Alcohols Flashcards

1
Q

What does the name of all alcohols end in

A

–ol

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2
Q

What is alcohols functional group

A

–OH (hydroxyl group)

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3
Q

What is a unique thing about the first three alcohols

A

They are polar so they are soluble in water

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4
Q

What is alcohols general formula

A

CnH2n+1 OH

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5
Q

Name two properties of alcohol

A

The hydroxyl group are responsible for its properties

It contains hydrogen bonding as it contains oxygen and hydrogen (This means when compared to alkanes of a similar mass, an alcohol will have a higher BPT)

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6
Q

Alcohols have multiple hydroxyl groups this means that they can be?

A

Diols (2) and triol(3)

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7
Q

What type of melting and boiling points does diols and triols have and what is their viscosity

A

They have a high melting & boiling point and they also have higher viscosity

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8
Q

Why do diols and triols have higher melting and boiling points?

A

This is because there are more hydrogen bonding present

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9
Q

Further oxidation of PRIMARY ALCOHOLS form what?

A

Carboxylic Acid

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10
Q

Why can’t a Tertiary alcohol be oxidised

A

This is because it will involve breaking up the carbon chain

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11
Q

During the reaction with acidified Potassium permanganate (MnO4-) what is the colour change?

A

The purple permanganate is reduced to colourless

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12
Q

During a reaction with acidified dichromate solution (K2Cr2O7) what is the colour change

A

The orange dichromate ions is reduced to green

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13
Q

What is the colour change for copper (ii) oxide and heat

A

From black to red

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14
Q

What is the colour change in the oxidation of aldehydes with Benedict’s solution/Fehling’s solution

A

From blue to orange-red

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15
Q

What is the colour change when a Tollens solution is used

A

A ‘silver mirror’ is formed

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16
Q

Boiling point ———- as number of OH groups increases

A

Increases

17
Q

Why does boiling point increase as number of OH groups increases?

A

As the number of OH groups increases, there are more hydrogen bonds between molecules, so more energy is required to break hydrogen bonds. Therefore the boiling point increases.