C2 - Chemical Resources Flashcards
C2 - Chemical Resources
What is the crust?
The Earth’s outer layer of solid rock. Average depth of 20km
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What is the lithosphere?
It includes the crust and upper part of the mantle. It is made up of a jigsaw of tectonic plates and is cold and rigid - over 100km thick in places.
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What is the mantle?
Solid section between the crust and core. Very rigid and temperature increases. Becomes less rigid and flows very slowly - semi liquid.
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What is the core?
It is just over half the Earth’s radius. 2 parts - inner core (solid) and outer core (liquid).
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What causes tectonic plates to move?
Radioactive decay creates lots of heat which creates convection currents in the mantle, causing the plates of the lithosphere to move.
C2 - Chemical Resources
What are tectonic plates?
Big rocky rafts that float on the mantle because they are less dense. Move very slowly - about 2.5cm per year.
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What can tectonic plates cause?
Earthquakes and volcanoes where the plates meet, caused by movement of the plates against each other.
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Why is it difficult to study the Earth’s inner structure?
The crust is too thick to drill through.
C2 - Chemical Resources
How can scientists study the Earth’s structure?
Using seismic waves produced by earthquakes or man made explosions. Measure the time it takes for them to travel through the Earth and where they are detected.
C2 - Chemical Resources
What are the two types of seismic wave?
P-Waves which can only travel through solids and liquids. S-Waves can only travel through solids.
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How are volcanoes formed?
As an oceanic plate is forced down, it melts and starts to rise. Molten rock (magma) from the mantle emerges through crust and boils over - sometimes violently.
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Which plate is denser?
Oceanic plate
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What is subduction?
When tectonic plates collide a dense oceanic plate is forced under a less dense continental plate.
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Which igneous rock is formed from volcanoes with runny lava and a fairly safe eruption?
Iron-rich basalt
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Which igneous rock is formed from volcanoes with thick lava and an explosive eruption?
Silica-rich Rhyolite
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Why is it tricky to predict a volcanic eruption?
Volcanoes are unpredictable - scientists may only be able to say an eruption is more likely, not certain.
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How are sedimentary rocks formed?
Layers of sediment laid down in lakes or seas which get buried over millions of years, squeezing out the water. Fluid flowing through pores deposit natural mineral cement.
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What is the word equation for thermal decomposition of limestone?
calcium carbonate → calcium oxide + carbon dioxide
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What is the symbol equation for thermal decomposition of limestone?
CaCO₃ → CaO + CO₂
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How are metamorphic rocks formed?
Heat and pressure on sedimentary or igneous rocks over a long time. As long as they don’t melt they are metamorphic.
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What is an example of a metamorphic rock?
Marble - formed from limestone. The heat and pressure breaks down limestone so it reforms as small crystals making marble harder and it has more texture.
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Why are ignous rocks very hard?
They contain different minerals in randomly arranged interlocking crystals.
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What is an example of an igneous rock?
Granite - ideal for steps and buildings
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How are aluminium and iron made?
They are extracted from their ores.
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What is glass made from?
Heat up limestone (calcium carbonate), sand (silicon dioxide) and soda (sodium carbonate) until it melts.
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What are bricks made from?
Clay. It is initially soft when dug up but is hardened by very high temperatures.
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How can cement be made?
Powdered clay containing aluminium and silicates, and powdered limestone are roasted to make a complex mixture of calium and aluminium silicates.
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How is concrete made?
Cement is mixed with sand, aggregate (gavel) and water.
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What is reinforced concrete made of?
Concrete and solid steel supports - e.g. Steel rods. Because of this it is a composite material.
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Why is reinforced concrete a better construction material?
It combines the hardness of concrete with the flexibility and strength of steel.
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What are the environmental impacts of extracting rocks?
Quarrying uses land/destroys habitats and costs money to return it to new. Transporting rocks causes noise and pollution. Process produces dusta nd noise. Old sites are dangerous - disused mines are known to collapse (causing subsidence)
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What does electrolysis mean?
