Atoms Ions And Compounds Flashcards
Isotopes
Atoms of the same element with different numbers of neutrons and a different mass
Cations
+ve
Anions
-be
For mass why not just add no. Protons and neutrons
Strong nuclear force is holding protons and neutrons comes at the expense of a loss of a fraction of their mass (mass defect)
Standard mass for atomic mass
U= 1/12 mass of an atom of carbon 12
Relative isotopic mass
The mass of an isotope relative to 1/12 the mass of an atom of carbon 12
Relative atomic mass
The weighted mean mass of an atom of an element relative to 1/12 the mass of an atom of carbon 12
Takes account of abundance and isotopic mass
How does a mass spectrometer work
Sample placed in Massbach samplers vaporised then ionised to form positive ions Ions accelerated- heavier move slower and are deflected less. Ions separated. Detected on mass spectrum as a mass to charge ratio. Each ion adds a signal, higher abundance=greater signal
Binary compound
Contain two elements only
Manganate(vII)
MnO4-
Sulfite
SO32-
Nitrite
No2-
How does phosphorus exist
P4
Avogadros constant
6.02x10^23/mol
1 mol= the amount of substance that contains 6.02x10^23 particles
12g of carbon 12 has 6.02x10^23 particles
Molar mass
Gmol^-1
Molecular formula
The actual number of atoms of each element in a molecule
Empirical formula
The simplest whole number ratio of atoms of each element in a compound
Relative molecular mass
For simple molecules compares the mass of a molecule the mass of an atom of carbon 12
Relative formula mass
Mass of empirical unit compares the mass of a formula unit with the mass of an atom of carbon 12
Assumptions one finding formula of hydrated salts
All water has been lost and no further decomposition
Volume of one mole of gas molecules
24dm^3
Moles gas vol
Vol=mol x 24
Ideal gas equation assumptions
Random motion elastic collisions negligible size no intermolecular forces
Ideal gas equation
pV=nRT P=pressure Pa V=vol m^3 N=mols R=constant 8.314 T=temp in K
Atom economy
A measure of how well atoms have been utilised
Hi atom economy produce large proportion of desired product and are important for sustainability
Atom economy=sum of molar mass of desired product/total mass of products x100