Biological Molecules 3 - Lipids Flashcards
What do lipids include?
triglycerides and phospholipids
What two molecules do lipids consist of?
glycerol and fatty acids
Are lipids insoluble?
Yes but that can dissolve in organic liquids such as ethanol
What is different about a lipid from a carbohydrate?
It contains proportionally less oxygen than carohydrates.
What does a glycerol look like?
It has 3 carbons, 4 hydrogens and 3 OH groups.https://www.differencebetween.com/difference-between-glycerol-and-vs-fatty-acids/
What is the general formula of fatty acids? And give an example of what they could look like.
COOH.(CH2)nCH3
https://www.creative-proteomics.com/blog/index.php/biref-introduction-of-short-chain-fatty-acids/
Give the definition of a glycerol
It is an alcohol that dissolves in water meaning it is a hydrophilic molecule
Why are triglycerides not considered polymers?
They are made up of two diff. types of subunits ( glycerol and fatty acids) which both have different structures. Triglycerides aren’t made up of identical monomers.
Are fatty acids hydrophobic or hydrophilic?
Hydrophobic meaning they are repelled by water.
What does a triglyceride look like?
https://clinidiabet.com/en/infodiabetes/cardiodiabetes/15.htm
How does one fatty acid differ from another?
By the length of the hydrocarbon chain (CH2n) and the variation of lipid structure is caused by the different types of fatty acid
What are the 2 types of fatty acid?
saturated and unsaturated
What does the hydrocarbon chain in a saturated fatty acid consist of?
It consists of no carbon-to-carbon double bonds, is a straight solid hydrocarbon chain and has the maximum no. of hydrogen atoms bonded to the carbon atoms, hence the term saturated.
What is does a unsaturated fatty acid hydrocarbon chain consist of?
There are one or many (mono/poly) carbon-to-carbon double bonds
the chain doesn’t contain the maximum no. of hydrogen atoms as the carbon has used one of its bonds to double bond with another carbon, hence the term unsaturated.
The chain is kinked where there is a double C bond so it is more of a fluid/liquid
How is a triglyceride formed and broken?
One glycerol molecule combines with three fatty acid molecules.
There is an ester bond between the fatty acid and glycerol
one triglyceride will therefore have 3 ester bonds
ester bonds are formed by condensation reactions
water is formed from the hydrogen in the OH group on the glycerol and the full OH group from the COOH unit from the fatty acid.
if a lipid is broken down, it undergoes a hydrolysis reaction.
Which type of fat can damage the heart and coronary arteries and contribute to heart disease?
saturated fat
What is a low-density lipoprotein? (LDL)
They contain and transport saturated fat and cause harm. This fatty material can block major arteries, known a plaque, and can cause myocardial infarction, also known as a heart attack.
What is a high density lipoprotein (HDL)?
contain and transport unsaturated fats and they carry harmful fats away to the liver for disposal. a high proportion of HDL in the blood lowers the risk of heart disease
What health implications that high fat intake cause?
atherosclerosis, aneurysm, and myocardial infarction
What does an aneurysm do?
damages the thin artery wall by inflation. the artery can’t handle the pressure and blood cant get away from the heart
what are the properties of lipids?
insoluble in water but soluble in organic solvents
fats are solid at room temp.
oils are liquid at room temp.
Give the 6 functions of lipids and describe each of them.
Energy storage - in seeds and animals, release more energy than carbohydrates when used as an alternative respiratory substrate
Protection of vital organs - used as shock absorption, preventing physical damage to internal organs
Thermal insulation - used as heat insulator e.g blubber in whales, seals and polar bears
Buoyancy - lipids are less dense than water so they float, they have a role in maintaining buoyancy in organisms such as fish
Metabolic water - produced when lipids are oxidised by respiration, vital in desert animals such as camels whose hump is made of fat.
Waterproofing - waxes are hydrophobic and cover the exoskeleton of insects and cuticles of plant leaves, reducing water loss
What are phospholipids made of?
they have glycerol, two fatty acids and a phosphate group
Which part of the phospholipid is hydrophilic? And which is hydrophobic?
The phospholipid head - including glycerol and phosphate group.
Fatty acid tails
