insoluble precipitate of calcium carbonate. Works whether hardness is due to calcium sulfate or calcium hydrogencarbonate.
C6 - Chemistry Out There
What is the ionic equation for removing hardness with sodium carbonate?
Ca2+ (aq) + CO32- (aq) → CaCO3 (s)
C6 - Chemistry Out There
How does ‘ion exchange resin work’?
Lots of sodium ions (or hydrogen ions) and these are exchanged for calcium or magnesium ions.
C6 - Chemistry Out There
What is the method for comparing the hardness of water samples?
- 100cm3 of water - conical flask
- Add 1cm3 of soap solution. Bung in and shake.
- Repeat until lasting lather formed (bubbles cover surface for at least 30 secs)
- Record amount of soap needed.
C6 - Chemistry Out There
Gain of electrons
What is reduction?
C6 - Chemistry Out There
Accept electrons and gets reduced
What does an oxidising agent do?
C6 - Chemistry Out There
Donate electrons and get oxidised
What does a reducing agent do?
C6 - Chemistry Out There
One metal kicking another one out of a compound
What does displacement reactions involve?
C6 - Chemistry Out There
A more reactive metal will displace a less reactive metal from its compound
What is the rule for displacement reactions?
C6 - Chemistry Out There
When they come into contact with air and water
Why do some iron and steels rust?
C6 - Chemistry Out There
When iron is in contact with both water and oxygen
When does rusting of iron only occur?
C6 - Chemistry Out There
Hydrated iron (III) oxide
What is rust a form of?
C6 - Chemistry Out There
Iron + oxygen + water -> hydrated iron (III) oxide
What is the equation for rusting?
C6 - Chemistry Out There
Redox
What type of reaction is rusting of iron?
C6 - Chemistry Out There
Loses electrons - oxidised. Each Fe atom loses 3 electrons to become Fe3+.
What happens to iron when it reacts with oxygen?
C6 - Chemistry Out There
Reduced. Each O atom gains 2 electrons to become O2-.
What happens to oxygen when it reacts with iron?
C6 - Chemistry Out There
Make alloys. Barrier. Tin coating/plating. More reactive metals (galvanising)
What are the 4 ways to prevent rusting?
C6 - Chemistry Out There
Iron with carbon and small quantities of other metals
What are steels alloys of?
C6 - Chemistry Out There
One of most common steels - rustproof alloy of iron, carbon and chromium.
What is stainless steel?
C6 - Chemistry Out There
Keeps out water, oxygen or both.
How does a barrier prevent rusting?
C6 - Chemistry Out There
Ideal for large and small structures. Nice and colourful.
How is painting ideal to prevent rusting?
C6 - Chemistry Out There
Has to be used when moving parts are involved e.g. Bike chains
How is oiling or greasing used to prevent rusting?
C6 - Chemistry Out There
A coat of tin is applied to the object e.g. Food cans.
What is tin plating?
C6 - Chemistry Out There
Acts as a barrier, stopping water and oxygen from reaching iron surface.
How does tin plating prevent rusting?
C6 - Chemistry Out There
Tin remains intact. If scratched, iron will lose electrons and rust even faster.
Tin plating only as long as…
C6 - Chemistry Out There
They could be starting to rust.
Why is it not always a good idea to buy reduced bashed tins?
C6 - Chemistry Out There
Place a more reactive metal with the iron. Water and oxygen react with the sacrificial metal instead of iron.
How does the sacrificial method work?
C6 - Chemistry Out There
A coat of zinc put on object. Zinc is sacrificial protection - more reactive - loses electrons in preference to iron.
What is galvanising?
C6 - Chemistry Out There
Steel buckets and corrugated iron roofing
What sort of items are galvanised?
C6 - Chemistry Out There
E.g. Magnesium can be bolted onto iron. Magnesium loses electrons in preference to iron.
How can blocks of metal prevent rusting?
C6 - Chemistry Out There
Hulls of ships and underground iron pipes.
When are block of metal used on items?
C6 - Chemistry Out There
Loss of electrons
What is oxidation?
C6 - Chemistry Out There
Breaking down a substance with electricity
What does electrolysis mean?
C6 - Chemistry Out There
Electric current passed through a molten or dissolved ionic compound, causing it to decompose. This creates a flow of charge through the electrolyte.
How does electrolysis work?
C6 - Chemistry Out There
Move towards the cathode (-ve) and gain electrons.
What happens to the positive ions in electrolysis?
C6 - Chemistry Out There
Move towards anode (+ve) and lose electrons
What happens to negative ions in electrolysis?
C6 - Chemistry Out There
They become atoms or molecules and are discharged from the solution at the electrodes.
What happens in electrolysis when ions lose or gain electrons?
C6 - Chemistry Out There
4OH- - 4e- → O2 + 2H2O
What is the ionic equation at the anode during electrolysis of copper (II) sulfate?
C6 - Chemistry Out There
Cu2+ + 2e- → Cu
What is the ionic equation at the cathode during electrolysis of copper (II) sulfate?
C6 - Chemistry Out There
Hydrogen ions (H+), hydroxide ions (OH-) and ions from the solute (ionic compounds)
What are ions are there in aqueous solutions?
C6 - Chemistry Out There
Discharge ions from the water instead of from the solute
What is it sometimes easier to do in electrolysis?
C6 - Chemistry Out There
Produce hydrogen at the cathode and oxygen at the anode.
What does discharging ions from the water instead of the solute do in electrolysis?
C6 - Chemistry Out There
SO42- , H+ , OH-
What ions does a solution of aqueous sulfuric acid contain?
C6 - Chemistry Out There
2H+ + 2e- → H2
What is the equation at the cathode for electrolysis with sulfuric acid?
C6 - Chemistry Out There
4OH- - 4e- → O2 + 2H2O
What is the equation at the anode for electrolysis with sulfuric acid?
C6 - Chemistry Out There
Oxidation
What reaction takes place at the anode?
C6 - Chemistry Out There
Reduction
What reaction takes place at the cathode?
C6 - Chemistry Out There
Cathode
Where is hydrogen produced in electrolysis?
C6 - Chemistry Out There
Anode
Where is oxygen produced in electrolysis?
C6 - Chemistry Out There
Cu2+ + 2e- → Cu
What is the reaction at the cathode for the electrolysis of copper(II) sulfate solution?
C6 - Chemistry Out There
4OH- - 4e- -> O2 + 2H2O
What is the reaction at the anode for the electrolysis of copper(II) sulfate solution?
C6 - Chemistry Out There
Negative
What charge does the cathode have?
C6 - Chemistry Out There
Positive
What charge does the anode have?
C6 - Chemistry Out There
Solution turns from green to yellow
What happens when chlorine gas is passed through a solution of iron(II) salt?
C6 - Chemistry Out There
Iron (II) ion is oxidised to iron (III). Fe2+ ion loses an electron to form Fe3+
Why does the solution change colour when chlorine gas is passed through a solution of iron(II) salt?
C6 - Chemistry Out There
Oxidising agent - chlorine gas
What causes the reaction to oxidise and turn a different colour when chlorine gas is passed through a solution of iron(II) salt?
C6 - Chemistry Out There
Iron (II) ion
What must be the reducing agent when chlorine gas is passed through a solution of iron(II) salt?
C6 - Chemistry Out There
Chlorine gains the electron Fe2+ lost. Chlorine reduced.
What happens to the chlorine when chlorine gas is passed through a solution of iron(II) salt?
C6 - Chemistry Out There
When iron atoms are oxidised.
When iron atoms are reacted with dilute acid how are iron (II) ions formed?
C6 - Chemistry Out There
Lose electrons - oxidised by hydrogen ions
When iron atoms are reacted with dilute acid what happens to the iron atoms?
C6 - Chemistry Out There
Gain electrons - reduced by iron atoms.
When iron atoms are reacted with dilute acid what happens to the hydrogen atoms?
C6 - Chemistry Out There
Magnesium, zinc, iron, tin/copper.
What is the order of reactivity for zinc, iron, magnesium and tin/copper from most reactive to least reactive?
C6 - Chemistry Out There
Gain electrons - are reduced
What happens to metal ions in displacement reactions?
C6 - Chemistry Out There
Loses electrons - are oxidised
What happens to the metal atoms in displacement reactions?
