Bonding and Structure 1 Flashcards

1
Q

What are ions?

A

Charged particles that is formed when an

atom loses or gains electrons

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2
Q

What is the charge of the ion

when electrons are gained?

A

Negative

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3
Q

What are molecular ions?

A

Covalently bonded atoms that lose or

gain electrons

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4
Q

Which electrons are lost when
an atom becomes a positive
ion?

A

Electrons in the highest energy levels

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5
Q

Do metals usually gain or lose

electrons?

A

Lose electrons

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6
Q

Which are the 4 elements that
don’t tend to form ions and
why?

A

The elements are beryllium, boron, carbon
and silicon
Requires a lot of energy to transfer outer shell
electrons

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7
Q

What are the 3 main types of

chemical bonds?

A

● Ionic
● Covalent
● Metallic

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8
Q

Define ionic bonding

A

The electrostatic attraction between

positive and negative ions

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9
Q

Give an example of an ionically bonded substance

A

NaCl (Sodium Chloride - salt)

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10
Q

What determines the strength of an ionic bond?

A
  • Ionic radius and ionic charge
  • Ionic bonding is stronger and the melting points
    higher when the ions are smaller and/ or have
    higher charges.
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11
Q

Explain the trend in ionic

radius down a group

A

Ionic radii increase going down the group.

This is because down the group the ions have more
shells of electrons and thus the outermost electron experience less pull from the positive nucleus.

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12
Q

Explain the trend in ionic radius for this set of isoelectronic ions,
e.g. N3- to Al3+

x
| x
| x
| x
| x
| x
|________________________________
N3- O2- F- (Ne) Na+ Mg2+ Al3+

A

There are increasing numbers of protons from N to F
and then Na to Al but the same number of electrons.
Therefore nuclear attraction between the outermost
electrons and nucleus increases and ions get
smaller

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13
Q

What are the physical
properties of ionic
compounds?

A
  • high melting points
  • non conductor of electricity when solid
  • conductor of electricity when in solution or molten
  • brittle /
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14
Q

In a solution of CuCrO4 with connected electrodes which electrode will the 2 ions migrate to?

A

Cu 2+ &raquo_space; migrates to negative electrode

CrO4 2- &raquo_space; migrates to positive electrode

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15
Q

Define covalent bonding

A

Electrostatic attraction between a shared

pair of electrons and the nuclei

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16
Q

Define metallic bonding

A

Electrostatic attraction between the
positive metal ions and the sea of
delocalised electrons

17
Q

Electrons in which shell are
represented in a dot and cross
diagram?

A

The outer shell