Biogeochemical cycles Flashcards
Are nutrients and energy lost up in an ecosystem
Energy: Lost as heat, cannot be reused, decreases system’s usefulness.
Nutrients: Recycled indefinitely, never used up, can be reused continuously.
Biogeochemical cycles
Circular movement of nutrients between living and non-living components of the ecosystem (biogeochemical cycle).
Types of Nutrient Cycles
Perfect Cycle: Nutrients replaced as fast as utilized (e.g., Gaseous cycles). Imperfect Cycle: Some nutrients lost or locked up (e.g., Sedimentary cycles).
Gaseous Cycle: Reservoir = atmosphere/hydrosphere (e.g., water, carbon, nitrogen, methane cycles). Sedimentary Cycle: Reservoir = Earth’s crust (e.g., phosphorus, sulfur, calcium, magnesium cycles).
Carbon Cycle
Gaseous Cycle
Short-term: Carbon exchanged between atmosphere, organisms, Earth. CO₂ absorbed by plants, transferred to animals, and returned through respiration/decomposition.
Long-term: Carbon stored in soils/aquatic sediments for millions of years. Fossil fuels release carbon back to the atmosphere when burned.
What does decomposition of organic matter produce?
The decomposition of decaying organic matter produces nitrogen and carbon dioxide.
Photosynthesis
Sunlight (free energy) is converted into carbohydrates (potential energy) using water and carbon dioxide. Oxygen is released in the process.
Nitrogen Cycle
(Gaseous Cycle)
Nitrogen Cycle ==> Nitrogen → (N2 Fixing/Ammonification) → Ammonia/Ammonium Ions → (Nitrification) → Nitrite → → Nitrate → (Denitrification) → Nitrogen
Conversion of nitrogen into oxides how?
Nitrogen in Atmosphere: Exists as N₂ (two nitrogen atoms with triple covalent bond).
Nitrogen Oxides (NO, NO₂, N₂O): Formed by lightning, UV radiation, industrial combustion, forest fires, vehicle exhausts, and power plants.
Ammonification
a process that converts organic nitrogen into ammonia or ammonium. from atmosphere by N2 fixers or from urea/uric acid waste by bacteria.
N2-fixers
Nitrogenase: Enzyme in prokaryotes that fixes atmospheric nitrogen into ammonia (NH₃) and ammonium ions (NH₄⁺).
N₂-fixers: Microbes that fix nitrogen, including:
1. Free-living (non-symbiotic): Soil bacteria like Azotobacter, Beijemickia, Clostridium, Rhodospirillum.
2. Symbiotic: Bacteria like Rhizobium that form partnerships with leguminous and non-leguminous plants.
3. Cyanobacteria: Blue-green algae such as Nostoc, Anabaena, Spirulina (N-fixation in oceans).
Nitrification
Ammonium converted to nitrites and nitrates
Ammonium → Nitrite: By Nitrosomonas and Nitrococcus.
Nitrite → Nitrate: By Nitrobacter.
Nitrates ultimately absorbed by plants
Importance of Nitrification
In Agriculture for fertilizers
Ammonia → Nitrate (NO₃⁻), increases nitrogen leaching, water solubility.
In Wastewater Treatment:
Nitrification followed by denitrification.
Denitrification
Nitrate → Nitrogen (N₂)
Denitrifying Bacteria: Pseudomonas, Thiobacillus
Converts nitrates/nitrites to elemental nitrogen, which escapes to the atmosphere, completing the nitrogen cycle.
Methane
More potent GHG than CO₂, short-lived in atmosphere.
Contributes to ground-level ozone formation (air pollutant).
Oxidizes to CO₂ after 1-2 decades.
Methane Cycle
Natural Sources: Decomposing biological matter, wetlands, oceans, termite digestion.
Human Activities: 50-65% of global CH₄ emissions, primarily from:
Agriculture (40%: livestock, rice)
Fossil Fuels (35%)
Waste (20%: landfills, wastewater)
Methane Sinks:
Soils: Methanotrophic bacteria (Methane Oxidation).
Hydroxyl Radicals (OH): Atmospheric cleanser, methane sink.
Clathrate Deposits:
Previously methane sinks in oceans/permafrost, now melting due to warming, releasing methane.