bonding Flashcards
ionic bonding
electrostatic forces of attraction between oppositely charged ions in a lattice.
ionic lattice
each ion is surrounded by oppositely charged ions. They are held in place by electrostatic forces of attraction. However, the ionic model assumes all ions to be perfectly spherical.
ionic properties
High melting point due to strong electrostatic forces of attraction between oppositely charged ions which requires lots of energy to break. Can only conduct when molten or dissolved in water. As a solid, the ions are in fixed positions but when molten, the bonds break and the ions are free to move and carry charge. Some ionic compounds can dissolve as the slightly positive hydrogen atoms are attracted to the anions while slightly negative oxygen atoms are attracted to the cations.
ammonium ion formula
NH4^+
hydroxide ion formula
OH^-
sulfate ion formula
SO4^2-
carbonate ion formula
CO3^2-
nitrate ion formula
NO3^-
hydrogen carbonate ion formula
HCO3^-
covalent bonding
electrostatic attraction between the shared electrons and the two positive nuclei of non-metals
dative/coordinate bond
a shared pair of electrons supplied by one atom. represented by an arrow.
simple covalent molecules
low m.p and b.p because they have weak intermolecular forces of attraction that are easy to overcome. therefore, they are gases at room temperature. the cannot conduct electricity as they have no free electricity.
compare diamond and graphite
both are giant covalent structures that have high m.p. because there are lots of strong covalent bonds holding the carbon atoms together. diamond is hard because it is a lattice structure held by very strong covalent bonds. Graphite is softer as it is arranged in layers that can slide over each other. The carbon atoms in diamond form 4 bonds while in graphite, it can only form 3. Therefore, it can conduct electricity as it has delocalised electrons.
metallic bonding
the electrostatic force of attraction between the positively charged metal ions and the negatively charged sea of delocalised electrons. Atoms contribute their outer shell electrons to the sea of delocalised electrons.
properties of metals
metal atoms are held together by strong electrostatic forces of attraction that require lots of energy to break so their m.p is high. they conduct electricity because they have a sea of delocalised electrons that are free to move and carry charge. they are malleable because the atoms are arranged in layers that can easily slide over eachother.