Bonding and Structure 2 Flashcards

1
Q

Why does giant ionic lattices
conduct electricity when liquid
but not when solid?

A
In solid state the ions are in fixed 
positions and thus cannot move. When 
they are in liquid state the ions are 
mobile and thus can freely carry the 
charge
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2
Q

Giant ionic lattices have high
or low melting and boiling
point? Explain your answer

A

They have high melting and boiling point
because a large amount of energy is
required to overcome the electrostatic
bonds

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3
Q

In what type of solvents do

ionic lattices dissolve?

A

Polar solvents

E.g water

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4
Q

Why are ionic compounds

soluble in water?

A

Water has a polar bond. Hydrogen atoms have a + charge and oxygen atoms have a - charge.

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5
Q

What is it called when atoms
are bonded by a single pair of
shared electrons?

A

Single bond

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6
Q

How many covalent bonds

does carbon form?

A

4

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7
Q

How many covalent bonds

does oxygen form?

A

2

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8
Q

What is the effect of multiple
covalent bonds on bond
length and strength

A

Double/triple bonds exert greater
electron density therefore the attraction
between nucleus and electron is greater
resulting in a shorter and stronger bond.

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9
Q

What is a lone pair?

A

Electrons in the outer shell that are not

involved in the bonding

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10
Q

What is formed when atoms

share two pairs of electrons?

A

Double bond

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11
Q

What is formed when atoms

share three pairs of electrons?

A

Triple bond

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12
Q

What is a dative covalent

bond?

A

A bond where both of the shared

electrons are supplied by one atom

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13
Q

How are oxonium ions

formed?

A

Formed when acid is added to water,

H3O+

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14
Q

What does the expansion of the octet mean?

A

When a bonded atom has more than 8

electrons in the outer shell

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15
Q

What are the types of covalent

structure?

A

● Simple molecular lattice

● Giant covalent lattice

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16
Q

Describe the bonding in simple

molecular structures

A

Atoms within the same molecule are held
by strong covalent bonds and different
molecules are held by weak
intermolecular forces

17
Q

Why do simple molecular
structures have low melting
and boiling point?

A

Small amount of energy is enough to

overcome the intermolecular forces

18
Q

Can simple molecular

structures conduct electricity?

A

No, they are non conductors

19
Q

Why do simple molecular
structures not conduct
electricity?

A

The have no free charged particles to

move around

20
Q

Simple molecular structures
dissolve in what type of
solvent?

A

Non polar solvents

21
Q

Give examples of giant

covalent structures

A

● Diamond
● Graphite
● Silicon dioxide, SiO2

22
Q

List some properties of giant

covalent structures? (3)

A

● High melting and boiling point
● Non conductors of electricity, except graphite
● Insoluble in polar and non polar solvents

23
Q

How does graphite conduct

electricity?

A

Delocalised electrons present between
the layers are able to move freely
carrying the charge