Bonding and Structure 1 Flashcards
What are ions?
Charged particles that is formed when an
atom loses or gains electrons
What is the charge of the ion
when electrons are gained?
Negative
What are molecular ions?
Covalently bonded atoms that lose or
gain electrons
Which electrons are lost when
an atom becomes a positive
ion?
Electrons in the highest energy levels
Do metals usually gain or lose
electrons?
Lose electrons
Which are the 4 elements that
don’t tend to form ions and
why?
The elements are beryllium, boron, carbon
and silicon
Requires a lot of energy to transfer outer shell
electrons
What are the 3 main types of
chemical bonds?
● Ionic
● Covalent
● Metallic
Define ionic bonding
The electrostatic attraction between
positive and negative ions
Give an example of an ionically bonded substance
NaCl (Sodium Chloride - salt)
What determines the strength of an ionic bond?
- Ionic radius and ionic charge
- Ionic bonding is stronger and the melting points
higher when the ions are smaller and/ or have
higher charges.
Explain the trend in ionic
radius down a group
Ionic radii increase going down the group.
This is because down the group the ions have more
shells of electrons and thus the outermost electron experience less pull from the positive nucleus.
Explain the trend in ionic radius for this set of isoelectronic ions,
e.g. N3- to Al3+
x
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| x
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N3- O2- F- (Ne) Na+ Mg2+ Al3+
There are increasing numbers of protons from N to F
and then Na to Al but the same number of electrons.
Therefore nuclear attraction between the outermost
electrons and nucleus increases and ions get
smaller
What are the physical
properties of ionic
compounds?
- high melting points
- non conductor of electricity when solid
- conductor of electricity when in solution or molten
- brittle /
In a solution of CuCrO4 with connected electrodes which electrode will the 2 ions migrate to?
Cu 2+ »_space; migrates to negative electrode
CrO4 2- »_space; migrates to positive electrode
Define covalent bonding
Electrostatic attraction between a shared
pair of electrons and the nuclei