AMD and gold cyanidation Flashcards

1
Q

what happens during the chemical rxn for the oxidation of pyrite

A

produces loos H+ ions with acidifies then the environment
a yellow by-product called ferric hydroxide is produced

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2
Q

what types of rocks is pyrite found in

A

metamorphic, specifically shales that are interbedded within coal seams
common near coastal swamps

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3
Q

how do microbes influence the oxidation of pyrite

A

they catalyze the oxidation process
they convert metals into their soluble state

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4
Q

what are treatments for AMD

A

adding a buffer to water systems (fresh)
limit areas of exposed rock which can oxidize
compacting the rock so its smaller
cover the rock with sealing layers

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5
Q

what does cyanide do during gold extraction

A

used to separate cold from other compounds, commonly silver

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6
Q

what happened at Baia mare romania?

A

large cyanide leak from gold mining into the Somes River
killed many fish (main food source)
worst spill since Chernobyl

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7
Q

what is the most common oxidation agent

A

O2, when compounds contact the atmosphere

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8
Q

what sort of scale is the pH built on

A

logarithmic
small change on scale e means big change in H+ count

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9
Q

where are acidic soils found?

A

jungles and rainforests

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10
Q

where are basic soils found?

A

deserts

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11
Q

how does rain impact soil pH?

A

H2O combines with CO2 in the atmos to form carbonic acid (weak 5.5) and has the ability to reduce to the soil pH

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12
Q

what is the common ph of plants

A

slightly acidic- 5.5-7

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13
Q

what is gossan

A

the rusty exposure of a rock

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14
Q

what is the rusty exposure of a rock?

A

gossan

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15
Q

how is AMD preventable

A

prevent or delay oxidation

bacteria inhibition
desulfurization (prevent the formation of SO2)
physical barrier
chemical barrier

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16
Q

limitations of physical barriers

A

expensive
effective for only a short term
generate a lot of waste

17
Q

limitations of bactericides for AMD

A

short effective period and only work on fresh tilling sites
commonly toxic fro aquiatic envrion

18
Q

how does AMD impact health

A

degradation of habitiats and intoxicate food sources

19
Q

what are treatments for AMD

A

adding a buffer to water systems (fresh)
limit areas of exposed rock that can oxidize
compacting the rock so its smaller
cover the rock with sealing layers

20
Q

how does cyanide interfere with cell function

A

prevents the cells from using oxygen and leads to depression of the NS and respiratory arrest

21
Q

what are the impurities of the gold smelting process called

A

slag