Atomic Structure Flashcards

1
Q

Atomic Structure: The Atom

What are the Subatomic Particles?

A
  • Protons
  • Electrons
  • Neutrons
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2
Q

Atomic Structure: The Atom

What is the Relative Mass of a Proton?

A

1

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3
Q

Atomic Structure: The Atom

What is the Relative Charge of a Proton?

A

+1

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4
Q

Atomic Structure: The Atom

What is the Relative Mass of an Electron?

A

0

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5
Q

Atomic Structure: The Atom

What is the Relative Charge of an Electron?

A

-1

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6
Q

Atomic Structure: The Atom

What is the Relative Mass of a Neutron?

A

1

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7
Q

Atomic Structure: The Atom

What is the Relative Charge of a Neutron?

A

0

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8
Q

Atomic Structure: The Atom

Which one’s greather Atomic number or Mass number?

A

Mass number

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9
Q

Atomic Structure: The Atom

What is the Atomic Number?

A

Proton number

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10
Q

Atomic Structure: The Atom

What is the Mass Number?

A

Total number of protons & neutrons

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11
Q

Atomic Structure: Isotopes

What is an Isotope?

A

Atoms with the same atomic number but different mass number

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12
Q

Atomic Structure: Isotopes

Which properties do Isotopes share?

A

Chemical
↳ have the same electron configuration

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13
Q

Atomic Structure: Isotopes

Which properties in Isotopes differ?

A

Physical
↳ depend on its mass

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14
Q

Atomic Structure: Relative Mass

What is the Relative Atomic Mass?

A

Average mass of an atom compared to 1/12 of carbon 12

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15
Q

Atomic Structure: Relative Mass

What is the Relative Isotopic Mass?

A

Average mass of an isotope compared to 1/12 of carbon 12

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16
Q

Atomic Structure: Relative Mass

What is meant by the term ‘Abundance’?

A

How much

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17
Q

Atomic Structure: Relative Mass

How would you workout the Ar from Isotopic Abundances?

A
  • Multiply each relative isotopic mass by its % relative isotopic abundance
  • Add them up
  • Divide by 100
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18
Q

Atomic Structure: Mass Spectra

What does the Mass Spectra show?

A
  • Relative Isotopic Masses
  • Abundances of diff elements
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19
Q

Atomic Structure: Mass Spectra

What does the y-axis show?

A

The abundance of ions

Often as %

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20
Q

Atomic Structure: Mass Spectra

What does the Height of the peak show?

A

Relative Isotopic Abundance

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21
Q

Atomic Structure: Mass Spectra

What does the x-axis show?

A

m/z or the Relative Isotopic Mass

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22
Q

Atomic Structure: Mass Spectra

How would you workout the Relative Atomic Mass from a Mass Spectra graph?

A
  • Multiply each Relative Isotopic Mass by its Relative Isotopic Abundance
  • Add them up
  • Divide by the sum of Isotopic Abundances
23
Q

Atomic Structure: Mass Spectra

How would you workout the Relative Abundance for Diatomics?

A
  • Express each % as a decimal
  • Make a table showing each possible mol
  • Add together any duplications
24
Q

Atomic Structure: Mass Spectra

How would you workout the Mass Spectrum for Diatomics?

