book!! Flashcards

1
Q

what interconversion does it electrochemistry deal with

A

interconversion of electrical energy and chemical energy

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2
Q

how do electrical effects occur

A

due to the movement of electrical charge

either ions in solution or electrons in a conductor

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3
Q

electrical current definition

A

the rate at which a charge passes a point

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4
Q

symbol for electrical current

A

I

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5
Q

symbol for current

A

A (amperes)

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6
Q

what must be present for an electrical current to flow between 2 points in a circuit

A

potential difference (VOLTAGE) between the 2 points

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7
Q

what is the potential difference

A

the driving force that pushes electrons // ions around the circuit

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8
Q

what is potential difference measured in

A

Volts
V

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9
Q

what law relates current and potential difference

A

ohms law

V = I x R

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10
Q

what is R in ohms law

A

the resistance of the material that the current is flowing through

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11
Q

what is resistance measured in

A

measured in ohms

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12
Q

what does a higher resistance mean

A

it means it’s harder for the charge to flow through the material

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13
Q

how does current affect voltage in an electrochemical cell

A

a high current leads to a loss in voltage??
as the reactants are used up

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14
Q

how does a large resistance affect current and voltage

A

a larger resistance decreases current and voltage.

voltage doesn’t decrease as fast tho!!

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15
Q

high current means

A

voltage falls quick
reactants are used up fast

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16
Q

large resistance means

A

voltage falls slower
reactants are used up slower
current is low

17
Q

high resistance in terms of voltage

A

high resistance = max voltage
very very small current

18
Q

what is max voltage called

A

zero current cell potential

electromotive force (emf)

Ecell

19
Q

high resistance ====

A

max voltage ( emf)
nearly no current

20
Q

simple electrochem system:: zinc metal in copper (||) sulphate

A

zinc dissolves
copper solid is formed

solution changes from blue to colourless (lack of copper in solution due to it forming a solid from gaining 2 e-)

21
Q

what equations are present in electrochem chem reactions

A

half reactions!!

one shows oxidation (loss of e-)
one shows reduction (gain of e-)

22
Q

what reactions are seen in electrochem chem

A

half reactions

23
Q

what are half reactions

A

one shows reduction ( gain of e-)
one shows oxidation (loss of e-)

24
Q

what a redux reaction

A

when oxidation and reduction occur simultaneously

25
Q

what happens on the surface of a metal in electrochem cells

A

electron transfer::

metal dissolves and forms an ion (losing e-)

ions in solution gain these e- to form a metal (seen on the surface)

26
Q

what interconversion electrochem chemistry involve

A

interconversion of chemical and electrical energy

27
Q

how can charge be moved by e- transfer

A

through conductors
ion transport in solution

28
Q

max voltage in a cell

A

Ecell
EMF
zero current cell potential