Splitting up with electricity
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What charge does the anode have?
Positive
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What charge does the cathode have?
Negative
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What is the reaction at the cathode for electrolysis of copper?
Cu²⁺ + 2e⁻ → Cu
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What is the reaction at the anode for electrolysis of copper?
Cu → Cu²⁺ + 2e⁻
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What type of reaction takes place at the cathode?
REDUCTION - electrons are gained
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What type of reaction takes place at the anode?
OXIDATION - electrons are lost
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Why is recycling copper better than extracting new?
Cheaper than mining and extracting from ores. Recycling uses 15% of the energy that extracting new requires.
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What are the issues with recycling copper?
It is difficult to convince people that the effort is worth it and for them to sort their rubbish. Sorting out the copper from other metals takes time and energy.
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What is an alloy?
A mixture of a metal other elements. They can can be two or more different metals or they can be mixture of a metal and non metal.
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What is steel?
An alloy of iron and carbon. It is harder and stronger than iron. Steel is less likely to rust whereas iron would.
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What is bronze an alloy of and what are its uses?
Copper and zinc. Brass is harder than either material alone and can be used in musical instruments and fixtures and fittings like screws.
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What is solder an alloy of and what are its uses?
Lead and tin - because it solidifies as it cools it is used to solder things together.
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What is amalgam an alloy of and what are its uses?
Mercury - a large scale use is in dentistry.
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What is nitinol?
The name given to a family of alloys of nickel and titanium that have shape memory.
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What alloy can be used to make spectacles?
Nitinol as the frames can be bent or sat on but still return to their normal shape.
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What is the word equation for the rusting of iron?
iron + oxygen + water → hydrated iron (III) oxide
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What factors increase the reaction in the rusting of iron?
If the water is acidic or salty.
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Why doesn’t aluminium corrode?
It reacts very quickly with oxygen in the air to form aluminium oxide which becomes a protective layer stopping any more reaction taking place.
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What are the advantages of aluminium over steel?
It has a lower density, making the car lighter and giving a better fuel economy. Also it corrodes less so will have a longer lifetime.
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What is the disadvantage of using aluminium to make car bodies?
It is much more expensive than iron or steel.
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What part of a car is steel good for?
Bodywork because it is strong and can be hammered into sheets and welded together.
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What part of a car is aluminium good for?
Parts of the engine - it is strong and low density so using it reduces the overall weight.
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What part of a car is glass good for?
Its transparency is used in the windscreens and windows.
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What part of a car is plastic good for?
It is light and hard wearing, making it useful for internal coverings on doors and dashboards. Also as electrical insulators on wires.
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What part of a car are fibres good for?
Natural and synthetic are hard wearing and are used to cover the seats and floor.
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What is the European Law for recycling cars?
85% of the materials in a car must be recyclable - rising to 95% by 2015
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What is the biggest problem with recycling cars?
All the non-metal parts must be separated before they are recycled.
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Describe universal indicator…
A combination of dyes that changes colour gradually as the pH changes.
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What is phenolphthalein an example of?
A sudden change indicator - it goes from colourless to pink when the pH rises above 8.
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What is an acid?
A substance with a pH less than 7. Acids form H⁺ ions in water.
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What is pH a measure of?
The concentration of H⁺ ions
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What is a base?
A substance with a pH over 7 and is soluble in water. They form OH⁻ ions in water.
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What is the word equation for neutralisation?
acid + base → salt + water
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What is the ionic equation for neutralisation?
H⁺ + OH⁻ ⇌ H₂O
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What are the word equations for metal oxides/hydroxides?
acid + metal oxide/hydroxide → salt + water
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Complete: acid + carbonate…
→ salt + water + carbon dioxide
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What is the word equation for acids and ammonia?
Acid + ammonia → ammonium salt
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What are the 3 essential elements in fertilisers and what are they needed for?
