Alcohols And Ethers Flashcards
Alkyl groups ____ the conjugate base of alcohols and thus _____ the pka.
Destabilize
Increase
The presence of an electron withdrawing group will ____ the negativity charged conjugate base of an alcohol and this will ____ the pjs
Stabilize
Decrease
Phenols are ____ acidic than aliphatic alcohols due to resonance structures
More
Phenols have ___ melting and boiling points but are _____ in water
High
Slightly soluble
Electron withdrawing substituents _____ acidity while electron donating groups ____ acidity for phenols
Increase
DecreaSe
What are the two most common reducing agents ? Which is the stronger reducing agent ?
LAH and NaBH4
LAH
What are the two most common oxidizing agents ? Which one is more powerful ?
PCC and KMnO4
KMnO49
Treatment of phenols with oxidizing agents produce compounds called ?
Quinones
Ethers boil at ___ temperatures compared to alcohols due to no hydrogen bonding
Low
Ethers react with oxygen in the air to form highly explosive compounds called ?
Peroxides
In asymmetrical epoxide a the most substituted Carbon is attacked by the Nucleophile in the presence of ____ while the least substituted is attacked in the present of ____
Acid
Base