A
  • Divide all Relative Abundances by the smallest one
    ↳ works out the smallest whole number ratio
25
# **Atomic Structure:** Electron Structure What is meant by the term 'Configuration'?
Arrangement
26
# **Atomic Structure:** Electron Structure What are the 4 Subshells? | (blocks)
* S * P * D * F
27
# **Atomic Structure:** Electron Structure What is an Orbital?
Space where you find electrons
28
# **Atomic Structure:** Electron Structure How many electrons can each orbital hold?
Level 1 (s) = 2 Level 2 (s+p) = 8 Level 3 (s+p+d) = 18 Level 4 (spdf) = 32
29
# **Atomic Structure:** Electron Structure What is S Block Shape?
Spherical
30
# **Atomic Structure:** Electron Structure What is the P Block Shape?
Dumbbell
31
# **Atomic Structure:** Electron Configuration What are its Rules?
1. Electrons enter the lowest available energy level 2. No 2 electrons can have the same spin 3. When in orbitals of equal energy, electrons will try to remain unpaired
32
# **Atomic Structure:** Electron Configuration How would u formulate a Condensed one?
1. Locate element of choice 2. Find **noble gas** that comes DIRECTLY **before** your element 3. Put the **chemical symbol** of that **noble gas** in **squared brackets** 4. Complete the rest of the configuration
33
# **Atomic Structure:** Electron Configuration What's Chronium's EC?
* **Donate one** of their **4s electron** to their **3rd shell** ↳ **more stable** with a **full/half full d-shell**
34
# **Atomic Structure** Electron Configuration What's Copper's EC?
* **Donate one** of their **4s electron** to their **3rd shell** ↳ **more stable** with a **full/half full d-shell**
35
# **Atomic Structure:** Electron Configuration What are Isoelectric Ions?
Different charged ions with the same electron configuration
36
# **Atomic Structure:** Atomic Emission Spectra What happens when an electron is given EMR?
It absorbs the heat ↳ giving it enough energy to jump to a higher QL
37
# **Atomic Structure:** Atomic Emission Spectra What happens to that same electron over time?
It will fall back to its OG QL ↳ releasing heat
38
# **Atomic Structure:** Ionisation Energies What is meant by the term 'Ionisation Energy'? | (endo)
Amount of energy needed to remove electrons from atoms
39
# **Atomic Structure:** Ionisation Energies What is the 1st Ionisation Energy?
Energy required to remove **ONE MOLE** of electrons from **ONE MOLE** of gaseous atoms to form **ONE MOLE** of gaseous positive ions
40
# **Atomic Structure:** Ionisation Energies What are the factors affection Ionisation energy?
* **Atomic Radius** : smaller = greater attraction to nucleus * **Nuclear Charge** : more electrons = greater pull from nucleus * **Shiedling** : less pull from nucleus **:** blocked by inner electrons
41
# **Atomic Structure:** Ionisation Energies What happens to the Ionisation Energy as u go Down a group?
Decreases
42
# **Atomic Structure:** Ionisation Energies Why does the Ionisation Energy decrease going Down a group?
* Down a group, the bigger the Atomic Radius ↳ has more shells * Less Nuclear Charge ↳ easier to remove outer electrons **:** Shielding
43
# **Atomic Structure:** Ionisation Energies What is meant by Successive Ionisation Energy?
As you ionise something successively, you ionise it more than once
44
# **Atomic Structure:** Ionisation Energies Why is the Successive Ionisation Energy higher?
- Positively charged ions have a greater number of protons than electrons ↳ more energy is needed **:** as you're staring from a positive level rather than neutral
45
# **Atomic Structure:** Ionisation Energies What is meant by the term '2nd Ionisation Energy'?
Energy required to remove **ONE MOLE** of electrons from **ONE MOLE** of gaseous ions to form **ONE MOLE** of **TWO** gaseous positive ions
46
# **Atomic Structure:** Ionisation Energies How would u workout an element's group using a table with its data values?
1. Locate the biggest adjacent numeric jump 2. Element's group is based on where the jump starts
47
# **Atomic Structure:** Periodicity What is meant by the term 'Periodicity'?
Trends
48
# **Atomic Structure:** Periodicity What happens to the Atomic Radius across a period? Why? | Size of the atom
**DECREASES** ↳ because the nuclear charge increases & attracts the outer electrons closer to the nucleus
49
# **Atomic Structure:** Periodicity What happens to the Ionisation Energy across a period? Why? | General trend of ionisation across QL 2 & 3
**GENERALLY INCREASES** ↳ proton number increases **:** stronger nuclear charge
50
# **Atomic Structure:** Periodicity Why is there a drop in energy between Mg & Al?
* **Further away** from the **nucleus**, the **more energy** that **electron** has ↳ has less attraction from nucleus * Its **outershell** is **shielded** by the **inner elecrons** ↳ this makes the outershell of electrons to be lost easily * Therefore it is easier to remove that outshell which requires **less heat**
51
# **Atomic Structure:** Periodicity Why is there a drop in energy between P & S?
* Sulfur **refills its 1st orbital** due to its configuration * When **electrons** are **paired** they exert a force of **repulsion** ↳ this force is enough to make the energy drop
52
# **Atomic Structure:** Periodicity What happens to the Mp/Bp across a period? Why? | (For metals)
**INCREASES** * metallic bonds get stronger
53
# **Atomic Structure:** Periodicity What happens to the Mp/Bp across a period? Why? | (For non-metals)
**DECREASES** * LFs are weak & easy to overcome
54
# **Atomic Structure:** Periodicity What happens to Mp/Bp when the Atomic radius increases?
**INCREASES** * there are more electrons **:** more LFs ↳ more energy needed to break bonds