bonding and structure Flashcards
ionic bonding
strong electrostatic attraction between oppositely charged ions
covalent bond
strong electrostatic attraction between two nuclei and the shared pair of electrons between them
electronegativity
the ability of an atom to attract the bonding electrons in a covalent bond
metallic bonding
strong electrostatic attraction between metal ions and delocalised electrons
Dative covalent bond
Electrostatic force of attraction between two positive nuclei and two electrons from the same atom
explain why hydrogen bonding causes ice to be less dense than liquid water
more space between molecules
due to the 3D lattice shape
H bonds are longer than covalent bonds
why does Bcl3 have a trigonal planar shape with a bond angle of 120
3 bond pairs 0 lone pairs
bond pairs become more spread apart/max separation
due to repulsion
trend in ionic radius of isoelectronic ions along a period
radius increases due to more protons
which increases attraction of nucleus to electrons
( and decreases atomic radius)
explain why boiling temperatures increase from chlorine to iodine
more electrons
stronger london forces
more energy required to break intermolecular forces
how are carbon atoms arranged in graphene and graphite
hexagonal rings within a layer
bond angles in a layer of graphene are
all 120 degrees
describe how london forces form between molecules
uneven distribution of electrons
causes an instantaneous dipole
induces a second dipole on another molecule
explain why O-H bond are shorter than S-H bonds
sulphur has a larger atomic radius
so more shieling between outer e- and nucleus
less attraction between outer e- and nucleus