Atoms Flashcards
Principles of electrons
Heisenberg uncertainty principle
The position and momentum of an electron cannot be known simultaneously.
Principles of electrons
Pauli exclusion principle
No two electrons can have the same four quantum numbers. Therefore: paired electrons must have opposite spin (one +1/2, other -1/2)
Principles of electrons
Hund’s rule
All orbitals in a subshell must contain at least one electron before any orbital can be filled with a second electron.
The first electron in each orbital all have the same parallel spin, while the second electron in the orbital has opposite spin
Principles of electrons
Aufbau principle
Electrons will fill the lower energy orbitals before moving to the higher energy orbitals.
Order in which energy of orbitals increases is determined by the (n+l) rule, where the sum of the principal (n) and azimuthal (l) quantum numbers determine the energy level of the orbital
Principles of electrons
Diamagnetic vs paramagnetic
Diamagnetic: If there are no unpaired electrons. Results in being repelled by a magnetic field.
Paramagnetic: If there are any unpaired electrons. Results in being attracted by a magnetic field.
Quantum numbers
Each orbital holds a maximum of 2 electrons
There are n2 orbitals per shell and therefore 2n2 electrons per shell
Each subshell holds 4l + 2 electrons.
For example the p subshell holds 6 electrons, the d subshell holds 10
Quantum numbers
n
Quantum numbers
l
Quantum numbers
ml
Quantum numbers
ms
Constants and equations
Avogadro’s number
Constants and equations
Speed of light in a vacuum
Constants and equations
Planck’s constant (h)
Constants and equations
Energy of a photon