Atoms Flashcards

1
Q

Principles of electrons

Heisenberg uncertainty principle

A

The position and momentum of an electron cannot be known simultaneously.

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2
Q

Principles of electrons

Pauli exclusion principle

A

No two electrons can have the same four quantum numbers. Therefore: paired electrons must have opposite spin (one +1/2, other -1/2)

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3
Q

Principles of electrons

Hund’s rule

A

All orbitals in a subshell must contain at least one electron before any orbital can be filled with a second electron.
The first electron in each orbital all have the same parallel spin, while the second electron in the orbital has opposite spin

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4
Q

Principles of electrons

Aufbau principle

A

Electrons will fill the lower energy orbitals before moving to the higher energy orbitals.
Order in which energy of orbitals increases is determined by the (n+l) rule, where the sum of the principal (n) and azimuthal (l) quantum numbers determine the energy level of the orbital

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5
Q

Principles of electrons

Diamagnetic vs paramagnetic

A

Diamagnetic: If there are no unpaired electrons. Results in being repelled by a magnetic field.

Paramagnetic: If there are any unpaired electrons. Results in being attracted by a magnetic field.

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6
Q

Quantum numbers

A

Each orbital holds a maximum of 2 electrons

There are n2 orbitals per shell and therefore 2n2 electrons per shell
Each subshell holds 4l + 2 electrons.

For example the p subshell holds 6 electrons, the d subshell holds 10

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7
Q

Quantum numbers

n

A
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8
Q

Quantum numbers

l

A
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9
Q

Quantum numbers

ml

A
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10
Q

Quantum numbers

ms

A
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11
Q

Constants and equations

Avogadro’s number

A
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12
Q

Constants and equations

Speed of light in a vacuum

A
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13
Q

Constants and equations

Planck’s constant (h)

A
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14
Q

Constants and equations

Energy of a photon

A
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