Nitrogen - making proteins (amino acids) Phosphorous - respiration and growth Potassium - helps enzymes needed for photosynthesis and respiration.
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What must a fertiliser be able to do in order to be taken up by roots?
dissolve in water
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Give 4 examples of fertilisers…
Ammonium nitrate, ammonium sulfate, ammonium phosphate, potassium nitrate.
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What is the issue with fertilisers?
Eutrophication
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What is eutrophication?
Fertilisers run off into rivers and streams, increasing levels of nitrates and phosphates. Algae uses these nutrients to multiply rapidly - algael bloom, blocking off sunlight to plants meaning they die. Aerobic bacteria which eats dead plants multiply and use all oxygen, killing fish and insects.
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What does methyl orange indicator do?
Turns from yellow to red when alkali is neutralised (used in making ammonium nitrate)
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How is ammonium nitrate made?
Titration - methyl orange used. Nitric acid added to ammonia - goes from yellow to red. Evaporate solution until a little solution left - leave to crystallise. To get pure, note amount of acid needed and repeat but without indicator.
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What is the equation for the Haber process?
N₂ + 3H₂ ⇌ 2NH₃
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Where do the reactants for the Haber process come from?
Nitrogen - from the air (makes up 78% of air) Hydrogen - from cracking of oil fractions or natural gas
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What are the industrial conditions for making ammonia?
Pressure - High (200 atmospheres) Temperature - 450°C Catalyst - Iron
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Why is the pressure high in the Haber Process?
It favours the forward reaction and this high pressure increases the % yield of ammonia.
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Why is a high temperature used in the Haber process?
It favours the reverse reaction - so a high temperature decreases the % yield. 450 is optimum because it gives a fast reaction rate and a reasonable % yield (compromise).
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What happens to unused hydrogen and nitrogen when making ammonia?
It is recycled - so nothing is wasted.
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Why is an iron catalyst used in the Haber Process?
It makes the reaction go faster which gets it to its equilibrium proportions more quickly - but doesn’t affect the position of equilibrium or % yield.
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What are optimum conditions?
Those that give the lowest production costs.
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What 5 factors affect production cost?
Price of energy, cost of raw materials, labour costs/wages, plant costs (equipment), rate of production
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What is solution mining?
Pumping hot water underground which dissolves the salt and the salt solution is forced to the surface because of the water pressure.
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What is the issue with salt mining?
The holes must be filled in otherwise it will cause subsidence where the land collapses and slides in to the hole.
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What is produced in the electrolysis of brine?
Hydrogen gas, chlorine gas and sodium hydroxide.
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What is produced at the anode during the electrolysis of brine? (including half-equations)
Chlorine gas: 2Cl⁻ - 2e⁻ → Cl₂ OXIDATION
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What is produced at the cathode during the electrolysis of brine? (including half-equations)
Hydrogen gas: 2H⁺ + 2e⁻ → H₂ REDUCTION
C2 - Chemical Resources
The Earth’s outer layer of solid rock. Average depth of 20km
What is the crust?
C2 - Chemical Resources
It includes the crust and upper part of the mantle. It is made up of a jigsaw of tectonic plates and is cold and rigid - over 100km thick in places.
What is the lithosphere?
C2 - Chemical Resources
Solid section between the crust and core. Very rigid and temperature increases. Becomes less rigid and flows very slowly - semi liquid.
What is the mantle?
C2 - Chemical Resources
It is just over half the Earth’s radius. 2 parts - inner core (solid) and outer core (liquid).
What is the core?
C2 - Chemical Resources
Radioactive decay creates lots of heat which creates convection currents in the mantle, causing the plates of the lithosphere to move.
What causes tectonic plates to move?
C2 - Chemical Resources
Big rocky rafts that float on the mantle because they are less dense. Move very slowly - about 2.5cm per year.
What are tectonic plates?
C2 - Chemical Resources
Earthquakes and volcanoes where the plates meet, caused by movement of the plates against each other.
What can tectonic plates cause?
