Aromatics And Amines Flashcards

1
Q

What is the hydrogenation value for cyclohexa13diene and why (3)

A

-239 to -121

It is more stable because some overlap of p orbitals so delocalised electrons

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2
Q

How do hydrogen bonds from between polypeptide chains

A

The electron deficient H+ in the nitrogen attracts the lone pair on oxygen of C=O

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3
Q

Which structures are secondary
Which one is tertiary

A

Alpha helix and beta pleated

Disulphide bridge

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4
Q

How do amines react with water
And why
What type of reaction is it

A

Accept a proton
They are bases
Reversible (not strong base)

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5
Q

Why is benzene a planar molecule

A

The c c bonds are all the same length and

All have bond angle between a CC single bond and cc double bond

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6
Q

Why is benzen toxic

A

It is carcinogenic

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7
Q

Why so methylbenzene not reactive than Benz e

A

Methyl group releases electrons into delocalised system which makes it more attractive to electrophiles

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8
Q

Equation for nitrobenzene electrophiles

A

Hno3 and h2so4

No2+
Hso4-
Water

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