ammonia Flashcards

1
Q

state the observation

burning of ammonia in air

A

a greenish-yellow flame is observed

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2
Q

state the observation

when ammonia is burnt in an atmosphere of excess oxygen

A

ammonia burns with a pale blue flame in the atmosphere of excess oxygen

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3
Q

state the observation

excess of chlorine gas is reacted with ammonia gas

A

a yellow explosive liquid is formed (nitrogen trichloride)

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4
Q

state the observation

ammonia is passed through the copper oxide

A

black copper oxide changes to red copper

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5
Q

state the observation

excess of ammonia is passed through an aqueous solution of lead nitrate

A

a white precipitate is produced which is insoluble even in an excess of ammonia

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6
Q

state the observation

a piece of moist red litmus paper is placed in a gas jar of ammonia

A

it turns blue

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7
Q

state the observation

neutral litmus solution is added to an alkaline solution

A

it turns blue

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8
Q

this gas is used as a reducing agent in reducing copper oxide to copper

A

ammonia

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9
Q

gas produced when excess ammonia reacts with chlorine

A

nitrogen

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10
Q

alkaline gas which gives dense white fumes with HCl

A

ammonia

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11
Q

the gas that can be oxidized to sulphur

A

hydrogen sulphide

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12
Q

an oxidizing agent which does not contain any sulphur

A

chlorine gas

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13
Q

warming ammonium sulphate with sodium hydroxide solution

A

ammonia

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14
Q

drying agent used to dry ammonia

A

CaO

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15
Q

passing dry ammonia over heated copper oxide gives ______

A

copper

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16
Q

ammonia can be obtained by adding water to _______

A

magnesium nitride

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17
Q

ammonium nitrate is used in ___________________

A

preparing explosives

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18
Q

with excess of chlorine what does ammonia form

A

NCl3 [nitrogen trichloride]

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19
Q

why is liquid nitrogen employed in refrigerator

A

because it has a high latent heat of vaporization so it takes high amount of heat from the surroundings resulting in the fall of temperature

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20
Q

why is ammonia soluble in water

A

this is because it is a polar molecule

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21
Q

nesseler’s reagent is an alkaline solution of _____

A

K2HgI4 [Potassium tetraiodomercurate(II)]

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22
Q

what temperature is catalytic oxidation of ammonia carried out at ?????

A

800 degrees celcius

23
Q

where is the nitrogen used in haeber’s process obtained from

A

fractional distillation of air

24
Q

how is ammonia gas collected

A

downward displacement of air

25
why is ammonia used as a cleaning agent
ammonia solution emulsifies fat and grease so that they can be removed without leaving any residue
26
ammonia solution is used as a laboratory reagent to identify metal ions
aqueous solution of ammonia can precipitate insoluble hydroxide of metals from their salt solutions hence it is used in the analytical analysis of the salts in the labaratory
27
ammonia is present in sewage water
this because ammonia is produced due to bacterial decomposition of urea [NH2CONH2] present in urea
28
solution of ammonia contains hydroxide ions
since ammonia turns red litmus solution blue it reacts with water to form salt and water
29
ammonia cannot be collected over water
ammonia is extremely soluble in water and cannot be collected over water
30
though ammonia nitrite readily gives nitrogen on heating, a mixture of ammonium chloride and sodium nitrite in water is heated to prepare nitrgoen in the labaratory
ammonium nitrite cannot be stored even at room therefore nitrogen is obtained by heating ammonium chloride and sodium nitrite
31
magnesium nitride reacts with water to liberate _____ and _________
ammonia and magnesium hydroxide
32
what is labaratory bench reagent
it is a dilute solution of liquor ammonia
33
why is dry or liquid ammonia neutral to litmus
ammonia is a covalent compound therefore in the absence of ions dry or liquid Ammonia has no effect on litmus
34
state the purpose of liquifycing ammonia produced in haeber's process
the ammonia procuced is liquifiedto seperate it from uncombined nitrogen and hydrogen
35
write the equation for Haeber's process that forms ammonia
N2 + 3H2 --> 2NH3 (reversible) {200-900atm and 450-500 degrees celcius and catalyst Fe and Mo}
36
what test does Nessler's reagent give with ammonium salts
when ammonium compound is added to colourless Nessler's reagent a brown colour is observed
37
why is acidic drying agent not used for drying ammonia
because acidic drying agents such as H2SO4 react with ammonia
38
how does the solubility of ammonia vary with its temperature
its solubility decreases with an increase in temperature
39
how will you separate ammonia from uncombined N2 and H2
by liquefication by dissolving in water
40
why is catalyst chamber provided with a heat exchanger
this is so that the outgoing ammonia gas and the unreacted gases exchange their heat with the incoming nitrogen and hydrogen
41
which is more dense, ammonia or hydrogen chloride how is it collected
hydrogen chloride is denser than ammonia upward displacement of air
42
what happens when ammonia and HCl gas react write the equation
NH3 + HCl --> NH4Cl
43
give 2 evidences to show that the solution of ammonia in water contains hydroxide ions
i) solution of ammonia is alkaline towards litmus ii) the solution of ammonia precipitates insoluble metal hydroxide
44
what is the reactant used in the preapration of ammonia gas
Mg3N2 + H2O
45
what is the drying agent used in the preparation of ammonia gas
quicklime (Cao)
46
what is the method of collection used in the preparation of ammonia gas
downward displacement of air
47
large scale use of ammonia
manufacture of nitric acid by ostwalds process
48
what properties of ammonia make it a source of hydrogen
--> ammonia can be liquified and transported easily and on decomposition gives hydrogen --> liquid hydrogen is dangerous to transport in cylinders
49
how is ammonium chloride prepared
neutralisation
50
when ammonium chloride is heated what reaction does it undergo
thermal dissociation
51
what does heating ammonia chloride with sodium hydroxide produce
ammonia
52
why is ammonia nitrate not used in the preparatuon of ammonia
- -> it is explosive in nature | - -> it decomposes giving nitrous oxide and water vapour
53
how do you find out if the jar is full of ammonia gas
bring a rod dipped in HCL to the mouth of the jar for which ammonium chloride will be formed