acids and bases Flashcards

1
Q

acid

A

proton donor

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2
Q

base

A

proton acceptor

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3
Q

strong acid

A

An acid that completely dissociates to ions when in solution (0-1)

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4
Q

weak acid

A

An acid that only slightly dissociates when in solution (3-5)

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5
Q

strong base

A

A base that completely dissociates to ions when in solution (12-14)

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6
Q

weak base

A

A base that only slightly dissociates when in solution (9-11)

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7
Q

pH

A

-log10[H+]

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8
Q

[H+]

A

10^-pH

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9
Q

Kw

A

[H+][OH-]

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10
Q

Ka

A

[H+][A-]/[HA]
10^-pKa

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11
Q

pKA

A

-log10Ka

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12
Q

what is a buffer

A

A solution which is able to resist changes in pH when
small volumes of acid or base are added.

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13
Q

what do buffers contain

A

Acidic buffer solutions contain a weak acid and the salt of that weak acid and basic buffer
solutions contain a weak base and the salt of that weak base.

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14
Q

why are buffers important

A

Buffer solutions are common in nature in order to keep systems regulated. This is important as
enzymes or reactions in living organisms often require a specific pH, which can be maintained
using a buffer solution.

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15
Q

how to work out pH of a strong acid diluted with water

A

find no. moles of H+ using n=cv
find new [H+] using new total volume
use pH=-log[H+]

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16
Q

how to work out pH of a weak acid

A

use [H+][A-]/[HA]
assume [H+]=[A-]
find [H+] and use pH=-log[H+]

17
Q

how to work out pH of a strong base

A

use Kw=[H+][OH-]
find [H+] and use pH=-log[H+]

18
Q

how to work out pH of a strong acid and strong base

A

calculate no. moles of H+ and OH-
find which one is in XS
find conc of the one in XS using n=cv
if H+ is in XS, use pH=-log[H+]
if OH is in XS use Kw

19
Q

how to work out pH of weak acid and salt

A

a buffer forms
find no. moles HA and A-
find conc [HA] and [A-]
use Ka=[H+][A-]/[HA] to find [H+]
find pH

20
Q

how to work out pH of a weak acid and a strong base

A

find moles of HA and OH-
find which one is in XS
find new conc [HA] using XS moles
find [A-] (mols A- =mols OH-)
use Ka expression to find [H+]
find pH

21
Q

find pH if a small amount of acid or base is added to a weak acid and salt or a weak acid and strong base

A

find no. moles of H+ or OH- added
decide which way the equilibrium moves and find the new no. moles of HA and A-
find new conc of HA and A-
use Ka expression to find [H+] and find pH