AROMATIC HYDROCARBONS Flashcards

1
Q

It was first isolated in 1825 from the oily residues after heating whale oil

A

Benzene or C6H6

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2
Q

Benzene was isolated by in

A

1825 by Michael Faraday

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3
Q

In 1834 benzene’s was prepared from

A

Benzoic acid

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4
Q

Benzobic acid was obtained from the chemical degradation of

A

Gum benzoin

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5
Q

It is the parent hydrocarbon of the especially stable compounds known as aromatic compounds

A

Benzene

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6
Q

It is the term that came to mean any compound structurally derived from benzene

A

Aromatic

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7
Q

This compounds are hydrocarbons that contain a benzene ring as a structural unit

A

Aromatic hydrocarbons

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8
Q

In addition to benzene other examples include

A

Toluene and napthalene

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9
Q

The most common reactions of aromatic compounds involve

A

Substitution

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10
Q

The most common reactions of aromatic compounds involved substitution of other atoms or groups for a ring hydrogen on the aromatic unit or more precisely called

A

Electrophilic aromatic substitution reaction

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11
Q

The halogenation of aromatic hydrocarbons include

A

Bromination and chlorination of benzene

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12
Q

Bromination and chlorination of benzene requires a Lewis acid such as

A

Ferric bromide / ferric chloride

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13
Q

Electrophilic iodine is obtained by treating iodide with an oxidizing agent such as

A

Nitric acid

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14
Q

Nitration of benzene with nitric acid requires what acid as a catalyst

A

Sulfuric acid

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15
Q

A sulfuric acid is a strong acid because of what

A

Three electron withdrawing oxygen atoms and the stability of its conjugate base

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16
Q

Two electrophilic substitution reactions bear the names of

A

Charles freidel and James crafts

17
Q

It is the two electrophilic substitution reaction that bears the name of Charles freidel and James crafts

A

Friedel crafts reaction

18
Q

Places and acyl group on a benzene ring

A

Friedel crafts acylation

19
Q

Places an alkyl group on a benzene ring

A

Friedel crafts alkylation

20
Q

These can be used for friedel crafts acylation

A

Acyl halide and acid anhydride