Biochem part 3 Carbs Flashcards

1
Q

Monosaccharides are categorized into two groups:

A

Ketone and Aldehyde

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2
Q

in monosaccharides, the ______ group is always on carbon 1

A

Aldehyde

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3
Q

in monosaccharides, the ______ group is always on carbon 2

A

Ketone

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4
Q

Glucose, Galactose, and Mannose are all examples of ______

A

aldohexose

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5
Q

Ribose is an aldo_____

A

aldopentose

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6
Q

Fructose is a ____hexose

A

ketohexose

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7
Q

what is a reducing sugar

A

any sugar that has an aldehyde group OR can form one in solution (usually a disaccharide)

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8
Q

t/f fructose is an example of a reducing sugar

A

FALSE

KETOhexose

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9
Q

Different compounds with the same chemical formula (different configurations)

A

isomer

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10
Q

monosaccharides which differ in their configuration around one specific carbon.

A

Epimer
Glucose and Galactose are C-4 epimers
Glucose and Mannose are C-2 epimers

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11
Q

Mirror images of the same compound; L or D glucose

A

Enantiomers

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12
Q

Anomeric carbons are formed when sugars cyclize; for an aldehyde the anomeric carbon is C-___

A

C-1

aldeyhde group always carbon 1

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13
Q

Lactose is made of which 2 monosaccharides, and which bonds

A

Glucose and Galactose (beta 1,4)

-Lactase can break these bonds

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14
Q

Maltose is made of which 2 monosaccharides, and which bonds

A

Glucose and Glucose (alpha 1,4)

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15
Q

Isomaltose is made of which 2 monosaccharides, and which bonds

A

Glucose and Glucose (alpha 1,6)

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16
Q

Cellobiose is made of which 2 monosaccharidse, and which bonds

A

Glucose and Glucose (beta 1.4)
- humans do not contain the enzyme need to break these beta 1,4 bonds. We do have lactase to break b1,4 bonds in lactose.

17
Q

Amylopectin breaks into which 2 disaccharides

A

Maltose and Isomaltose

18
Q

Glycogen contains what types of bonds

A

alpha 1,4 and alpha 1,6

19
Q

Glycogen is the most highly branched polysaccharide, what is the branch point

A

alpha 1,6 linkages

20
Q

Cellulose contains what types of bonds

A

beta 1,4

- do NOT contain cellulase to break these bonds

21
Q

Glycosaminoglycans (GAGs) aka

A

mucopolysaccharides

22
Q

The major structural characteristic of GAGs is a repeating _____ unit

A

disaccharide unit (protein-sugar molecules)

23
Q

2 most common GAGs

A
Hyaluronic acid (synovial fluid)
Chondroitin sulfate (cartilage, tendons, ligs)
24
Q

GAGs are large (positive/negative) charged heteropolysaccharides which bind large amounts of _____

A

negative; water

25
Q

Amylopectin is a homolog of ____

A

glycogen

26
Q

alpha-amylase breaks amylose into _____

A

maltose

27
Q

Amylopectin contains which types of bonds

A

alpha 1,4 and alpha 1,6

-in plants