Amines Flashcards
1
Q
Amine creation, reduction of nitriles
A
R—C≡N + 4[H] / 2H2 —–>(LiAlH4 in ethoxyethane/ Ni Catalyst heat) R—CH2—NH2
1
Q
Amine creation, nitrile + halogenalkane
A
R—X + KCN —–> (warm ethanol) R—C≡N + KX
2
Q
Main product with excess ammonia
A
1y Amine
3
Q
Main product with excess Haloalkane
A
4y Ammonium salt
4
Q
Base strength order
A
1y > 2y > 3y > NH3 > Aromatic Amine