Alcohols And Ethers Flashcards

0
Q

Alkyl groups ____ the conjugate base of alcohols and thus _____ the pka.

A

Destabilize

Increase

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1
Q

The presence of an electron withdrawing group will ____ the negativity charged conjugate base of an alcohol and this will ____ the pjs

A

Stabilize

Decrease

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2
Q

Phenols are ____ acidic than aliphatic alcohols due to resonance structures

A

More

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3
Q

Phenols have ___ melting and boiling points but are _____ in water

A

High

Slightly soluble

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4
Q

Electron withdrawing substituents _____ acidity while electron donating groups ____ acidity for phenols

A

Increase

DecreaSe

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5
Q

What are the two most common reducing agents ? Which is the stronger reducing agent ?

A

LAH and NaBH4

LAH

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6
Q

What are the two most common oxidizing agents ? Which one is more powerful ?

A

PCC and KMnO4

KMnO49

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7
Q

Treatment of phenols with oxidizing agents produce compounds called ?

A

Quinones

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8
Q

Ethers boil at ___ temperatures compared to alcohols due to no hydrogen bonding

A

Low

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9
Q

Ethers react with oxygen in the air to form highly explosive compounds called ?

A

Peroxides

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10
Q

In asymmetrical epoxide a the most substituted Carbon is attacked by the Nucleophile in the presence of ____ while the least substituted is attacked in the present of ____

A

Acid

Base

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