C6 - Chemistry Out There
Doesn’t lather. Makes scum
What happens between hard water and soap?
C6 - Chemistry Out There
Add more soap, use softer water.
What do you need to do to get a good lather with hard water?
C6 - Chemistry Out There
Limescale (calcium carbonate)
What does hard water form on pipes/kettles/boilers?
C6 - Chemistry Out There
Thermal insulator
What does limescale act as?
C6 - Chemistry Out There
Kettle with limescale in heating element will take longer to boil.
How is a kettle with limescale different to a clean kettle?
C6 - Chemistry Out There
Block them
What can limescale eventually do to pipes?
C6 - Chemistry Out There
Calcium ions (Ca2+), magnesium ions (Mg2+), or both.
What does hard water contain?
C6 - Chemistry Out There
The soils/rocks contain Ca and Mg compounds - these ions dissolve in the water.
What happens as water flows over rocks and through soil?
C6 - Chemistry Out There
Water
What does magnesium sulfate dissolve in?
C6 - Chemistry Out There
Chalk, limestone and marble.
What does calcium carbonate commonly exist as?
C6 - Chemistry Out There
No but reacts with acids.
Does calcium carbonate dissolve in water?
C6 - Chemistry Out There
Carbon dioxide from air dissolves in rainwater forming carbonic acid.
How do we know rainwater is slightly acidic?
C6 - Chemistry Out There
Carbon dioxide + water → carbonic acid
What is the word equation when rainwater reacts with carbon dioxide?
C6 - Chemistry Out There
CO2 + H2O -> H2CO3
What is the symbol equation when rainwater reacts with carbon dioxide?
C6 - Chemistry Out There
H2CO3
What is the molecular formula of carbonic acid?
C6 - Chemistry Out There
Calcium carbonate
What can rainwater react with to form calcium hydrogencarbonate?
C6 - Chemistry Out There
Carbon dioxide + water + calcium carbonate → calcium hydrogencarbonate
What is the word equation for producing calcium hydrogencarbonate?
C6 - Chemistry Out There
H2CO3 + CaCO3 → Ca(HCO3)2
What is the symbol equation for producing calcium hydrogencarbonate?
C6 - Chemistry Out There
Temporary and permanent
What are the two types of hardness?
C6 - Chemistry Out There
Hydrogencarbonate ion (HCO3-) in Ca(HCO3)2
What is temporary hardness caused by?
C6 - Chemistry Out There
Dissolved calcium sulfate (amongst other things)
What is permanent hardness caused by?
C6 - Chemistry Out There
By boiling
How is temporary hardness removed?
C6 - Chemistry Out There
Calcium hydrogencarbonate decomposes to form insoluble calcium carbonate.
What does boiling do to temporary hardness?
C6 - Chemistry Out There
Calcium carbonate precipitate (limescale) is insoluble
Why doesn’t boiling remove permanent hardness?
C6 - Chemistry Out There
Calcium hydrogencarbonate → calcium carbonate + water + carbon dioxide
What is the word equation for removing temporary hardness?
C6 - Chemistry Out There
Ca(HCO3)2 (aq) → CaCO3 (s) + H2O (l) + CO2 (g)
What is the symbol equation for removing temporary hardness?
C6 - Chemistry Out There
Using washing soda (sodium carbonate, NaCO3) or by ‘ion exchange resin’.
How can bot types of hardness be removed?
C6 - Chemistry Out There
Carbonate ions join to calcium ions to make insoluble precipitate of calcium carbonate. Works whether hardness is due to calcium sulfate or calcium hydrogencarbonate.
How does NaCO3 remove both types of hardness?
C6 - Chemistry Out There
Ca2+ (aq) + CO32- (aq) → CaCO3 (s)
What is the ionic equation for removing hardness with sodium carbonate?
C6 - Chemistry Out There
Lots of sodium ions (or hydrogen ions) and these are exchanged for calcium or magnesium ions.
How does ‘ion exchange resin work’?
C6 - Chemistry Out There
- 100cm3 of water - conical flask
- Add 1cm3 of soap solution. Bung in and shake.
- Repeat until lasting lather formed (bubbles cover surface for at least 30 secs)
- Record amount of soap needed.
What is the method for comparing the hardness of water samples?