C6 - Chemistry Out There Flashcards
C6 - Chemistry Out There
What is reduction?
Gain of electrons
C6 - Chemistry Out There
What does an oxidising agent do?
Accept electrons and gets reduced
C6 - Chemistry Out There
What does a reducing agent do?
Donate electrons and get oxidised
C6 - Chemistry Out There
What does displacement reactions involve?
One metal kicking another one out of a compound
C6 - Chemistry Out There
What is the rule for displacement reactions?
A more reactive metal will displace a less reactive metal from its compound
C6 - Chemistry Out There
Why do some iron and steels rust?
When they come into contact with air and water
C6 - Chemistry Out There
When does rusting of iron only occur?
When iron is in contact with both water and oxygen
C6 - Chemistry Out There
What is rust a form of?
Hydrated iron (III) oxide
C6 - Chemistry Out There
What is the equation for rusting?
Iron + oxygen + water -> hydrated iron (III) oxide
C6 - Chemistry Out There
What type of reaction is rusting of iron?
Redox
C6 - Chemistry Out There
What happens to iron when it reacts with oxygen?
Loses electrons - oxidised. Each Fe atom loses 3 electrons to become Fe3+.
C6 - Chemistry Out There
What happens to oxygen when it reacts with iron?
Reduced. Each O atom gains 2 electrons to become O2-.
C6 - Chemistry Out There
What are the 4 ways to prevent rusting?
Make alloys. Barrier. Tin coating/plating. More reactive metals (galvanising)
C6 - Chemistry Out There
What are steels alloys of?
Iron with carbon and small quantities of other metals
C6 - Chemistry Out There
What is stainless steel?
One of most common steels - rustproof alloy of iron, carbon and chromium.
C6 - Chemistry Out There
How does a barrier prevent rusting?
Keeps out water, oxygen or both.
C6 - Chemistry Out There
How is painting ideal to prevent rusting?
Ideal for large and small structures. Nice and colourful.
C6 - Chemistry Out There
How is oiling or greasing used to prevent rusting?
Has to be used when moving parts are involved e.g. Bike chains
C6 - Chemistry Out There
What is tin plating?
A coat of tin is applied to the object e.g. Food cans.
C6 - Chemistry Out There
How does tin plating prevent rusting?
Acts as a barrier, stopping water and oxygen from reaching iron surface.
C6 - Chemistry Out There
Tin plating only as long as…
Tin remains intact. If scratched, iron will lose electrons and rust even faster.
C6 - Chemistry Out There
Why is it not always a good idea to buy reduced bashed tins?
They could be starting to rust.
C6 - Chemistry Out There
How does the sacrificial method work?
Place a more reactive metal with the iron. Water and oxygen react with the sacrificial metal instead of iron.
C6 - Chemistry Out There
What is galvanising?
A coat of zinc put on object. Zinc is sacrificial protection - more reactive - loses electrons in preference to iron.
C6 - Chemistry Out There
What sort of items are galvanised?
Steel buckets and corrugated iron roofing
C6 - Chemistry Out There
How can blocks of metal prevent rusting?
E.g. Magnesium can be bolted onto iron. Magnesium loses electrons in preference to iron.
C6 - Chemistry Out There
When are block of metal used on items?
Hulls of ships and underground iron pipes.
C6 - Chemistry Out There
What is oxidation?
Loss of electrons
C6 - Chemistry Out There
What does electrolysis mean?
Breaking down a substance with electricity
C6 - Chemistry Out There
How does electrolysis work?
Electric current passed through a molten or dissolved ionic compound, causing it to decompose. This creates a flow of charge through the electrolyte.
C6 - Chemistry Out There
What happens to the positive ions in electrolysis?
Move towards the cathode (-ve) and gain electrons.
C6 - Chemistry Out There
What happens to negative ions in electrolysis?
Move towards anode (+ve) and lose electrons
C6 - Chemistry Out There
What happens in electrolysis when ions lose or gain electrons?
They become atoms or molecules and are discharged from the solution at the electrodes.
C6 - Chemistry Out There
What is the ionic equation at the anode during electrolysis of copper (II) sulfate?
4OH- - 4e- → O2 + 2H2O
C6 - Chemistry Out There
What is the ionic equation at the cathode during electrolysis of copper (II) sulfate?
Cu2+ + 2e- → Cu
C6 - Chemistry Out There
What are ions are there in aqueous solutions?
Hydrogen ions (H+), hydroxide ions (OH-) and ions from the solute (ionic compounds)
C6 - Chemistry Out There
What is it sometimes easier to do in electrolysis?
