ANACHEM LAB Flashcards
Members of Group 1 Cations
1 Chloride
2 Bromide
3 Iodide
4 Cyanide
5 Ferrocyanide
6 Ferricyanide
7 Thiocyanate
Chlorides, Bromides, and Iodides are mostly in ____________________
Single oxidation State
Chlorides, Bromides, and Iodides with hydrogen form __________________
Hydrohalides
Chlorides, Bromides, and Iodides form precipitate with ______________ with characteristic colors that could he as a means of identifying them from one another.
Silver Ions
Chlorides, Bromides, and Iodides are ________ reducing agents
Good
Cl-
Chloride
Br-
Bromide
I-
Iodide
CN-
Cyanide
Fe(CN)6 4-
Ferrocyanide
Fe(CN)6 3-
Ferricyanide
SCN-
Thiocyanate
when _________ halides are heated with a few drops of ___________ or conc _______ they form to their corresponding hydrohalide gasses
Alkali, H2SO4, HCl
Chloride evolve in to hydrohalide form
HCl gas (WHITE FUMES)
Bromide evolve in to hydrohalide form
HBr, Br2, SO2 gases (BROWN ON WARMING, and WHITE FUMES)
Iodide evolve in to hydrohalide form
HI, I2, SO2 gases (BROWN ON WARMING VIOLET VAPORS)
Color of Precipitate and Solubility in H20, NH4OH, and HNO3 of AgCl
White, insoluble (Water), Soluble (NH4OH), Insoluble (HNO3)
Color of Precipitate and Solubility in H20, NH4OH, and HNO3 of AgBr
Cream, Soluble (Water), Slightly soluble (NH4OH), Insoluble HNO3
Color of Precipitate and Solubility in H20, NH4OH, and HNO3 of AgI
Light Yellow, slightly soluble (Water), Insoluble (NH4OH & HNO3)
An iodine solution added to starch solution will give a characteristic ____________ color
dark blue
When an alkali iodide is added to a solution of mercuric chloride ___________________________ will precipitate which is soluble in excess of the iodide salt.
a scarlet mercuric iodide
Members of Group II Anions
- Sulfide
- Nitrite
- Acetate
S2-
Silfide
NO2-
Nitrite