Arene Flashcards

1
Q

Cum se stabileste fm

A

CnH2n+2-2*NE

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2
Q

date care confirma structura lui kekule

A

rap 1;1 C:H, cei 6 H echivalenti, bz poate fi hidrogenat

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3
Q

Date ce vin in contradictie cu kekule

A

bz articipa la S, ag ox folos la alchene nu au treaba cu bz, neconstatata dorinta de polimerizare, nu exista mai multi iz disubstituiti, distantele dintre at de C 1,39A

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4
Q

ce demonstreaza structura bz

A

echivalenta celor 6 C-C si delocalizarea e pi

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5
Q

decarboxilarea ac monocarbox. cond

A

exces de NaOH la t

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6
Q

Hidrogenoliza toluenului cond

A

Pt/Al2O3 la 600-700

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7
Q

reformarea catalitica cond

A

Pt/Al2O3, 500, 15-30 atm

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8
Q

trimerizarea acetilenei cond

A

600-800 tuburi ceramice

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9
Q

trimerizarea propinei cond

A

t in med acid

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10
Q

stare de agregare

A

mononucleare lichide, polinucleare solide

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11
Q

solubilitate

A

insolubile in apa, solubile in solventi organici

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12
Q

densitate

A

mai mare ca a celorlalte hc, mai mica decat a apei

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13
Q

cum sunt vaporii de bz

A

toxici si inflamabili

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14
Q

cine e solvent

A

bz si toluenul

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15
Q

halogenare cu br si cl cond

A

FeX3, AlX3

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16
Q

Halogenare cu I

A

HNO3

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17
Q

Reactia de nitrare

A

amestec nitrant, sulfonitric

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18
Q

nitrobenzen solubilitate

A

insolubil in apa, solubil in alcool sau eter

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19
Q

nitrobenzen aspect

A

miros de migdale amare, lichid alb galbui

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20
Q

nitrobenzen nume alternativ

A

esenta de mirban

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21
Q

sulfonare cond

A

h2so4 concentrat sau oleum

22
Q

alchilare cu alchene cond

A

alcl3+H2o

23
Q

compusi halogenati cond

A

alcl3+H2o

24
Q

alcooli cond

A

h2so4

25
Q

ce inseamna reactivitate marita

A

X legat de un atom de C sp3 din poz alilica/benzilica

26
Q

ce formeaza anhidridele ciclice prin acilarea fc

A

cetoacizi

27
Q

cum se obtine beta nitronaftalina

A

pe cai indirecte

28
Q

de ce are loc sulfonarea nft in pozitia alfa la 80C

A

deoarece r este controlata cinetic

29
Q

cum este controlata suflonarea naftalinei la 160c

A

termodinamic

30
Q

cum este alfa cloronft

A

neizolabila

31
Q

cum este beta cloronft

A

se obine indirect

32
Q

care este produsul final de reactie al clorurarii la nft

A

1,2,3,4-tetracloronatfalina

33
Q

bromurare nft conditii

A

febr3

34
Q

ce izomer al ciclohexanului e mai stabil

A

forma scaun

35
Q

ce fel de izomerie prezinta decalina

A

geometrica

36
Q

stare de agregare tetralina si decalina

A

lichida

37
Q

utilizari decalina si tetralina

A

carburanti, dizolvanti

38
Q

cond aditia halogenilor la bz

A

hv

39
Q

cati stereoizomeri are HCH

A

6

40
Q

denumiri alternative lindan

A

hexacloran, gamehexan

41
Q

utilizari lindan

A

insecticid

42
Q

oxidarea bz cond

A

V2O5, 500C (9/2 O2)

43
Q

ce izomer al ac 1,4 butendioic este ac maleic

A

cis

44
Q

celalalt izomer se numeste

A

acid fumaric

45
Q

oxidarea nft conditii

A

V2O5, 350C (9/2 O2)

46
Q

oxidare antracen cond

A

K2Cr2O7 in prez de acid acetic (8)

47
Q

oxidare cumen cond

A

O2 la 120C

48
Q

produs de reactie oxidare cumen

A

hidroperoxid de cumen=>fenol si acetona in med H2SO4

49
Q

efect inductiv definitie

A

deplasarea e sigma catre unul dintree atomii participanti la -

50
Q

efect electromer definitie

A

deplasarea e pi catre unul dintre atomii participanti la =