C Unit 2.6 Halogenoalkanes Flashcards
What is a halogenoalkane?
- A homologous series
- In which one/or more of the hydrogen atoms
- Have been replaced by a halogen
Explain a halogenoalkane undergoing an elimination reaction
Hydrogen halides are acidic ∴ can be removed using an alkali
Dissolving NaOH in ethanol will avoid a substitution reaction
(halogen replaced with an OH group - apparently that’s 2.5)
How do i show u 1-bromoprone converted into propene and hydrogen bromide
Meh, i’ll state the chemical formula ig?
C3H7Br + NaOH (in ethanol) -> C3H6 + HBr
From saturated to unsaturated
(do i needa know this?)
Show unsymmetrical halogenoalkanes forming into more than one product when undergoing an elimination reaction
Chemical formula state D:
Bro idk, if this is helpful lowkey, I’ll think about writing it ig (will forget)
What is a nucleophile?
Has an electron pair that can be donated to an electron deficient centre
How do C-X (carbon halogen bonds) able to undergo necleophilic attack?
- They’re polar and have a permanent dipole
- Electron-deficient carbons can undergo
- Nucleophilic attack leading to substitution
What should be included within nucleophilic substitution diagram?
- Lone pairs
- Dipoles
- Charges
- Curly arrows
How to draw nucleophilic substitution???
This is so bad….
- C2H5X (X = random halogen)
- Curly arrow from OH ion pointing towards the C connected to X
- Show O as lone pair within OH and the negative charge
- Show C has delta positive and X has delta negative - Show curly arrow from bond between C-X and X
- Results:
C2H5OH + X-
- Show X as lone pair with negative charge
Can u draw nucleophilic substitution for other halogenalkenes?
Heck yea
Describe the rate of nucleophilic substitution towards carbon-halogens
- Rate increases down the group
- The more reactive the halogen
- The stronger the bond
- The longer the reaction will take
Show me rates of reaction between 3 halogenoalkanes in terms of nucleophilic substitution
Slowest
RCl
RBr
RI
Fastest
How to test for halogenalkanes?
- Add water (hydrolysis)
- Add silver nitrate (AgNO3)
Draw mechanism for nucleophilic substitution of 1-chloroproane with water
Ehhhh, wait
How is the nucleophilic substitution with water very slow?
- Water not good nucleophile
- Lacks full negative charge [of, say, a hydroxide ion]
How would u speed up nucleophilic substitution with water?
Add sodium hydroxide (NaOH)