C1- Atomic Structure Flashcards

(47 cards)

1
Q

what are the theee subatomic particles that make up an atom

A

protons neutrons electrons

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2
Q

proton:

1) relative mass
2) actual mass
3) relative charge

A

1) 1
2) 1.67x10^-27Kg
3) +1

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3
Q

neutron:

1) relative mass

A

1) 1

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4
Q

electron:

1) relative mass
2) relative charge

A

1) 1/1840
2) -1

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5
Q

what subatomic particles are neucleons

A

protons and neutrons

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6
Q

what is different about isotooes

A

number of neutrons

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7
Q

what is the mass number equal to

A

number of protons and neutrons

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8
Q

name three tyoes of isotooes of hydrogen

A

protium
deuterium
tritium

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9
Q

what is relative atomic mass RAM relative to

A

1/12 the mass of carbon-12

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10
Q

what dies TOF stand for

A

time of flight

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11
Q

name two methids of ionisation

A

electrospray and electron impact

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12
Q

what tyoe if solvent is used in TOF-MS

A

polar solvent

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13
Q

how are particles accelerated in TOF-MS

A

using an electric field

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14
Q

all particles are given the same…

A

kinetic energy

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15
Q

what sorr of oarticles move fastee?

A

lighter oarticles

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16
Q

how are particles detected in TOF-MS

A

ions cause an electric current to flow when they hit the detector

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17
Q

what is plotted in a mass spectrum

A

relative abundance vs mass to charge ratio (m/z)

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18
Q

what is the largest peak in a MS called

A

base peak

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19
Q

what does the base peak show?

A

the most stable ion

20
Q

what dies the peak with the highest mass show?

A

the molecular ion

21
Q

what does the molecular ion peak show?

A

relative molecular mass

22
Q

what is the wnergy level number called

A

the principle wuantum number

23
Q

what happens to the energy levels as you move further from the nucleus?

A

they get closer together

24
Q

what is a sub shell

A

an orbital or combination of orbitals

25
name to 4 sub shells
s, p, d and f
26
hiw many electrons can an irbital hold
1
27
ehy do electrons in the same orbital have opposite spins?
to minimise repulsion
28
how many s orbitals are there
1 per energy level
29
how many p orbitals are there
3 per energy level starting at n=3
30
how many d orbitals are there
5 per energy level starting at n=5
31
in what order are the sub shells filled
1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 7s
32
whoch is written first 3d or 4s
3d
33
what do up and down areows represent
the spin of an electron
34
how are p orbitals filled
1 in each orbital before pairing
35
why does chromium have the configuration 4s1 3d5
1/2 filled d shell is more stable
36
why dies copper have the configuration 4s1 3d10
filled d subshell is more stable
37
why is a full/half full d subshell more stable
symmetry around a nucleus
38
what happens to metal atoms to form ions
lose electrons
39
what haooens to non metal atoms to form ions
gain electrons
40
which electrons are lost first for transition metals 3d or 4s
3d
41
what is the first ionisation energy?
the energy required to remove mole of electrons from one mol of gaseous atoms to form one mole of gaseous ions
42
what dies a large gap in successive ionisation energy mean
the electron has been lost from an energy level closer to the nucleus
43
why do successive ionisation energies increase
greater effective nuclear charge
44
what is the trend in ionisation emergy down group 2
decreases
45
what is the GENERAL trend in ionisation energy across period 3
inscreases
46
why is the first ionisation energy of Al less than Mg
occupying the 3p subshell which is further from the nucleus
47
why is the first ionisation energy of S less than P
repulsion between paired electrons