Atomic + Molecular Structure Flashcards

1
Q

What did Dalton’s Atomic Theory state?

A
  • All elements are composed of atoms
  • Atoms of 1 element differ from atoms of other elements
  • All compounds of composed of different atoms
  • No destruction/construction of atoms
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Protons weigh about

A

1 amu

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

The atomic # (or Z) equals to the

A

Number of protons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

The further the valence electron is from the nucleus the

A

Weaker the attraction is between the electron and the nucleus

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Rutherford stated that the atom has a

A

Densely-charged nucleus which accounts for a small portion of the volume

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Planck developed the first quantum theory, proposing that

A

Energy is emitted as electromagnetic radiation in quanta

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

What is the energy of a quantum?

A

E = h • f

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

What is the angular momentum (L) according to the Bohr model?

A

L = nh / 2π

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

The energy of the electron is given by

A

E = -Rh / n^2

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

The energy of an electron is related to the

A

Orbital radius

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

The smaller the radius means the

A

Lower the energy

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

What is the electromagnetic energy of protonss?

A

E = h•c / wavelength

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Each element maintains its own

A

Atomic emission spectrum

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

The Lyman series describes emission to

A

n = 1 (UV)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

The Balmer series describes emission to

A

n = 2 (UV + Vis)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

The Pascher series describes emission to

A

n = 3 (Inf)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

What is the equation to find energy level transitions?

A

E = -Rh (1/ni^2 - 1/nf^2)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

The pauli exclusion principle states that

A

No 2 electrons in a given atom have the same 4 quantum numbers

19
Q

The max number of n correlates to the

A

Number of the period

20
Q

The larger the n the

A

Higher the energy level + radius

21
Q

The max number of electrons in a SHELL is denoted by

A

2n^2

22
Q

As the distance from the nucleus increases, the

A

Difference in energy between adjacent shells decreases

23
Q

The azimuthal quantum number (l) ranges from

A

0 to n-1

24
Q

When l = 0, the orbital is

A

S

25
Q

When l = 1, the orbital is

A

P

26
Q

When l = 2, the orbital is

A

D

27
Q

When l = 3, the orbital is

A

F

28
Q

The maximum number of electrons found in a subshell can be found by

A

4l + 2

29
Q

The greater the value of l, the greater the

A

Energy

30
Q

The magnetic quantum number (ml) ranges from

A

l to -l

31
Q

Two electrons in the same orbital must have

A

Opposite spins

32
Q

Electrons in different orbitals with the same ms values have

A

Parallel spins

33
Q

Electrons in the same orbitals with different ms values have

A

Paired spins

34
Q

The Aufbau principle states that

A

Subshells are filled from the lowest to highest energy

35
Q

Which equation allows for one to determine subshell energy?

A

(n + 1)

36
Q

The lower the sum of (n+1) the

A

Lower the energy

37
Q

Hund’s Rule states that

A

Orbitals are filled first before pairing

38
Q

When a molecule is paramagnetic it means that it contains

A

Unpaired electrons

39
Q

How does the magnetic field act when an atom is paramagnetic?

A

It aligns the spin of the electrons and attracts them

40
Q

Diamagnetic atoms lack

A

Unpaired electrons

41
Q

Diamagnetic atoms are repelled by the

A

Magnetic field

42
Q

Which atoms are stable?

A

Ones with half-filled or fully-filled subshells

43
Q

Half-filled subshells are found in columns

A

6 and 12