Aromatic Compounds Flashcards
What are all the atoms in an aromatic compound hybridized to?
Sp2
3 things describing aromatic compounds ?
Cyclic
Conjugated
Posses 4n + 2 pi electrons
What is Huckels rule?
Aromatic compounds must have 4n + 2 pi electrons
What are anti aromatic compounds ?
Cyclic conjugated molecules possessing 4n pi electrons
Aromatic compounds are also referred to as ___ or ____ and are represented by Ar. While aliphatic compounds are also called ___ and are represented by the symbol R
Aryl or arenes
Alkyl
The Benzene group is called a ____ group when named as a Substituent.
Phenyl
What is needed for an electrophilic aromatic substitution?
An acid catalyst or Lewis acid.
What do aromatic rings react with to form sulfonic acid
Fuming sulfuric acid ( so3 and h2so4)
What are the activating , ortho-para directing substituents?
Nh3, NR2, OH, NHCOR, OR, OCOR, R
What are the deactivating , slightly electron withdrawing ortho paro substituents?
F, Cl, Br, I
What are the deactivating meta - directing substituents
NO2, SO3H, carbonyl compounds (COOH, COOR, COR, CHO)