C3.1 Introducing Chemical Reactions Flashcards

1
Q

How do you write formulae of metal elements

A

Written as empirical formulae
As metals exist as giant metallic lattices

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2
Q

How do you write the formulae of non-metal elements

A

Individual atoms
Weak intermolecular forces

Group 7 is diatomic molecules, attracted with weak intermolecular forces - 2 atoms covalently bonded together

Other non metal molecules exist as giant covalent structures such as carbon and silicon.

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3
Q

How do you write the formulae for ionic compounds

A

Total number of positive charges = total number of negative charges
Examples:
NaCl: 1 Na+ ion and 1 Cl- ion

With compound ions if there are more than 1 of that compound, you put it in brackets:
NaOH
Mg(OH)2

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4
Q

Law of conservation of mass

A

Same atoms are present at the start and end of a reaction
Just joined in a different way
Total mass stays the same during a chemical reaction

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5
Q

Why the mass seems to change during some reactions

A

Substances can leave or enter the reaction mixture in a non-enclosed system
Usually happens in an open container when the reaction involves a substance in the gas state

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6
Q

What are balanced equations and word equations

A

Word equations:
Simple model for a chemical reaction
Shows the names of reactants and products involved
Balanced equation: more detailed model
Shows how the atoms are rearranged in a reaction
Relative amounts of each substance involved
Need to consider ion charges from each periodic table group and diatomic elements

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7
Q

How do you write balanced equations

A

Balanced when there are equal numbers of atoms of each element on both sides of the arrow

Step 1: Write the word equation and write formula for each substance under
Step 2: Add numbers on the left of 1 or more formulae, if necessary, making equal numbers of atoms on each side

Need to consider ion charges from each periodic table group and diatomic elements

Use CHOMO (hint: not a FNAF character)

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8
Q

What are state symbols

A

Show the physical state of each substance in a chemical reaction
Written in subscript letters in brackets next to products/reactants

State symbol-meaning
(s) - solid
(I) - liquid
(g) - gas
(aq) - aqueous solution

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9
Q

What are half equations

A

Model for the change that happens to 1 reactant in a chemical reaction
Balance charges
Balance numbers of atoms
Make sure of diatomic elements (H, N, F, O, I, Cl, Br)
Example: 2Na(s) + Cl2(g) -> 2NaCl(s)

Atom to ion example: Cl2 + 2e- —> 2Cl- (reduction)
Ion to atom example: Cl2 —> 2Cl- + 2e- (oxidisation)

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10
Q

What are ionic equations

A

Show the ions present in a reaction mixture
Also includes the formulae of any molecular substances present
Example:
Default: HCl(aq) + NaOH(aq) -> NaCl(aq) + H2O(l)
Ionic equation: H+(aq) + Cl-(aq) + Na+(aq) + OH-(aq) - Na+(aq) + Cl-(aq) + H2O(l)
H2O is not split up as it is covalently bonded not ionic bonding.

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11
Q

What are spectator ions

A

Ions that appear in the same form on both sides of the equation.
They are in the reaction mixture but do not take part in the reaction

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12
Q

Net ionic equation

A

Leaves out spectator ions

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13
Q

Form an ionic equation using half equations (links to C3.4 Electrolysis)

A
  1. Write down the anode half equation: 2Cl- —> Cl2 + 2e-
  2. Write down the cathode half equation: 2H+ + 2e- —> H2
  3. Combine both equations, keeping same species on either side of arrow: 2Cl- + 2H+ + 2e- —> Cl2 + 2e- + H2
  4. Cancel out electrons on either side: 2Cl- + 2H+ —> Cl2 + H2 (2e- goes from either side)
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14
Q

What is a precipitate

A

Product when 2 solutions are mixed
Always in solid state

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15
Q

What is a mole

A

Unit for amount of substance
1 mole of anything contains the same number of things

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16
Q

How many entities are there in 1 mole

A

Avogardo’s constant = 6.02 x 10²³
6.02 x 10²³ entities in 1 mole
An entity is a molecule, and some substances are bonded, with different numbers of atoms eg. Oxygen
For that multiply: number of atoms in the molecule x the number of moles x 6.02 x 10²³

17
Q

How do you measure a mole of a substance

A

Number of moles = Mass / Ar or Mr

18
Q

How do you calculate masses of reactants and products

A

Mass (g) = Ar x moles

19
Q

Mole calculation

A

Example: Nitrogen reacts with hydrogen to produce ammonia:
N2(g) + 3H2(g) -> 2NH3(g)
1) Calculate molar masses using Ar values:
Molar mass of N2 = 2x14=28g/mol
Molar mass of NH3 = 14 + (3x1) = 17g/mol
2) Calculate the amount of N2 in 84 g by the equation: mass = molar mass x amount
Amount = mass/molar mass = 84g/28g per mol = 3 mol
3) Calculate the moles of NH3 made from this amount of N2:
From the balanced equation:
1mol of N2 makes 2mol of NH3
So, 3 mol of N2 makes 6mol of NH3
4 calculate the mass of NH3 in this amount:
Mass = molar mass * amount
Mass = 17g/mol x 6mol = 102g

20
Q

What is a limiting reactant

A

1 reactant is usually in excess in a reaction mixture
More is present than is needed to react with the other reactant, so some is left at the end
Other reactant is in a limiting amount, that gets used up first.
Amount of product formed is determined by the amount of the limiting reactant

Reactant with less moles

21
Q

Calculating stoichiometry

A

Example: An oxide of copper is heated with excess hydrogen H2 forming 6.4g of copper and 0.9g of water. Calculate the balanced equation. Ar of copper=63.5 , Ar of water = 18
1) Calculate the amount of each measured substance:
Moles of Cu = mass/Ar = 6.4g/63.5 = 0.1 mol
Moles of H2O = mass/Ar = 0.9g/18 = 0.05 mol
2) Simplify the ratio of the substances:
Cu : H2O = 0.1:0.05 = 2:1
The right of the equation = 2Cu + H2O
Hydrogen is H2 so the equation must be Cu2O + H2 -> 2Cu + H2O

22
Q

What charge do hydrogen ions have

A

+1 charge

23
Q

What charge do metals in groups 1+2+3 form

A

positive ions
charge same as non IUPAC group number

24
Q

What charge do transition metals have

A

Transition metals preproduction positive ions that usually have a 2+ charge, except from silver and iron(lll)

25
Q

What charge do non metals in groups 5+6+7 have

A

negative
number of charges = 8 - their non IUPAC group number

26
Q

What are the 7 diatomic elements

A

hydrogen (H)
nitrogen (N)
oxygen (O)
fluorine (F)
chlorine (Cl)
bromine (Br)
and iodine (I)
They are called diatomic elements because the atoms appear in pairs.

27
Q

Metal + acid

A

Metal + acid => hydrogen + salt

28
Q

-OH

A

Hydroxide

29
Q

NO₃-

A

Nitrate

30
Q

CO₃²⁻

A

Carbonate

31
Q

SO₄²⁻

A

Sulfate

32
Q

Electronic structure of bromine

A

2.8.18.7

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