C3 Flashcards
What elements are diatomic?
All of group 7
Oxygen
Hydrogen
Nitrogen
What does Sulfur molecules exist as?
S8
What is the molecule phosphorus ?
P4
What does the molecular formula show?
The symbol for each element and the number of atoms in each element
Hydroxide ion:
OH-
Nitrate ion
NO3-
Carbonate ion:
CO3 2-
Sulfate ion
SO4 2-
How do you form ionic compounds?
Switch their charge number for a subscript number but the other way round
Ammonium ion
NH4 +
What is the law of conservation of mass?
During a chemical reaction no atoms are created or destroyed
What is the explanation if the mass increased?
One of reactants was a gas (which wasn’t weighed)
What is the explanation for when mass decreases
One of the products was a gas escaped and therefore mass was not accounted for
How do you show that mass has been conserved in a reaction?
Add up the relative masses (Mr) of each side to see that they are the same
Ammonia
NH3
What does aqueous mean?
Dissolved in water
How do you balance equations?
Use big numbers
Make sure there are the same amount of atoms on one side than the other
Do hydrogen and oxygen last
How do you write half equations?
Focus on one reactant, whether it lost of gained electrons
*one side will be neutral and the other will have a charge
If lost electrons instead of subtracting m add in the other side
Half equations rules
If became positive: lost electrons
If became negative: gained electrons
How do you write ionic equations
Exclude the spectator ions
Write the charge and state for the remainder
What are spectator ions?
Ions that do not change state or charge in a reaction
What state is a precipitate?
Solid
What is the definition of a mole?
amount of substance that contains the same number of particles (6.02 × 1023) as there are atoms in 12.0 g of 12C
What is the definition for avogadro’s constant?
The number of entities in one mole , equal to the number of atoms in 12g of carbon-12 atoms
What is the value of avogradro’s constant?
6.02 ✖️10^ 23
How many molecules and atoms are in one mol of water?
6.02✖️10^23 molecules
(6.02✖️10^23) ✖️3 atoms
How do you calculate the mass of a mole of a substance?
You find the Mr (relative formula mass) for that substance
How do you find the mean mass of one atom?
Mean mass of one atom = Mr➗ Avogadro’s constant
What equation do you use for reacting masses?
Mass = moles✖️Mr
How do you calculate reacting masses?
- Circle the two part involved
- Find the mols
IGNORE ANY BIG NUMBERS - Find the ratio
- Convert it back to mass
How do you balance the equation with stoichiometry?
- From the masses find the moles for each element
- Put it in the simplest ratio
- These become the big number
What is the limiting reactant ?
The reactant in least amount deciding the amount of product
What must you always remember to do?
Round to 3.s.f
How do you find out the limiting reactant?
- Find the amount of moles in each one
- Find the original ratio and the ratio the other two give
- Whichever one does not for the old ratio ,eg
lower is limiting and higher is excess
Why is a reaction endothermic?
Bond breaking is endothermic
Bond making is exothermic
There was more bond breaking than making.
More energy taken in than released
Endothermic?
Taking energy in
Making surroundings cooler
Eg: photosynthesis
Why is a reaction exothermic
Bond breaking is endothermic
Bond making is exothermic
More bond making than breaking
More energy given out then taken in
Exothermic?
Giving energy out to surroundings
Hot
Eg: combustion/neutralisation
What is activation energy?
The minimum amount on of energy required to start a reaction
What should an endothermic reaction profile look like?
📈products higher than reactants
Takes in energy for itself
📈 y axis = energy
📈 x axis = progress of reaction
📈 activation energy line from reactants to peak
📈 positive energy change from reactants to products
What should an exothermic reaction profile look like?
📉reactants higher than products
Gives our energy
📉y axis = energy
📉x axis = profess of reaction
📉activation energy from reactants to peak
📉negative energy change
What is energy change
Difference between energy transferred FROM surroundings to break bonds and between energy transferred TO the surroundings when bond making
What is bond energy?
The energy needed to break 1 mol of a particular covalent bond
Units = KJ/mol
What are redox reactions?
Reduction = loss of oxygen
Gain of electrons
Oxidation =gain of oxygen
Loss of electrons
OILRIG
How do you find oxidising and reducing agents?
