Analysis of the Earth and Environment Lecture 14: The Atmosphere Flashcards
Define the atmosphere
The envelope of gases surrounding the earth or another planet.
What is the atmospheric pressure of Earth
Atm. Pressure at the surface of
the Earth is ~1013 hPa.
Describe the composition of Earths atmosphere
78% Nitrogen
21% Oxygen
1% other gasses:
-0.93 %argon
-0.04% trace gases (including the greenhouse gases carbon dioxide, methane, nitrous oxide and ozone.)
What are the four sections of the atmosphere
Split into 4 main layers based of Temperature
Troposphere
Stratosphere
Mesosphere
Thermosphere
Troposphere and stratosphere account for 99.9% of mass of atmosphere (almost half concentrated within 6 km of the Earth’s surface).
Describe the Troposphere
The troposphere is the lowest section. Extends upward 6 - 10 km
We live in this part of atmosphere. Almost all weather takes place here - most clouds found here as 99% of atmospheric water is found here.
As you get higher in the troposphere the temperatures decreases
Describe the Stratosphere
Extends from top of Troposphere about 50km
The Stratosphere contains the Ozone layer which absorbs high energy UV light converting it into heat. As a result, the higher you go in the Stratosphere the higher the temperature.
Describe the Mesosphere
Extends from top of Stratosphere around 80km
Most meteors burn up in this layer
Mesosphere is the coldest layer of the atmosphere (-100 degrees centigrade)
Describe the Thermosphere
Highest part of Earth’s atmosphere. Extends to between 500 to 1000km
Temperatures vary from 500 to 2000 degrees centigrade (or higher). However air is so thin up here that is not the same kind of temp experienced at surface.
Aurora occurs in thermosphere, as well as where international space station orbits
Define the Barometric law
Pressure decreases exponentially with height above the Earth’s surface
Describe the atmospheric composition and conditions of Mercury
Mercury’s gravity is around a third of that on earth so it cannot retain much of an atmosphere. Solar winds are also a big influence.
42% Oxygen
29% Sodium
22% Hydronium
7% Other gases
Describe the atmospheric composition and conditions of Mars
Temperatures on Mars can reach 35 degrees C. The atmosphere is mainly CO2 so greenhouse effects are there,but with less gravity the volatiles escaped over time ? Now the pressure and concentration of the gas is very low (millibar).
95% Carbon Dioxide
3% Nitrogen
1.5% Argon
0.5% Other gasses
Describe the atmospheric composition and conditions of Venus
Atmospheric pressure on Venus is around 92x that on Earth,mainly CO2,and a temperature of around 480 degrees C. Both are partly due to greenhouse effects.
96% Carbon dioxide
3% Nitrogen
1% Other gasses
Clouds of sulfuric acid
Describe the origins of Earths atmospheric composition
- Origins
In the early years of our planet the atmosphere was composed of H and He: as the primordial disk from planetary formation. - Chemical/Pre-biological
Atmosphere formed from volcanic outgassing dominated by water vapour,CO2,SO2 and other gases. - Microbial era
Initial O2 formed through photodissociation, this allowed an ozone layer to be formed, early microbes emitted O2 as waste product. - Biological era
Simultaneous decrease in atmospheric CO2 and the increase in O2 due to respiration/transpiration processes as life developed.
Define the ionosphere
The ionosphere is the very upper part of the atmosphere that is ionized by solar
radiation. This is where the atomic oxidation number comes from.
Describe how radiation interacts with the ionosphere
Solar radiation at ultraviolet (UV)and shorter x-ray wavelength are considered ionizing since photons of energy at these frequencies are capable of dislodging an electron from a neutral gas atom or molecule during collision.
At the same time, an opposing process called
recombination begins to take place
in which a free electron is “captured” by a positive ion if it moves close enough to it.
Describe how radiation reacts with gasses
As the gas density increases at lower altitudes,the recombination process accelerates since the gas molecules and ions are closer together.
- The point of balance between these two processes determines the degree of ionization present at any given time.
- This is also what is constantly happening with ozone in the atmosphere,it is continually being formed and destroyed,it is the
balance in that process that is important. - CFC are now banned as refrigerant as these chemicals disturb this balance, removing Ozone at altitude. But at ground level,Ozone is a pollutant
How is an ozone layer formed
The ozone layer is formed when ordinary molecules of oxygen gas (O2 ) in the stratosphere absorb UV radiation from the sun with wavelength <240 nm, which causes them to dissociate into single oxygen atoms.
Define the Chapman mechanism
A theory for the origin of this ozone layer was proposed in 1930 by a British scientist, Sydney Chapman, and is known as the Chapman
mechanism.
Describe the Decomposition of stratospheric Ozone
Ozone is a very reactive molecule and is termed a meta-stable molecule
- isolated molecules will decompose slowly
- when in contact with a molecule of another gas, it will react quickly.