Atomic Structure Flashcards
What is Mass Spectrometry?
It measures mass of atoms and their relative abundance enabling relative atomic mass values to be calculated
-measures fragmentation patterns
Mass Spectrum stages of operation?
Injection of vaporized sample
Vaporization: vaporized and the gas streams into ionization chamber
Ionization: making positive ions
Acceleration:only positive ions attracted through slits
Deflection:magnetic field deflects lighter ions more than heavy ions
Detection: measures the mass and relative amounts of ions present
How are line spectra produced?
By thin gases in which the atoms do not experience many collisions
How are continuous Spectra produced?
When the gas pressures are higher, so that lines broadened by collisions between the atoms until they are smeared into a continum
Explain Emission Spectra
Atom electrons are excited from their lowest state to an excited state. When electrons drop from a higher level to a lower level they emit energy which corresponds to a particular wavelength and shows up on line spectra.
The bigger the drop, the higher the energy
What are the properties of Isotopes?
- Are almost identical to one another
- Slight difference in physical properties(bp)
- Some radioactive
- React with different rates