bonding Flashcards

1
Q

ionic bonding

A

electrostatic forces of attraction between oppositely charged ions in a lattice.

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2
Q

ionic lattice

A

each ion is surrounded by oppositely charged ions. They are held in place by electrostatic forces of attraction. However, the ionic model assumes all ions to be perfectly spherical.

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3
Q

ionic properties

A

High melting point due to strong electrostatic forces of attraction between oppositely charged ions which requires lots of energy to break. Can only conduct when molten or dissolved in water. As a solid, the ions are in fixed positions but when molten, the bonds break and the ions are free to move and carry charge. Some ionic compounds can dissolve as the slightly positive hydrogen atoms are attracted to the anions while slightly negative oxygen atoms are attracted to the cations.

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4
Q

ammonium ion formula

A

NH4^+

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5
Q

hydroxide ion formula

A

OH^-

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6
Q

sulfate ion formula

A

SO4^2-

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7
Q

carbonate ion formula

A

CO3^2-

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8
Q

nitrate ion formula

A

NO3^-

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9
Q

hydrogen carbonate ion formula

A

HCO3^-

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10
Q

covalent bonding

A

electrostatic attraction between the shared electrons and the two positive nuclei of non-metals

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11
Q

dative/coordinate bond

A

a shared pair of electrons supplied by one atom. represented by an arrow.

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12
Q

simple covalent molecules

A

low m.p and b.p because they have weak intermolecular forces of attraction that are easy to overcome. therefore, they are gases at room temperature. the cannot conduct electricity as they have no free electricity.

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13
Q

compare diamond and graphite

A

both are giant covalent structures that have high m.p. because there are lots of strong covalent bonds holding the carbon atoms together. diamond is hard because it is a lattice structure held by very strong covalent bonds. Graphite is softer as it is arranged in layers that can slide over each other. The carbon atoms in diamond form 4 bonds while in graphite, it can only form 3. Therefore, it can conduct electricity as it has delocalised electrons.

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14
Q

metallic bonding

A

the electrostatic force of attraction between the positively charged metal ions and the negatively charged sea of delocalised electrons. Atoms contribute their outer shell electrons to the sea of delocalised electrons.

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15
Q

properties of metals

A

metal atoms are held together by strong electrostatic forces of attraction that require lots of energy to break so their m.p is high. they conduct electricity because they have a sea of delocalised electrons that are free to move and carry charge. they are malleable because the atoms are arranged in layers that can easily slide over eachother.

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16
Q

factors affecting metallic bond strength

A

charge of ion
number of delocalised electrons
size of ion

17
Q

trigonal pyramidal

A

3 bonding pairs
1 lone pair
bond angle 107

18
Q

bent

A

2 bonding pairs
2 lone pairs
bond angle 104.5

19
Q

trigonal bipyramidal

A

5 bonding pairs
0 lone pairs
bond angle 120 and 90

20
Q

t-shaped

A

3 bonding pairs
2 lone pairs
bond angle 88

21
Q

octahedral

A

6 bonding pairs
0 lone pairs
bond angle 90

22
Q

trigonal planar

A

3 bonding pairs
0 lone pairs
bond angle 120

23
Q

seesaw

A

4 bonding pairs
1 lone pair
bond angle 87 and 102

24
Q

square planar

A

4 bonding pairs
2 lone pairs
bond angle 90

25
Q

tetrahedral

A

4 bonding pairs
0 lone pairs
bond angle 109.5

26
Q

linear

A

2 bonding pairs
0 lone pairs
bond angle 180

27
Q

working out shape of H20

A
central atom= oxygen
O= group 6
bonded to 2 hydrogens
6+2/2= 4 pairs
4-2=2
2 b.p 2 l.p
28
Q

electronegativity

A

the power of an atom to attract a pair of electrons in a covalent bond

29
Q

factors affecting electronegativity

A

nuclear charge- more protons means stronger attraction between the nucleus and bonding pair of electrons (greater nuclear charge = greater electronegativity)
atomic radius - the closer to the nucleus, the stronger the attraction between the nucleus and bonding pairs of electrons. (smaller atomic radius = greater electronegativity)
shielding - less electron shells between the nucleus and electrons = less shielding so stronger attraction between nucleus and bonding pair of electrons