Aromatic Chemistry Flashcards

1
Q

what is a pi bond?

A

overlap of unhybridised p orbitals on each C atom

double sausage of e- density above and below bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

what is benzene?

A

C6H6
adjacent pi bonds
delocalised e-
alternating single and double bonds sp2 bond overlap is strong
all binds equal length
e- density forms donught shape so are delocalised

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

what are red curly arrows for?

A

show the donation of e- so the movement of e- density

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

what are conjugated molecules?

A

have alternating single or double bonds

occurs when unhybridised p orbitals on 3+ atoms overlap
allow for delocalisation of e-

stabilised molecules due to resonance
can exist longer

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

what is delocalisation?

A

each pi e- is shared by other C
electrons are free to move around the other elements

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

what is conjugation?

A

have alternating single and double bonds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly