Alchine Flashcards

1
Q

lungimea leg triple

A

1,204

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2
Q

izomerie

A

de fct, de poz, de catena, optica

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3
Q

unde au polii alchinele marginale

A

pol pozitiv H, pol negativ C

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4
Q

Ce caracter au at de H legati de un C din tripla

A

slab acid

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5
Q

constanta de aciditate a alchinelor cu tripla marginala

A

10 la -25

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6
Q

dehidrohalogenarea comp dihalogenati vicinali

A

baze tari alcaline, sol alcoolice la t

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7
Q

Care alchine sunt gaze

A

acetilena, propina, 1-butina

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8
Q

in ce conditii sun gaze alchinele de mai sus

A

cond obisnuite (20)

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9
Q

Ce alchine au pf mai scazute

A

cele marginale

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10
Q

actilena are pf mai mic ca

A

2-butina

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11
Q

si mai mare ca

A

1-pentina,1-butina, propina

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12
Q

de ce este acetilena soluila in apa

A

dat polaritatii legaturii

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13
Q

cat dizolva 1 vol de apa si la ce t

A

1,7 vol acetilena la 0C

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14
Q

c% a acetilenei in sol saturata de apa

A

0,20%

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15
Q

C% molara a acetilenei

A

0,075m/L

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16
Q

cat dizolva 1 vol acetilena si la ce pres

A

300 vol acetilena la 12 atm

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17
Q

in cate etape are loc halogenarea

A

2

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18
Q

cum e reactia acetilenei cu clorul in stare gazoasa

A

violenta, puternic exoterma

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19
Q

aditia hidracizilor cond

A

120-170 (170-200) HgCl2

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20
Q

in cate etape are loc aditia hidracizilor

A

in 2 etape

21
Q

PVC solubilitate

A

cetone, comp halo, esteri

22
Q

prop fizice

A

relativ dur, solid, se inmoaie la 90-95c

23
Q

Kucerov cond

A

HgSO4 si H2SO4

24
Q

aditia HCN cond

A

CuCl2, NH4Cl

25
Q

PNA caracteristici (5)

A

rez la purtare, elasticitate, flexibilitate, tuseu bun, nu sunt hidroscopice

26
Q

Aditia ac acetic cond

A

H3C-COO)2Zn la 200-250C

27
Q

PAV proprietati

A

solid, netoxic,

28
Q

solubilitate

A

in solventi org

29
Q

De ce hidrolizeaza PAV

A

ca are gr ester

30
Q

Alcoolul polivinilic

A

solid, cul alba,

31
Q

solubilitate

A

solubil in apa, glicol, glicerina

32
Q

dimerizarea acetilenei

A

cu2cl2, nh4cl

33
Q

neoprenul prop

A

mai rezistent la oxidare ca si cauciucul

34
Q

trimerizarea acetilenei cond

A

600-800

35
Q

tetramerizarea ce formeaza

A

ciclooctatetraena

36
Q

ce rezulta prin aditia alc inferiori la acetilena

A

monomeri vinilici

37
Q

aditia acetilenei la comp carbonilici in rap 1;1

A

cu2c2

38
Q

ce rezulta

A

alcooli nesaturati

39
Q

1;2 ce rezulta

A

dioli

40
Q

ce formeaza acetilena cu bayer

A

acid oxalic

41
Q

alchenele marginale ce formeaza

A

cetoacizi

42
Q

alchinele interne ce formeaza

A

dicetone

43
Q

butandiona alte nume

A

diacetil, dimetilglioxal

44
Q

la ce t se formeaza acetilura monosodica

A

150c

45
Q

ce comp sunt acetilurile met alca si alca-pam

A

compusi ionici, stabili la t obisnuita

46
Q

ce culoare are acetilura de diargint

A

alb-galbui

47
Q

c culoare are acetlura de dicupru

A

brun roscat

48
Q

ce se intampla cu acetilurile tranz la incalzire

A

sunt puternic explozive

49
Q

cum arde acetilena

A

cu flacara luminoasa