Buffers Flashcards
What is a buffer?
Aqueous solution consisting of a mixture of either a weak acid and its conjugate base (salt) or a weak base and its conjugate acid (salt). Consists of acid and base in equilibrium
Aha happens to the pH of a buffer when small amounts of strong acid (or base) is added to it?
It changes very slightly
What is a acidic buffer?
A weak acid and its conjugate base
CH3C00H + H20 to CH3C00- + H30+
What happens when a strong base is added to a acidic buffer?
The weak acid (AH) will give up its proton in order to transform the base (OH-) into water and the conjugate base.
pH will change only slightly
What happens when a strong acid is added to a acidic buffer?
The weak base (A-) will react with the H30 from the strong acid to form the weak acid (HA) and water.
pH will only change slightly
What is buffer capacity?
Ability of the buffer to resist changes in pH on addition of acid (or base)
What does buffer capacity depend on?
The polarity of the buffer. Buffer capacity increases as polarity of the buffer solution (C0) increase.
Buffer capacity depends on the pH of the solution
When is maximum buffer capacity obtained?
When pH of the solution is equal to the pKa of the buffer