C2 - Chemical Resources
The crust is too thick to drill through.
Why is it difficult to study the Earth’s inner structure?
C2 - Chemical Resources
Using seismic waves produced by earthquakes or man made explosions. Measure the time it takes for them to travel through the Earth and where they are detected.
How can scientists study the Earth’s structure?
C2 - Chemical Resources
P-Waves which can only travel through solids and liquids. S-Waves can only travel through solids.
What are the two types of seismic wave?
C2 - Chemical Resources
As an oceanic plate is forced down, it melts and starts to rise. Molten rock (magma) from the mantle emerges through crust and boils over - sometimes violently.
How are volcanoes formed?
C2 - Chemical Resources
Oceanic plate
Which plate is denser?
C2 - Chemical Resources
When tectonic plates collide a dense oceanic plate is forced under a less dense continental plate.
What is subduction?
C2 - Chemical Resources
Iron-rich basalt
Which igneous rock is formed from volcanoes with runny lava and a fairly safe eruption?
C2 - Chemical Resources
Silica-rich Rhyolite
Which igneous rock is formed from volcanoes with thick lava and an explosive eruption?
C2 - Chemical Resources
Volcanoes are unpredictable - scientists may only be able to say an eruption is more likely, not certain.
Why is it tricky to predict a volcanic eruption?
C2 - Chemical Resources
Layers of sediment laid down in lakes or seas which get buried over millions of years, squeezing out the water. Fluid flowing through pores deposit natural mineral cement.
How are sedimentary rocks formed?
C2 - Chemical Resources
calcium carbonate → calcium oxide + carbon dioxide
What is the word equation for thermal decomposition of limestone?
C2 - Chemical Resources
CaCO₃ → CaO + CO₂
What is the symbol equation for thermal decomposition of limestone?
C2 - Chemical Resources
Heat and pressure on sedimentary or igneous rocks over a long time. As long as they don’t melt they are metamorphic.
How are metamorphic rocks formed?
C2 - Chemical Resources
Marble - formed from limestone. The heat and pressure breaks down limestone so it reforms as small crystals making marble harder and it has more texture.
What is an example of a metamorphic rock?
C2 - Chemical Resources
They contain different minerals in randomly arranged interlocking crystals.
Why are ignous rocks very hard?
C2 - Chemical Resources
Granite - ideal for steps and buildings
What is an example of an igneous rock?
C2 - Chemical Resources
They are extracted from their ores.
How are aluminium and iron made?
C2 - Chemical Resources
Heat up limestone (calcium carbonate), sand (silicon dioxide) and soda (sodium carbonate) until it melts.
What is glass made from?
C2 - Chemical Resources
Clay. It is initially soft when dug up but is hardened by very high temperatures.
What are bricks made from?
C2 - Chemical Resources
Powdered clay containing aluminium and silicates, and powdered limestone are roasted to make a complex mixture of calium and aluminium silicates.
How can cement be made?
C2 - Chemical Resources
Cement is mixed with sand, aggregate (gavel) and water.
How is concrete made?
C2 - Chemical Resources
Concrete and solid steel supports - e.g. Steel rods. Because of this it is a composite material.
What is reinforced concrete made of?
C2 - Chemical Resources
It combines the hardness of concrete with the flexibility and strength of steel.
Why is reinforced concrete a better construction material?
C2 - Chemical Resources
Quarrying uses land/destroys habitats and costs money to return it to new. Transporting rocks causes noise and pollution. Process produces dusta nd noise. Old sites are dangerous - disused mines are known to collapse (causing subsidence)
What are the environmental impacts of extracting rocks?
C2 - Chemical Resources
Splitting up with electricity
What does electrolysis mean?
C2 - Chemical Resources
Positive
What charge does the anode have?
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Negative
What charge does the cathode have?
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Cu²⁺ + 2e⁻ → Cu
What is the reaction at the cathode for electrolysis of copper?
