Atomic structure electronic configuration Flashcards

1
Q

Energy level

A

The fixed quantity of energy an electron can have

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2
Q

Sub level

A

A group of orbitals of the same energy

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3
Q

Orbital

A

Region in space where there is a high probability of finding an electron

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4
Q

Energy sub level

A

s, p, d, f

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5
Q

Aufbau principles

A

Electrons fill orbitals of lowest energy first

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6
Q

Hunds rule

A

Electrons fill orbitals of the same energy singly first and then in pairs. Singly filled orbitals of the same energy have all their electrons spin in the one directions

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7
Q

Pauli (Exclusion) Principle

A

Each orbital holds at most two electrons. Electrons in the same orbital spin in opposite directions

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8
Q

Most stable electronic configurations

A

Full energy level or full sub level

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9
Q

Middle stable

A

Half full sub level

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10
Q

Least stable

A

Having one electron away from most stable

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11
Q

Niels Bohr statements about line emission spectrum in hydrogen
1st

A

Atoms begin with their electrons in ground state
Ground state means the electrons are in the lowest possible energy level

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12
Q

Niels Bohr statements about line emission spectrum in hydrogen]
2nd

A

Energy in the form of heat is given to the electron, the electron is promoted to a higher (excited state) energy level

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13
Q

Niels Bohr statements about line emission spectrum in hydrogen
3rd

A

The electron does not like being at a higher energy level so it falls back down to either the ground state or a lower excited state energy level. It loses its energy in the form of light

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14
Q

Niels Bohr statements about line emission spectrum in hydrogen
4th

A

Bohr called the higher of the two energy levels E2 and the lower one E1. He said E2 - E1 = hf
Where h = Planck constant and f is the frequency of light. He found this formula matched the frequency given off

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15
Q

Niels Bohr statements about line emission spectrum in hydrogen
5th

A

Due to the fact that he had lines of coloured light on a black background, he concluded that only certain energy levels were available and that these energy levels were fixed or quantised

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16
Q

Schrodinger’s Theory

A

Described the position of the electron in a different manner so Bohr’s theory is not correct

17
Q

Heisenberg uncertanty principle

A

It is impossible to simultaneously know both the position and momentum of an electron, as in the process of measuring one we change the other

18
Q

The Lyman series

A

When electron drop to n=1, this is a very high energy difference, these high energy differences are in the UV region of the spectrum.

19
Q

Balmer series

A

Drops to n=2 are in the visible region

20
Q

Paschen series

A

Drops to n=3 (and higher) are in the Infrared region.

21
Q

Atomic emission spectroscopy

A

method of chemical analysis that uses the intensity of light emitted from a flame, plasma, arc, or spark at a particular wavelength to determine the quantity of an element in a sample

22
Q

Louis De Broglie

A

First proposed the concept of the dual wave, particulate nature of matter

23
Q

S orbitals

A

Spherical

24
Q

P orbitals

A

Dumbell