Amines

Question 0

Compounds with 2 nitrogens ?

3?

Answer 0

Diazides

Azides

Question 1

Nitrogen compound with a double bond to carbon ?

Triple bond ?

Answer 1

Imine

Nitrile

Question 2

Nitroglycerin common use ?

Answer 2

Relaxant

Relieve coronary artery spasms and angina (chest pain )

Question 3

Nitrous oxide common use ?

Answer 3

Laughing gas and for dental anesthetic

Relaxant

Question 4

When would you say amine vs amino ?

Answer 4

Amine if it’s the highest priority, put at the end of the word
Amino if it’s not the highest priority and it’s a prefix

Question 5

Which has a higher melting point , amines or alcohols ? Why?

Answer 5

Alcohols , more electronegative

Question 6

Because nitrogen has a lone pair and is normally sp3 it goes through ___

Answer 6

Nitrogen inversion ; inversion of the orbital occupied by the lone lake

Question 7

Amines are ___ bases and ___ bases

Answer 7

Brønsted Lowry

Lewis

Question 8

Alkyl amine vs ammonia. Which one is more basic ?

Answer 8

Alkyl amine

Question 9

Anilines :
What increases Basicity
What decreases Basicity

Answer 9

Electron donating groups

Electron withdrawing groups

Question 10

Direct alkylation of ammonia can be a problem because ?

Answer 10

The product formed is more nucleophilic than ammonia and keeps reacting

Question 11

How to reduce multiple side products with alkylation ?

Answer 11

Use Gabriel synthesis. It uses phthalimide with an alkyl halide and a base and water

Question 12

Most common reducing reagents of nitro compounds ?

Answer 12

Zinc and dilute HCl

Question 13

Hoffmann elimination ? Double bond forms on ?

Answer 13

Exhaustive methylation. Silver oxide , water and heat allows the quaternary amine to leave.

Least substituted