Discharge ions from the water instead of from the solute
C6 - Chemistry Out There
What does discharging ions from the water instead of the solute do in electrolysis?
Produce hydrogen at the cathode and oxygen at the anode.
C6 - Chemistry Out There
What ions does a solution of aqueous sulfuric acid contain?
SO42- , H+ , OH-
C6 - Chemistry Out There
What is the equation at the cathode for electrolysis with sulfuric acid?
2H+ + 2e- → H2
C6 - Chemistry Out There
What is the equation at the anode for electrolysis with sulfuric acid?
4OH- - 4e- → O2 + 2H2O
C6 - Chemistry Out There
What reaction takes place at the anode?
Oxidation
C6 - Chemistry Out There
What reaction takes place at the cathode?
Reduction
C6 - Chemistry Out There
Where is hydrogen produced in electrolysis?
Cathode
C6 - Chemistry Out There
Where is oxygen produced in electrolysis?
Anode
C6 - Chemistry Out There
What is the reaction at the cathode for the electrolysis of copper(II) sulfate solution?
Cu2+ + 2e- → Cu
C6 - Chemistry Out There
What is the reaction at the anode for the electrolysis of copper(II) sulfate solution?
4OH- - 4e- -> O2 + 2H2O
C6 - Chemistry Out There
What charge does the cathode have?
Negative
C6 - Chemistry Out There
What charge does the anode have?
Positive
C6 - Chemistry Out There
What happens when chlorine gas is passed through a solution of iron(II) salt?
Solution turns from green to yellow
C6 - Chemistry Out There
Why does the solution change colour when chlorine gas is passed through a solution of iron(II) salt?
Iron (II) ion is oxidised to iron (III). Fe2+ ion loses an electron to form Fe3+
C6 - Chemistry Out There
What causes the reaction to oxidise and turn a different colour when chlorine gas is passed through a solution of iron(II) salt?
Oxidising agent - chlorine gas
C6 - Chemistry Out There
What must be the reducing agent when chlorine gas is passed through a solution of iron(II) salt?
Iron (II) ion
C6 - Chemistry Out There
What happens to the chlorine when chlorine gas is passed through a solution of iron(II) salt?
Chlorine gains the electron Fe2+ lost. Chlorine reduced.
C6 - Chemistry Out There
When iron atoms are reacted with dilute acid how are iron (II) ions formed?
When iron atoms are oxidised.
C6 - Chemistry Out There
When iron atoms are reacted with dilute acid what happens to the iron atoms?
Lose electrons - oxidised by hydrogen ions
C6 - Chemistry Out There
When iron atoms are reacted with dilute acid what happens to the hydrogen atoms?
Gain electrons - reduced by iron atoms.
C6 - Chemistry Out There
What is the order of reactivity for zinc, iron, magnesium and tin/copper from most reactive to least reactive?
Magnesium, zinc, iron, tin/copper.
C6 - Chemistry Out There
What happens to metal ions in displacement reactions?
Gain electrons - are reduced
C6 - Chemistry Out There
What happens to the metal atoms in displacement reactions?
Loses electrons - are oxidised
C6 - Chemistry Out There
What happens between hard water and soap?
Doesn’t lather. Makes scum
C6 - Chemistry Out There
What do you need to do to get a good lather with hard water?
Add more soap, use softer water.
C6 - Chemistry Out There
What does hard water form on pipes/kettles/boilers?
Limescale (calcium carbonate)
C6 - Chemistry Out There
What does limescale act as?
Thermal insulator
C6 - Chemistry Out There
How is a kettle with limescale different to a clean kettle?
Kettle with limescale in heating element will take longer to boil.
C6 - Chemistry Out There
What can limescale eventually do to pipes?
Block them
C6 - Chemistry Out There
What does hard water contain?
Calcium ions (Ca2+), magnesium ions (Mg2+), or both.
C6 - Chemistry Out There
What happens as water flows over rocks and through soil?
The soils/rocks contain Ca and Mg compounds - these ions dissolve in the water.
C6 - Chemistry Out There
What does magnesium sulfate dissolve in?
Water
C6 - Chemistry Out There
What does calcium carbonate commonly exist as?
Chalk, limestone and marble.
C6 - Chemistry Out There
Does calcium carbonate dissolve in water?
No but reacts with acids.
C6 - Chemistry Out There
How do we know rainwater is slightly acidic?
Carbon dioxide from air dissolves in rainwater forming carbonic acid.