acids and bases Flashcards
acid
proton donor
base
proton acceptor
strong acid
An acid that completely dissociates to ions when in solution (0-1)
weak acid
An acid that only slightly dissociates when in solution (3-5)
strong base
A base that completely dissociates to ions when in solution (12-14)
weak base
A base that only slightly dissociates when in solution (9-11)
pH
-log10[H+]
[H+]
10^-pH
Kw
[H+][OH-]
Ka
[H+][A-]/[HA]
10^-pKa
pKA
-log10Ka
what is a buffer
A solution which is able to resist changes in pH when
small volumes of acid or base are added.
what do buffers contain
Acidic buffer solutions contain a weak acid and the salt of that weak acid and basic buffer
solutions contain a weak base and the salt of that weak base.
why are buffers important
Buffer solutions are common in nature in order to keep systems regulated. This is important as
enzymes or reactions in living organisms often require a specific pH, which can be maintained
using a buffer solution.
how to work out pH of a strong acid diluted with water
find no. moles of H+ using n=cv
find new [H+] using new total volume
use pH=-log[H+]
how to work out pH of a weak acid
use [H+][A-]/[HA]
assume [H+]=[A-]
find [H+] and use pH=-log[H+]
how to work out pH of a strong base
use Kw=[H+][OH-]
find [H+] and use pH=-log[H+]
how to work out pH of a strong acid and strong base
calculate no. moles of H+ and OH-
find which one is in XS
find conc of the one in XS using n=cv
if H+ is in XS, use pH=-log[H+]
if OH is in XS use Kw
how to work out pH of weak acid and salt
a buffer forms
find no. moles HA and A-
find conc [HA] and [A-]
use Ka=[H+][A-]/[HA] to find [H+]
find pH
how to work out pH of a weak acid and a strong base
find moles of HA and OH-
find which one is in XS
find new conc [HA] using XS moles
find [A-] (mols A- =mols OH-)
use Ka expression to find [H+]
find pH
find pH if a small amount of acid or base is added to a weak acid and salt or a weak acid and strong base
find no. moles of H+ or OH- added
decide which way the equilibrium moves and find the new no. moles of HA and A-
find new conc of HA and A-
use Ka expression to find [H+] and find pH