C2 - Chemical Resources
Cu → Cu²⁺ + 2e⁻
What is the reaction at the anode for electrolysis of copper?
C2 - Chemical Resources
REDUCTION - electrons are gained
What type of reaction takes place at the cathode?
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OXIDATION - electrons are lost
What type of reaction takes place at the anode?
C2 - Chemical Resources
Cheaper than mining and extracting from ores. Recycling uses 15% of the energy that extracting new requires.
Why is recycling copper better than extracting new?
C2 - Chemical Resources
It is difficult to convince people that the effort is worth it and for them to sort their rubbish. Sorting out the copper from other metals takes time and energy.
What are the issues with recycling copper?
C2 - Chemical Resources
A mixture of a metal other elements. They can can be two or more different metals or they can be mixture of a metal and non metal.
What is an alloy?
C2 - Chemical Resources
An alloy of iron and carbon. It is harder and stronger than iron. Steel is less likely to rust whereas iron would.
What is steel?
C2 - Chemical Resources
Copper and zinc. Brass is harder than either material alone and can be used in musical instruments and fixtures and fittings like screws.
What is bronze an alloy of and what are its uses?
C2 - Chemical Resources
Lead and tin - because it solidifies as it cools it is used to solder things together.
What is solder an alloy of and what are its uses?
C2 - Chemical Resources
Mercury - a large scale use is in dentistry.
What is amalgam an alloy of and what are its uses?
C2 - Chemical Resources
The name given to a family of alloys of nickel and titanium that have shape memory.
What is nitinol?
C2 - Chemical Resources
Nitinol as the frames can be bent or sat on but still return to their normal shape.
What alloy can be used to make spectacles?
C2 - Chemical Resources
iron + oxygen + water → hydrated iron (III) oxide
What is the word equation for the rusting of iron?
C2 - Chemical Resources
If the water is acidic or salty.
What factors increase the reaction in the rusting of iron?
C2 - Chemical Resources
It reacts very quickly with oxygen in the air to form aluminium oxide which becomes a protective layer stopping any more reaction taking place.
Why doesn’t aluminium corrode?
C2 - Chemical Resources
It has a lower density, making the car lighter and giving a better fuel economy. Also it corrodes less so will have a longer lifetime.
What are the advantages of aluminium over steel?
C2 - Chemical Resources
It is much more expensive than iron or steel.
What is the disadvantage of using aluminium to make car bodies?
C2 - Chemical Resources
Bodywork because it is strong and can be hammered into sheets and welded together.
What part of a car is steel good for?
C2 - Chemical Resources
Parts of the engine - it is strong and low density so using it reduces the overall weight.
What part of a car is aluminium good for?
C2 - Chemical Resources
Its transparency is used in the windscreens and windows.
What part of a car is glass good for?
C2 - Chemical Resources
It is light and hard wearing, making it useful for internal coverings on doors and dashboards. Also as electrical insulators on wires.
What part of a car is plastic good for?
C2 - Chemical Resources
Natural and synthetic are hard wearing and are used to cover the seats and floor.
What part of a car are fibres good for?
C2 - Chemical Resources
85% of the materials in a car must be recyclable - rising to 95% by 2015
What is the European Law for recycling cars?
C2 - Chemical Resources
All the non-metal parts must be separated before they are recycled.
What is the biggest problem with recycling cars?
C2 - Chemical Resources
A combination of dyes that changes colour gradually as the pH changes.
Describe universal indicator…
C2 - Chemical Resources
A sudden change indicator - it goes from colourless to pink when the pH rises above 8.
What is phenolphthalein an example of?
C2 - Chemical Resources
A substance with a pH less than 7. Acids form H⁺ ions in water.
What is an acid?
C2 - Chemical Resources
The concentration of H⁺ ions
What is pH a measure of?
C2 - Chemical Resources
A substance with a pH over 7 and is soluble in water. They form OH⁻ ions in water.
What is a base?
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acid + base → salt + water
What is the word equation for neutralisation?
