Alkalinty Control Agents - Week 2 Flashcards
Caustic Soda - Composition
Sodium Hydroxide (NaOH)
Caustic Soda - Primary Function
For control of pH base muds For: 1. Activation of lingosulfonates 2. Solubilizing lignite 3. Limiting corrosion 4. Removing soluble ions 5. Treatment of certain contaminants
Caustic Soda - Secondary Function
None
Caustic Soda - Limitations
- Health Hazard. Add as a liquid from a chemical barrel
- Wear proper PPE when handling
- Corrosive
- Some products are sensitive to high pH
Caustic Soda - Treatment
As needed to control pH
Magnesium Oxide - Composition
An alkaline earth oxide ( MgO)
Magnesium Oxide - Primary Function
For pH control of fresh water and brines
Magnesium Oxide - Secondary Function
none
Magnesium Oxide - Limitations
pH up to 10
Magnesium Oxide - Features and Benefits
Will not form precipitates when added to calcium base brines
Magnesium Oxide - Treatment
Under normal operating conditions (1-3 ppb)
Potassium Hydroxide - Composition
A strong alkali known as caustic potash (KOH)
Potassium Hydroxide - Primary function
For control of pH base muds For: 1. Activation of lingosulfonates 2. Solubilizing lignite 3. Limiting corrosion 4. Removing soluble ions 5. Treatment of certain contaminants
Potassium Hydroxide - Secondary Function
To provide additional soluble potassium in potassium systems or where potassium ions are preferred as a shale inhibitor
Potassium Hydroxide - Limitations
- Health Hazard. Add as a liquid from a chemical barrel
- Wear proper PPE when handling
- Corrosive
- Some products are sensitive to high pH
Potassium Hydroxide - Treatment
As needed to control pH. Takes more KOH to provide a given pH as compared to NaOH
Soda Ash - Composition
Sodium Carbonate (Na2CO3)
Soda Ash - Primary Function
To remove soluble calcium from the mud
Soda Ash - Secondary Function
May be used to treat small amounts of cement contamination. Also may be used as a completion fluid.
Soda Ash - Limitations
- Over treatment may cause a carbonate problem
- Solubility is suppressed at high pH
- Treating large amounts of cement will result in high pH values and is not recommended
- Soda Ash is not effective for treating hardness from soluble magnesium
- If adding while using chemical barrels DO NOT mix with caustic soda
- Use proper PPE
Soda Ash - Treatment
Ranges: .1-.5 ppb
Sodium Bicarbonate - Composition
NaHCO3 (sodium bicarbonate)
Sodium Bicarbonate - Primary Function
Treating Cement contaminated muds
Sodium Bicarbonate - Secondary Function
None
Sodium Bicarbonate - Limitations
- Over-treatment may cause a carbonate problem
- Do not use to treat make-up water. Sodium Bicarbonate is soluble
Sodium Bicarbonate - Treatment
Ranges: .1-.5 ppb is typical. Green cement may require higher concentrations of sodium bicarbonate to be used.