Bonding Flashcards

1
Q

What type of bonding exists in monatomic gases?

A

LD Forces

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2
Q

What are London Dispersion Forces

A

They are weak attraction between atoms

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3
Q

Explain why sodium has a lower melting point than magnesium

A

Sodium has a stronger attractive force between the cations and the delocalised electron. Therefore, metallic bonding in magnesium is stronger than in sodium

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4
Q

Explain why sodium has a higher melting point than Caesium

A

This is because Caesium is larger in size. Which means the charge gets spread out evenly and caesium can be separated by using lesser energy.

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5
Q

Explain why Xenon has a higher bp than Argon

A

This is because it has more outer electrons to be evenly distributed which therefore means that it will have more LDF

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6
Q

What type of bonding contains positive ions and delocalized electrons

A

Metallic bonding

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7
Q

Why does silicon have a significantly higher melting point than nitrogen

A

This is because Silicon is a covalent network which means that when it melts strong covalent bonds are broken. Nitrogen is a diatomic molecule which has LDF between the molecules

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8
Q

Why does sulphur have a higher mpt than Chlorine

A

This is because Sulfur has a bigger molecule which means it has more electrons and stronger LDF

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9
Q

Why does Potassium have a higher mpt than Argon

A

This is because Potassium has metallic bonding and Argon which is monoatomic have very strong LDF

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10
Q

Explain how LDF arises

A

It occurs due to temporary fluctuations in electron density within the atom or molecule

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11
Q

Explain how permanent dipole- permanent dipole interactions arises

A

It occurs due to the difference in electronegativity between the atoms in a molecule which leads to the formation of a permanent dipole force.

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12
Q

Explain how hydrogen bonding occurs

A

It occurs due to hydrogen bonds being covalently bonded to highly electronegative elements like Nitrogen, Oxygen and Fluorine (NOF)

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13
Q

What type of forces do polar substances have

A

They have permanent dipole/permanent dipole interactions.

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14
Q

What type of forces do Non-polar substances have?

A

They have London Dispersion Forces (LDF)

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15
Q

What is a covalent bond

A

It is two positive nuclei sharing electrons.

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16
Q

What is a polar covalent bond

A

It occurs when two atoms share electrons unequally due to difference in electronegativity

17
Q

What is a non-polar/pure covalent bond

A

It occurs 2 atoms share electrons equally due to having the SAME electronegativity

18
Q

Name the 3 types of intermolecular bonding

A

LDF
Permanent dipole-permanent dipole interactions
Hydrogen bonding

19
Q

Explain why HCL has a higher boiling point than H2

A

This is because the LDF (Van der Waals Force) in HCL is stronger than the LDF in H2

20
Q

Explain why the boiling point of HALOGENS increases going down the group?

A

Intermolecular forces increases going down the group

LDF’s are the forces broken btw the molecules

The more the electron the stronger the LDF’s