C2 - Chemical Resources
H⁺ + OH⁻ ⇌ H₂O
What is the ionic equation for neutralisation?
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acid + metal oxide/hydroxide → salt + water
What are the word equations for metal oxides/hydroxides?
C2 - Chemical Resources
→ salt + water + carbon dioxide
Complete: acid + carbonate…
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Acid + ammonia → ammonium salt
What is the word equation for acids and ammonia?
C2 - Chemical Resources
Nitrogen - making proteins (amino acids) Phosphorous - respiration and growth Potassium - helps enzymes needed for photosynthesis and respiration.
What are the 3 essential elements in fertilisers and what are they needed for?
C2 - Chemical Resources
dissolve in water
What must a fertiliser be able to do in order to be taken up by roots?
C2 - Chemical Resources
Ammonium nitrate, ammonium sulfate, ammonium phosphate, potassium nitrate.
Give 4 examples of fertilisers…
C2 - Chemical Resources
Eutrophication
What is the issue with fertilisers?
C2 - Chemical Resources
Fertilisers run off into rivers and streams, increasing levels of nitrates and phosphates. Algae uses these nutrients to multiply rapidly - algael bloom, blocking off sunlight to plants meaning they die. Aerobic bacteria which eats dead plants multiply and use all oxygen, killing fish and insects.
What is eutrophication?
C2 - Chemical Resources
Turns from yellow to red when alkali is neutralised (used in making ammonium nitrate)
What does methyl orange indicator do?
C2 - Chemical Resources
Titration - methyl orange used. Nitric acid added to ammonia - goes from yellow to red. Evaporate solution until a little solution left - leave to crystallise. To get pure, note amount of acid needed and repeat but without indicator.
How is ammonium nitrate made?
C2 - Chemical Resources
N₂ + 3H₂ ⇌ 2NH₃
What is the equation for the Haber process?
C2 - Chemical Resources
Nitrogen - from the air (makes up 78% of air) Hydrogen - from cracking of oil fractions or natural gas
Where do the reactants for the Haber process come from?
C2 - Chemical Resources
Pressure - High (200 atmospheres) Temperature - 450°C Catalyst - Iron
What are the industrial conditions for making ammonia?
C2 - Chemical Resources
It favours the forward reaction and this high pressure increases the % yield of ammonia.
Why is the pressure high in the Haber Process?
C2 - Chemical Resources
It favours the reverse reaction - so a high temperature decreases the % yield. 450 is optimum because it gives a fast reaction rate and a reasonable % yield (compromise).
Why is a high temperature used in the Haber process?
C2 - Chemical Resources
It is recycled - so nothing is wasted.
What happens to unused hydrogen and nitrogen when making ammonia?
C2 - Chemical Resources
It makes the reaction go faster which gets it to its equilibrium proportions more quickly - but doesn’t affect the position of equilibrium or % yield.
Why is an iron catalyst used in the Haber Process?
C2 - Chemical Resources
Those that give the lowest production costs.
What are optimum conditions?
C2 - Chemical Resources
Price of energy, cost of raw materials, labour costs/wages, plant costs (equipment), rate of production
What 5 factors affect production cost?
C2 - Chemical Resources
Pumping hot water underground which dissolves the salt and the salt solution is forced to the surface because of the water pressure.
What is solution mining?
C2 - Chemical Resources
The holes must be filled in otherwise it will cause subsidence where the land collapses and slides in to the hole.
What is the issue with salt mining?
C2 - Chemical Resources
Hydrogen gas, chlorine gas and sodium hydroxide.
What is produced in the electrolysis of brine?
C2 - Chemical Resources
Chlorine gas: 2Cl⁻ - 2e⁻ → Cl₂ OXIDATION
What is produced at the anode during the electrolysis of brine? (including half-equations)
C2 - Chemical Resources
Hydrogen gas: 2H⁺ + 2e⁻ → H₂ REDUCTION
What is produced at the cathode during the electrolysis of brine? (including half-equations)