Atomic structure electronic configuration Flashcards
Energy level
The fixed quantity of energy an electron can have
Sub level
A group of orbitals of the same energy
Orbital
Region in space where there is a high probability of finding an electron
Energy sub level
s, p, d, f
Aufbau principles
Electrons fill orbitals of lowest energy first
Hunds rule
Electrons fill orbitals of the same energy singly first and then in pairs. Singly filled orbitals of the same energy have all their electrons spin in the one directions
Pauli (Exclusion) Principle
Each orbital holds at most two electrons. Electrons in the same orbital spin in opposite directions
Most stable electronic configurations
Full energy level or full sub level
Middle stable
Half full sub level
Least stable
Having one electron away from most stable
Niels Bohr statements about line emission spectrum in hydrogen
1st
Atoms begin with their electrons in ground state
Ground state means the electrons are in the lowest possible energy level
Niels Bohr statements about line emission spectrum in hydrogen]
2nd
Energy in the form of heat is given to the electron, the electron is promoted to a higher (excited state) energy level
Niels Bohr statements about line emission spectrum in hydrogen
3rd
The electron does not like being at a higher energy level so it falls back down to either the ground state or a lower excited state energy level. It loses its energy in the form of light
Niels Bohr statements about line emission spectrum in hydrogen
4th
Bohr called the higher of the two energy levels E2 and the lower one E1. He said E2 - E1 = hf
Where h = Planck constant and f is the frequency of light. He found this formula matched the frequency given off
Niels Bohr statements about line emission spectrum in hydrogen
5th
Due to the fact that he had lines of coloured light on a black background, he concluded that only certain energy levels were available and that these energy levels were fixed or quantised