Oxidising agent is the thing that got reduced
Reducing agent is the thing that got oxidised
* both can only be reactants
What is hydrochloric acid
HCl
Sulphuric acid
H2SO4
Nitric acid
NHO3
What is a metal(s) + acid
Salt + hydrogen
What is a metal oxide(s) + acid
Salt+ water
What is metal hydroxide +acid an state of metal hydroxide?
Salt+water
Metal hydroxide =aq
What is metal carbonate(s) +acid
Salt+water+carbon dioxide
What do acid’s release?
H+ ions
What do alkali’s release?
OH-
What is the difference between an alkaline and a base
Alkali’s are bases that are soluable
Describe the pH scale
Neutral = 7
Acid =<7
Alkali = > 7
How do you measure pH?
Use a pH meter:
1. Wash the probe
2. Put it in calibration buffer and adjust the reading
3. Put in in solution
Wash between each reading to prevent contamination
What is neutralisation?
A reaction an acid and a base to form a salt and water
What is the neutralisation equation?
H+ ➕OH- = H2O
aq ➕aq = l
What would you see when a metal carbonate/ metal is reacting?
Fizzing /effervescent
Because carbon dioxide / hydrogen is being released
What is the difference between dilute and concentrated acids?
Concentrated mean a high ratio of
Amount of Acid : volume of solution
Why are acids diluted?
To make them more safe
What is the difference between weak and strong acids ?
Weak acids only partially ionise (release H+ ions)
Strong acids fully ionise (release H+ ions)
*in aq solutions
Strong acids all so have a lower pH
What is the sign for a reaction that does not go to completion?
Half way arrows
Weak acid - partially ionising
What is the link between concentration and pH
As the concentrated ions increase by a factor of 10, the pH decreases by 1
What do titrations show?
How much of an acid is used to neutralise a bas
How do you read a titration curve?
X axis= volume of base/acid added
Y axis = pH
Vertices line = how much makes it neutral
What is electrolysis ?
The separation of compounds using electricity
What is an electrolyte ?
The solution or compound the electrodes are placed in
What is a cathode?
The negative electrode
Attracting positive ions
What is the anode?
The positive electrode
Attracting negative ions
What happens during molten electrolysis?
Positive ions gain electrons from the cathode to become neutral atoms (reduction)
Negative ions lose electrons at the anode to become neutral atoms (oxidation)
What are inert electrodes?
Electrodes that do not react, used in molten and aqueous electrolysis .
Eg: copper/platinum
What are the rules of aqueous electrolysis at the cathode?
If the metal is a known one (gold/silver/copper) - more un reactive then hydrogen then it will be discharged.
2H+ ➕2e- ➡️H2 a gas
What are the rules of aqueous electrolysis at the anode ?
Unless a halide is present hydroxide will be discharged
4OH-➡️2H2O ➕02➕4e-
What happens in aqueous electrolysis when there are complex molecules?
Say hydroxide gets discharged which is oxygen
What is the reactivity series acronym?
Please stop calling me a zombie in class
How does electroplating work ?
Cathode = thing you are trying to plate
Anode = thing you want to plate it with eg: silver
Electrolyte: must have the same metal as the anode
Cations(metal) moves from solution to anode, they are then replaced by the anode they loose electrons making them ions
What happens at the electrodes in electroplating?
Anode : loosing electrons to become ions
Ag ➖e- ➡️Ag-
Cathode : gaining lectins to become neutral
Ag+ ➕e-➡️Ag
How is copper purified?
Anode = impure copper
Cathode = pure copper
Electrolyte = copper sulphate
Copper ions from solution go to the cathode and ions made from the anode replace. Impurities/sludges is deposited at the bottom
What happens at the electrodes in copper purification?
Anode: losing electrons
Cu ➖2e-➡️cu2+
Cathode: gaining electrons to become neural
Cu2+ ➕2e- ➡️cu
Why can molten ionic solutions conduct?
The IONS are free to move and so can carry a charge
What is the unit of Avogrodro constant?
1/mol
What is the unit of avagradro’s constant?
1/ mol